Three-dimensional transient groundwater flow and saltwater transport models were constructed to assess the impacts of groundwater abstraction and climate change on the coastal aquifer of Tra Vinh province (Vietnam). The groundwater flow model was calibrated with groundwater levels (2007–2016) measured in 13 observation wells. The saltwater transport model was compared with the spatial distribution of total dissolved solids. Model performance was evaluated by comparing observed and simulated groundwater levels. The projected rainfalls from two climate models (MIROC5 and CRISO Mk3.6) were subsequently used to simulate possible effects of climate changes. The simulation revealed that groundwater is currently depleted due to overabstraction. Towards the future, groundwater storage will continue to be depleted with the current abstraction regime, further worsening in the north due to saltwater intrusion from inland trapped saltwater and on the coast due to seawater intrusion. Notwithstanding, the impact from climate change may be limited, with the computed groundwater recharge from the two climate models revealing no significant change from 2017 to 2066. Three feasible mitigation scenarios were analyzed: (1) reduced groundwater abstraction by 25, 35 and 50%, (2) increased groundwater recharge by 1.5 and 2 times in the sand dunes through managed aquifer recharge (reduced abstraction will stop groundwater-level decline, while increased recharge will restore depleted storage), and (3) combining 50% abstraction reduction and 1.5 times recharge increase in sand dune areas. The results show that combined interventions of reducing abstraction and increasing recharge are necessary for sustainable groundwater resources development in Tra Vinh province.
This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD)
waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters
were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO4=) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously
recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and
precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5
(stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates
of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially
sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO4=
anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous
free cations (Pb2+, Zn2+, Cu2+, Cd2+, Mn2+, Co2+, Ni2+) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely
scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10−1) of the SO 4= ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH
< 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co,
Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB. 相似文献
Extensive deposition of marine evaporites occurred during the Early–Middle Eocene in the South‐eastern Pyrenean basin (north‐east Spain). This study integrates stratigraphic and geochemical analyses of subsurface data (oil wells, seismic profiles and gravity data) together with field surveys to characterize this sedimentation in the foredeep and adjacent platform. Four major evaporite units were identified. The oldest was the Serrat Evaporites unit, with a platform‐slope‐basin configuration. Thick salina and sabkha sulphates accumulated on the platform, whereas resedimented and gravity‐derived sulphates were deposited on the slope, and salt and sulphates were deposited in the deep basin. In the subsequent unit (Vallfogona evaporites), thin sulphates formed on the platform, whereas very thick siliciclastic turbidites accumulated in the foredeep. However, some clastic gypsum coming from the platform (gypsarenites and gypsum olistoliths) was intercalated in these turbidites. The following unit, the Beuda Gypsum Formation developed in a sulphate platform‐basin configuration, where the topography of the depositional surface had become smooth. The youngest unit, the Besalú Gypsum, formed in a shallow setting. This small unit provides the last evidence of marine influence in a residual basin. Sulphur and oxygen isotope compositions are consistent with a marine origin for all evaporites. However, δ34S and δ18O values also suggest that, except for the oldest unit (Serrat Evaporites), there was some sulphate recycling from the older into the younger units. The South‐eastern Pyrenean basin constitutes a fine example of a foreland basin that underwent multiepisodic evaporitic sedimentation. In the basin, depositional factors evolved with time under a structural control. Decreasing complexity is observed in the lithofacies, as well as in the depositional models, together with a diminishing thickness of the evaporite units. 相似文献
We investigate the influence of mantle flow relative to the lithosphere on subduction dynamics. We use 2D thermo‐mechanical models assuming incompressible non‐Newtonian fluid rheology. Different mantle flow velocities consistent with absolute plate motion models are tested, as well as both directions of flow, either sustaining or opposing slab dip. The effects of different inflow/outflow velocity profiles, slab strengths and upper–lower mantle viscosity contrasts are also evaluated. Slab dip deviations between models with opposite mantle flow directions range from 37° for relatively strong slabs (ηmax = 1025 Pa s) to 50° for weaker slabs (ηmax = 1024 Pa s), accounting for a significant amount of natural slab dip variability. For imposed mantle flow supporting the slab, the initial stage of slab steepening is followed by a stage of continuous slab dip decrease. This slab shallowing eventually leads to mantle wedge closure, subduction cessation and slab break‐off, possibly driving subduction flips. 相似文献
Ground-penetrating radar (GPR) is a geophysical technique widely used to study the shallow subsurface and identify various sediment features that reflect electromagnetic waves. However, little is known about the exact cause of GPR reflections because few studies have coupled wave theory to petrophysical data. In this study, a 100- and 200-MHz GPR survey was conducted on aeolian deposits in a quarry. Time-domain reflectometry (TDR) was used to obtain detailed information on the product of relative permittivity (ɛr) and relative magnetic permeability (μr), which mainly controls the GPR contrast parameter in the subsurface. Combining TDR data and lacquer peels from the quarry wall allowed the identification of various relationships between sediment characteristics and ɛrμr. Synthetic radar traces, constructed using the TDR logs and sedimentological data from the lacquer peels, were compared with the actual GPR sections. Numerous peaks in ɛrμr, which are superimposed on a baseline value of 4 for dry sand, are caused by potential GPR reflectors. These increases in ɛrμr coincide with the presence of either organic material, having a higher water content and relative permittivity than the surrounding sediment, or iron oxide bands, enhancing relative magnetic permeability and causing water to stagnate on top of them. Sedimentary structures, as reflected in textural change, only result in possible GPR reflections when the volumetric water content exceeds 0·055. The synthetic radar traces provide an improved insight into the behaviour of radar waves and show that GPR results may be ambiguous because of multiples and interference. 相似文献
The cumulative effects of periodic redox cycling on the mobility of As,Fe,and S from alluvial sediment to groundwater were investigated in bioreactor experiments.Two particular sediments from the alluvial floodplain of the Mekong Delta River were investigated:Matrix A(14 m deep)had a higher pyrite concentration than matrix B(7 m deep)sediments.Gypsum was present in matrix B but absent in matrix A.In the reactors,the sediment suspensions were supplemented with As(Ⅲ)and SO_4~(2-),and were subjected to three full-redox cycles entailing phases of nitrogen/CO_2,compressed air sparging,and cellobiose addition.Major differences in As concentration and speciation were observed upon redox cycling.Evidences support the fact that initial sediment composition is the main factor controlling arsenic release and its speciation during the redox cycles.Indeed,a high pyrite content associated with a low SO_4~(2-)content resulted in an increase in dissolved As concentrations,mainly in the form of As(Ⅲ),after anoxic half-cycles;whereas a decrease in As concentrations mainly in the form of As(Ⅴ),was instead observed after oxic half-cycles.In addition,oxic conditions were found to be responsible for pyrite and arsenian pyrite oxidation,increasing the As pool available for mobilization.The same processes seem to occur in sediment with the presence of gypsum,but,in this case,dissolved As were sequestered by biotic or abiotic redox reactions occurring in the Fe—S system,and by specific physico-chemical condition(e.g.pH).The contrasting results obtained for two sediments sampled from the same core show that many complexes and entangled factors are at work,and further refinement is needed to explain the spatial and temporal variability of As release to groundwater of the Mekong River Delta(Vietnam). 相似文献
Natural Hazards - This contribution highlights that the paper presented by Ma et al. (Nat Hazards 89(2):741–756, 2017) presents VIF lower than 1 which does not coincide with the natural... 相似文献
Summary The Válencia Trough of northeastern Spain represents a poorly understood region of Cenozoic extension-related magmatism in western Europe. We present chemical data on mafic xenoliths and their host basalt from the Roca Negra cinder cone in the Catalán Volcanic Zone in the Válencia Trough. The xenoliths consist of augite+hornblende+ oxides±plagioclase±apatite±olivine::Lbiotitelorthopyroxene, and range from clinopyroxenites and hornblendites to gabbroic rocks. The major and trace element compositions of the xenoliths are compatible with formation as cumulates from a range of olivine tholeiitic to strongly alkaline magmas, and show a strong affinity to the Middle Miocene to Recent rift-related magmatism in the Cátalan Volcanic Zone. The xenoliths formed at temperatures of 1110–1180 °C, pressures of 2–7 kb (with 10 kb as the upper limit), and oxygen fugacities corresponding to 1–2 log units above the NNO oxygen buffer. The estimated pressure range implies formation in magma chambers within the crust, possibly also near the crust/mantle boundary (underplating). The presence of crustal cumulates indicates that the total volume of magmas emplaced into the crust in the Cátalan Volcanic Zone may be significantly larger than indicated by surface exposures. Isotopic compositions of the xenoliths are87Sr/86Sr: 0.703537–0.703647,143Nd/144Nd: 0.512732–0.512766,206Pb/204Pb: 18.097–19.106,207Pb/204Pb: 15.522–15.579, and208Pb/204Pb: 37.850–38.794. This range suggests the involvement of two mantle source components. One of these may be the low-velocity component recognized in Cenozoic magmatism in the eastern Atlantic Ocean to central Europe and western Mediterranean. The other component, which differs from those involved in other domains of Cenozoic volcanism in Europe and adjacent areas, may be located in the lithospheric mantle underlying NE Spain, which was metasomatized during late Variscan to early Alpine deformation.
Herkunft und Bedeutung mafischer Xenolithe aus känozoiscben Extensions-bezogenen Vulkaniten aus dem Valencia Trog, Nordost-Spanien
Zusammenfassung Der Válencia Trog in Nordost-Spanien stellt eine noch wenig verstandene Region mit känozoischen Extensions-bezogenern Magmatismus in Westeuropa dar. Wir geben hier chemische Daten über mafische Xenolithe und ihre basaltischen Muttergesteine aus dem Roca Negra Kegei in der vulkanischen Zone von Catalan im Valencia Trog. Die Xenolithe bestehen aus Augit+Hornblende+Oxiden±Plagioklas±Apatit±Olivin±Biotit±Orthopyroxen und reichen in ihrer Zusammensetzung von Klinopyroxeniten und Homblenditen his zu gabbroischen Gesteinen. Die Haupt- und Spurenelementzusammensetzung der Xenolithe entspricht einer Kumulatbildung aus Olivin-tholéitischen bis stark alkalischen Magmen and zeigt eine deutliche Affinität mit dem mittelmiozanen bis rezenten Rift-bezogenen Magmatismus in der vulkanischen Zone von Catalan. Die Xenolithe bildeten sich bei Temperaturen von 1.110 bis 1.180 °C und bei Drucken von 2–7 kb (mit 10 kb als Obergrenze) und bei Sauerstoff-Fugazitäten, die 1 bis 2 log Einheiten über dem NNO Sauerstoff-Puffer liegen. Die abgeschätzten Drucke weisen auf Bildung in Magmakammern innerhalb der Kruste bin, womölich auch in der Nähe der Kruste-Mantelgrenze (Underplating). Das Vorkommen von krustalen Kumulaten zeigt, daß das gesamte Volumen von Magma, das in die Kruste der vulkanischen Zone von Catalan eingedrungen ist, wesentlich größer ist als das, das man aus Oberflächen-Ausbissen entnehmen k6nnte. Die Isotopen-Zusammensetzung der Xenolithe sind87Sr/86Sr: 0.703537–0.703647,143Nd/144Nd: 0.512732–0.512766,206Pb/204 Pb: 18.097–19.106,207Pb/204Pb: 15.522–15.579, and208Pb/204Pb: 37.850–38.794. Dies läßt erkennen, daß es sich bier um zwei verschiedene Mantel-Quellen handelt. Eine davon könnte die Niedrig-Geschwindigkeitskomponente sein, die man in känozoiscben Magmatiten des östlichen Atlantischen Ozeans, sowie in Zentraleuropa und im westlichen Mittelmeer erkannt hat. Die andere Komponete unterscheidet sich von jenen, die in anderen Bereichen von känozoischem Vulkanismus in Europa und benachbarten Gebieten vorkommen. Sie könnte im lithosphärischen Mantel unterhalb von Nordost-Spanien liegen, der während der variszischen bis zur frühalpidischen Deformation metasomatisch beeinflußt wurde.