Combining in situ isotopic, trace element and textural analyses of quartz from four magmatic-hydrothermal ore deposits

This study couples in situ ¹⁶O, ¹⁷O and ¹⁸O isotope and in situ trace element analyses to investigate and characterize the geochemical and textural complexity of magmatic-hydrothermal quartz crystals. Euhedral quartz crystals contemporaneous with mineralization were obtained from four magmatic-hydrothermal ore deposits: El Indio Au–Ag–Cu deposit; Summitville Au–Ag–Cu deposit; North Parkes Cu–Au deposit and Kingsgate quartz-Mo–Bi–W deposit. The internal features of the crystals were imaged using cathodoluminescence and qualitative electron microprobe maps. Quantitative isotopic data were collected in situ using 157 nm laser ablation inductively coupled plasma mass spectrometry (for 40 trace elements in quartz) and sensitive high-resolution ion microprobe (for 3 isotopes in quartz). Imaging revealed fine oscillatory zoning, sector zoning, complex “macromosaic” textures and hidden xenocrystic cores. In situ oxygen isotope analyses revealed a δ¹⁸O range of up to 12.4 ± 0.3 ‰ in a single crystal—the largest isotopic range ever ascribed to oscillatory zonation in quartz. Some of these crystals contain a heavier δ¹⁸O signature than expected by existing models. While sector-zoned crystals exhibited strong trace element variations between faces, no evidence for anisotropic isotope fractionation was found. We found: (1) isotopic heterogeneity in hydrothermal quartz crystals is common and precludes provenance analysis (e.g., δD–δ¹⁸O) using bulk analytical techniques, (2) the trace element signature of quartz is not an effective pathfinder toward noble metal mineralization and (3) in three of the four samples, both textural and isotopic data indicate non-equilibrium deposition of quartz.     

Accumulation,solid partitioning and remobilisation of 99Tc in subtidal and intertidal sediments in the Irish Sea

Recent studies have shown that accumulation of ⁹⁹Tc in seabed sediments labelled by authorised radioactive liquid discharges into the NE Irish Sea from the Sellafield reprocessing complex is greater than previously thought. In this paper, new data on ⁹⁹Tc concentration profiles in subtidal and intertidal sediments from the eastern and western Irish Sea are provided with a view to elucidating the processes responsible for the incorporation and retention of ⁹⁹Tc in the seabed. The data show that substantial amounts of ⁹⁹Tc have accumulated in the fine-grained subtidal sediments off the Cumbrian coast, particularly after increased releases from Sellafield following the commissioning of the Enhanced Actinide Removal Plant (EARP) in 1994. In all the cores taken in this area, ⁹⁹Tc has been found to be present to depths in excess of 30 cm. Analysis of ¹³⁷Cs and ²⁴¹Am profiles, together with other supporting geochemical data, show a high degree of homogenisation of the sediments down to these depths as a result of physical and biological processes, and confirm that incorporation of ⁹⁹Tc into the sediment compartment is actually the result of mixing and reworking, rather than active sediment accumulation. In contrast, active deposition of material transported from this mixed pool of sediment appears to be the dominant mechanism controlling ⁹⁹Tc profiles in intertidal areas close to the Sellafield discharge outfall.Data obtained from the analysis of subtidal sediment cores from the western Irish Sea mud basin suggest that similar mixing processes to those occurring in the subtidal sediments of the eastern Irish Sea are also active in this area. Time-series data on ⁹⁹Tc concentrations in surficial sediments from this basin, gathered in the period 1988–2004, inclusive, show a clear increase in concentrations, by a factor of ～2, between samples collected pre-EARP and post-EARP. The constancy of ⁹⁹Tc concentrations in surface sediments throughout the 1980s and the early-1990s suggests that little redissolution and export of ⁹⁹Tc occurred over this extended period. A similar observation applies to the post-EARP period, when concentrations remained relatively constant despite the reported steady decrease in ⁹⁹Tc concentrations in the overlying waters.This apparent lack of remobilisation is consistent with data from sequential extraction analyses, which indicate that the bulk of the ⁹⁹Tc is strongly bound to non-labile geochemical phases, with only a small proportion associated with exchangeable and acido-soluble phases. Further, these analyses show that ⁹⁹Tc is not associated with oxygen-sensitive and highly-reactive acid-volatile sulphides (AVS) to any significant extent.     

<Emphasis Type=Bold>Paleoproterozoic Boninite-Like Rocks in an Intracratonic Setting from Northern Bastar Craton,Central India</Emphasis> by D.V. Subba Rao,V. Balaram,K. Naga Raju and D.N. Sridhar. Jour. Geol. Soc. India,v.72, 2008, pp.373–380

Discussion

Paleoproterozoic Boninite-Like Rocks in an Intracratonic Setting from Northern Bastar Craton, Central India by D.V. Subba Rao, V. Balaram, K. Naga Raju and D.N. Sridhar. Jour. Geol. Soc. India, v.72, 2008, pp.373–380     

A Relationship Between Transition Region Brightenings,Abundances, and Magnetic Topology

We present multi-instrument observations of active region (AR) 8048, made between 3 June and 5 June 1997, as part of the SOHO Joint Observing Program 33. This AR has a sigmoid-like global shape and undergoes transient brightenings in both soft X-rays and transition region (TR) lines. We compute a magneto-hydrostatic model of the AR magnetic field, using as boundary condition the photospheric observations of SOHO/MDI. The computed large-scale magnetic field lines show that the large-scale sigmoid is formed by two sets of coronal loops. Shorter loops, associated with the core of the SXT emission, coincide with the loops observed in the hotter CDS lines. These loops reveal a gradient of temperature, from 2 MK at the top to 1 MK at the ends. The field lines most closely matching these hot loops extend along the quasi-separatrix layers (QSLs) of the computed coronal field. The TR brightenings observed with SOHO/CDS can also be associated with the magnetic field topology, both QSL intersections with the photosphere, and places where separatrices issuing from bald patches (sites where field lines coming from the corona are tangent to the photosphere) intersect the photosphere. There are, furthermore, suggestions that the element abundances measured in the TR may depend on the type of topological structure present. Typically, the TR brightenings associated with QSLs have coronal abundances, while those associated with BP separatrices have abundances closer to photospheric values. We suggest that this difference is due to the location and manner in which magnetic reconnection occurs in two different topological structures. Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1023/A:1013302317042     

Production of organic molecules in the outer solar system by proton irradiation: Laboratory simulations

In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH₄, NH₃, and H₂S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6R_J from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.     

Evolution of the Fine Structure of Magnetic Fields in the Quiet Sun: Observations from Sunrise/IMaX and Extrapolations

Observations with the balloon-borne Sunrise/Imaging Magnetograph eXperiment (IMaX) provide high spatial resolution (roughly 100 km at disk center) measurements of the magnetic field in the photosphere of the quiet Sun. To investigate the magnetic structure of the chromosphere and corona, we extrapolate these photospheric measurements into the upper solar atmosphere and analyze a 22-minute long time series with a cadence of 33 seconds. Using the extrapolated magnetic-field lines as tracer, we investigate temporal evolution of the magnetic connectivity in the quiet Sun’s atmosphere. The majority of magnetic loops are asymmetric in the sense that the photospheric field strength at the loop foot points is very different. We find that the magnetic connectivity of the loops changes rapidly with a typical connection recycling time of about 3±1 minutes in the upper solar atmosphere and 12±4 minutes in the photosphere. This is considerably shorter than previously found. Nonetheless, our estimate of the energy released by the associated magnetic-reconnection processes is not likely to be the sole source for heating the chromosphere and corona in the quiet Sun.     

Solar Flare Prediction Using Advanced Feature Extraction, Machine Learning, and Feature Selection

Novel machine-learning and feature-selection algorithms have been developed to study: i) the flare-prediction-capability of magnetic feature (MF) properties generated by the recently developed Solar Monitor Active Region Tracker (SMART); ii) SMART’s MF properties that are most significantly related to flare occurrence. Spatiotemporal association algorithms are developed to associate MFs with flares from April 1996 to December 2010 in order to differentiate flaring and non-flaring MFs and enable the application of machine-learning and feature-selection algorithms. A machine-learning algorithm is applied to the associated datasets to determine the flare-prediction-capability of all 21 SMART MF properties. The prediction performance is assessed using standard forecast-verification measures and compared with the prediction measures of one of the standard technologies for flare-prediction that is also based on machine-learning: Automated Solar Activity Prediction (ASAP). The comparison shows that the combination of SMART MFs with machine-learning has the potential to achieve more accurate flare-prediction than ASAP. Feature-selection algorithms are then applied to determine the MF properties that are most related to flare occurrence. It is found that a reduced set of six MF properties can achieve a similar degree of prediction accuracy as the full set of 21 SMART MF properties.     

Bouguer gravity profiles across the highland-lowland escarpment on Mars

Selected Bouguer gravity profiles crossing the highland-lowland boundary of Mars are calculated. Density-depth models are presented for two areas. All profiles show an isostatic behaviour of the ancient highlands and the adjacent lowlands. Especially isostasy must be implied for the area of the escarpment. It is found that the whole Elysium dome is also nearly in isostatic equilibrium. These geophysical results and additional geological investigations imply a combination of subcrustal and minor surface erosion associated with relatively small vertical isostatic movements of the crust (sinking) in former highland areas. These processes caused a retreat of the highland escarpment of at least several hundred kilometers.