Change in the magnetic properties of bituminous coal intruded by an igneous dike, Dutch Creek Mine, Pitkin County, Colorado

Magnetization measurements have been made on natural coke–coal samples collected at various distances from a felsic porphyry dike in a coal seam in Dutch Creek Mine, Colorado to help characterize the nature and distribution of the iron-bearing phases. The magnetization passes through a maximum at the coke-to-coal transition about 31 cm from the dike contact. The magnetic measurements support the geochemical data indicating that magmatic fluids along with a high-temperature gas pulse moved into the coal bed. Interaction of the magmatic fluids with the coal diminished the reducing power of the thermal gas pulse from the dike to a point about 24 cm into the coal. The hot reducing gas penetrated further and produced a high temperature (400–525°C) zone (at about 31 cm) just ahead of the magmatic fluids. Metallic iron found in this zone is the principal cause of the observed high magnetization. Beyond this zone, the temperature was too low to alter the coal significantly.     

Electron paramagnetic resonance,optical absorption,and magnetic circular dichroism studies of the CO 3 − molecular-ion in irradiated natural beryl

Room temperature X-irradiation of some natural beryls produced several new absorption lines in the electron paramagnetic resonance (EPR) spectrum, a known series of optical absorption lines in the 500–700 nm range, and a shift of the absorption edge to lower energies. Several of the new EPR lines and part of the irradiation-induced shift of the absorption edge disappeared after a few days at room temperature, and were not examined in detail. However, three of the paramagnetic centres responsible for the new EPR lines were stable at room temperature and two of these have previously been identified as atomic hydrogen and the methyl radical, CH₃. These species were stable to ～150 and ～450°C respectively. The third stable species, hitherto unreported, showed a single-line EPR spectrum of axial symmetry, with g∥=2.0051 and g⊥=2.0152. This spectrum was found to be intensity-correlated with the series of optical bands in the 500–700 nm range, after thermal bleaching at 175°C. The EPR and optical spectra are therefore assigned to the same species. It is argued that this species is the CO ₃ ^? molecular ion, located in the widest part of the structural channel and aligned with the plane of the molecule perpendicular to the c axis. The EPR spectrum is consistent with a ² A′₂ ground state of a CO ₃ ^? molecule with trigonal symmetry, and this requires that the optical transition has a ² A′₂ → ² E′ character. Most of the features in the optical spectrum can be assigned to coupling of a totally symmetric mode of frequency ～1020 cm^?1 onto a zero-phonon line at 14,490 cm^?1 and a second weaker line at 16,020 cm^?1. However, both of these two fundamental lines are structured, and the two components show strong temperature-dependent derivative-shaped magnetic circular dichroism (MCD). Furthermore, the overall sign of the MCD for the line at 16,020 cm^?1 is opposite to that at 14,490 cm^?1. The separation (～120 cm^?1) of the two components of the 14,490 cm^?1 line is much larger than that expected from spin-orbit interaction, and the origin of this splitting is not yet understood.     

Structural characteristics of zooplankton of the Shardarinskoe Reservoir and their use in water quality assessment

Data on the Shardarinskoe Reservoir are used to assess the indicator role of zooplankton community under unstable hydrological regime. The structural characteristics of zooplankton featured significant seasonal variations. The averaged indices characterized reservoir water quality at the level of mesotrophic and eutrophic water bodies. The possible use of cyclopidas to characterize toxic pollution of water is discussed.     

MM5-HPAC simulation experiments

Summary We evaluate mesoscale model predicted boundary-layer flow and the subsequent HPAC (Hazard Prediction and Assessment Capability) dispersion computation. The HPAC software allows for prediction of the effects of surface release of hazardous material into the atmosphere and collateral damage on civilian populations using either observed or numerical weather model data. The advanced mesoscale weather model MM5 was employed in the study. The real-data MM5 model simulations were verified with high-resolution observations from the West Texas Mesonet. MM5 worked well in simulating meteorologically relatively quiescent conditions. We examined the sensitivity of HPAC computations to the MM5 model’s grid resolution, lateral boundary conditions, and input weather data. Results suggest that the MM5-HPAC conjugation can provide useful prediction of airborne transport of hazardous materials near the surface. However, the accuracy of diffusion computations strongly depends on the performance of MM5, which in turn is likely to be a function of weather scenarios. A given state-of-the-art mesoscale model may perform well in some cases but not in others. There is a potential benefit of using several different model winds separately to run HPAC. A composite result of the HPAC runs could give a more comprehensive depiction of the transport of surface hazardous agents.     

Fault structures and their geoelectric parameters in the epicentral zone of the 27 September 2003 Chuya earthquake (Gorny Altai) from resistivity data

This paper presents an integrated measurement technique based on DC methods (vertical electrical sounding, electrical resistivity tomography) which was used to identify faults and determine their geoelectric parameters in the western part of the Chuya basin. New information on the structure of the Chagan River valley located in the zone of the disastrous 27 September 2003 Chuya earthquake has been obtained from the results of these methods. Geoelectric cross-sections of the sedimentary sequence and the upper part of the basement were obtained from VES data, showing the block structure of the study area. Electrical resistivity tomography sections confirm the presence of a major fault between basement blocks of different heights and indicate the presence of faults bounding the valley on its right side and in the southwestern part.     

A sedimentation model of the maikop deposits of the Tuapse Basin in the Black Sea according to the results of 2-D and 3-D seismic surveys and field works in the Western Caucasus and Crimea

This work is based on the results of 2-D and 3-D surveys in the Tuapse Basin and field works in the Crimea-Caucasus region. Seven zones were outlined in the model of sedimentation starting from the eroded mountain structure of the Greater Caucasus down to deep water sediments of the Tuapse Basin. The slope and deep-water sediments of channels and fan complexes are characterized. Volume models of the sedimentation system in the Black Sea are shown for the first time.     

Optimal instrumentation of structures on flexible base for system identification

A criterion previously developed by Heredia-Zavoni and Esteva for selecting optimal sensor locations is used to analyse the optimal instrumentation of structures on soft soils. The stochastic response of a linear structural system on a flexible base is formulated for use of the criterion. The case of MDOF shear systems on flexible base, with uncertain lateral stiffness and subjected to random earthquake ground motions, is studied. The optimal location of accelerometers, the reduction of prior uncertainty on the lateral stiffness, the effects of the base flexibility, the relative influence of translation and rocking of the base, and the influence of recording noise are assessed and discussed. Copyright © 1999 John Wiley & Sons, Ltd.