A study of conditions at the inner core boundary of the earth

A study is made of the thermal and compositional conditions which the liquid outer core must satisfy at the inner core boundary, assuming the inner core to be growing by continual solidification of the heavy component of the liquid alloy in the outer core. It is found that the outer core is strongly destabilized by the compositional gradients driven by the separation process associated with the freezing. Further, it is argued that all the freezing necessary for the growth of the solid inner core cannot occur on a flat interface; most of it must occur above the solid boundary in a region labeled the slurry layer.     

中国西北地区早古生代柴达木北缘超高压变质带的大陆俯冲：证据来自此带中发现柯石英

作者使用激光拉曼微光谱在柴达木北缘超高压变质带与一大型榴辉岩体有关的泥质片麻岩的锆石单矿物中发现柯石英。柯石英呈包体产出。此外,还发现一些石墨包体。这发现表明曾发生原地超高压变质作用。地体很可能是在低于金刚石稳定区压力条件下结晶的。     

Variability of sediment diatom assemblages in an upland,wind-stressed lake (Loch Fleet,Galloway, S.W. Scotland)

The variability of diatom distribution in an acidified, upland wind-stressed lake (Loch Fleet, Galloway, S. W. Scotland) was assessed by analysis of 28 surface sediment samples and 11 cores. Correspondence analysis (CA) and cluster analysis were used to illustrate the variability of the surface sediment and core samples. There was reasonable uniformity of taxa in most of the surface sediment samples, although 7 samples, as indicated by both CA and cluster analyses were atypical. Most cores recorded clearly the acidification of the lake, although percentages of individual taxa varied up to 20% between cores. Two cores had old, preacidification diatom assemblages (of indeterminate age) close to the sediment surface. These old sediments were probably the source of the re-worked diatoms found in the atypical surface sediment assemblages. Diatom trends, as CA ordinations and pH profiles, were less variable than the surface sediment assemblages. It is argued that non-uniform sediment accumulation rates and diatom deposition cause variability in surface sediment diatom samples. This variability may be reduced in core profiles by homogenization during further resuspension/deposition cycles and burial. Cores, and the associated time component they offer, may be useful in assessing the variability of surface sediment assemblages.     

Tidal Stress/Strain and the b-values of Acoustic Emissions at the Underground Research Laboratory, Canada

The correlation between the b-values of acoustic emissions (AEs) and the phase of the moon was investigated at the Underground Research Laboratory (URL) in Canada. The same data as those used in Iwata (2002) were examined, which showed that the occurrence of AEs is correlated with the phase of the moon. It was expected, therefore, that the b-value of the AEs would also be sensitive to tidal stress/strain fluctuations. We investigated the variation of the b-values as a function of the phase of the moon. Results show that b-values immediately following the times of full/new moon are higher than those at other times. Using AIC (Akaike Information Criterion) and random (Monte Carlo) simulations, it was confirmed that this feature is statistically significant. We also investigated whether or not there was a change in the b-values immediately before the times of full/new moon, but no statistically significant change was observed. The results suggest that the effect of stress/strain fluctuations on AE occurrences at the URL is asymmetric to the times of full/new moon.All authors are members of the Academic Robotics Group. In listing The Academic Robotics Group, the authors are endeavoring to place each of the participant institutions on an equal footing in terms of effort and authorship. M. A. Talamini is serving as presenter.     

Temporal patterns and controls on runoff magnitude and solution chemistry of urban catchments in the semiarid southwestern United States

Urban expansion and the scarcity of water supplies in arid and semiarid regions have increased the importance of urban runoff to localized water resources. However, urban catchment responses to precipitation are poorly understood in semiarid regions where intense rainfall often results in large runoff events during the short summer monsoon season. To evaluate how urban runoff quantity and quality respond to rainfall magnitude and timing, we collected stream stage data and runoff samples throughout the 2007 and 2008 summer monsoons from four ephemeral drainages in Tucson, Arizona. Antecedent rainfall explained 20% to 30% of discharge (mm) and runoff ratio in the least impervious (22%) catchment but was not statistically related to hydrologic responses at more impervious sites. Regression models indicated that rainfall depth, imperviousness and their combined effect control discharge and runoff ratios (p < 0.01, r² = 0.91 and 0.75, respectively). In contrast, runoff quality did not vary with imperviousness or catchment size. Rainfall depth and duration, time since antecedent rainfall and event and cumulative discharge controlled runoff hydrochemistry and resulted in five specific solute response patterns: (i) strong event and seasonal solute mobilization (solute flush), (ii) event chemostasis and strong seasonal flush, (iii) event chemostasis and weak seasonal flush, (iv) event and seasonal chemostasis and (v) late seasonal flush. Our results indicate that hydrologic responses of semiarid catchments are controlled by rainfall partitioning at the event scale, whereas wetting magnitude, frequency and timing alter solute stores readily available for transport and control temporal runoff quality. Copyright © 2012 John Wiley & Sons, Ltd.     

Spatial and temporal variability and drivers of net ecosystem metabolism in western Gulf of Mexico estuaries

Net ecosystem metabolism (NEM) is becoming a commonly used ecological indicator of estuarine ecosystem metabolic rates. Estuarine ecosystem processes are spatially and temporally variable, but the corresponding variability in NEM has not been properly assessed. Spatial and temporal variability in NEM was assessed in four western Gulf of Mexico shallow water estuaries. NEM was calculated from high-frequency dissolved oxygen measurements. Interbay, intrabay, and water column spatial scales were assessed for NEM, gross primary production (GPP), and respiration (R) rate variability. Seasonal, monthly, and daily temporal scales in NEM, GPP, and R were also assessed. Environmental conditions were then compared to NEM to determine which factors were correlated with each temporal and spatial scale. There was significant NEM spatial variability on interbay, intrabay, and water column spatial scales. Significant spatial variability was ephemeral, so it was difficult to ascertain which environmental conditions were most influential at each spatial scale. Significant temporal variability in NEM on seasonal, monthly, and daily scales was found and it was correlated to temperature, salinity, and freshwater inflow, respectively. NEM correlated strongly with dissolved oxygen, temperature, and salinity, but the relationships where different in each bay. The dynamics of NEM on daily scales indicate that freshwater inflow events may be the main driver of NEM in the semiarid estuaries studied. The variable nature of NEM found here is further evidence that it is not valid to use single station monitoring deployments for assessment of whole estuarine ecosystem metabolic rates in large ecosystems. The relationship between NEM and temperature, salinity, and freshwater inflow events could drive predictive models assessing the potential influence of projected climate change and watershed development scenarios on estuarine metabolic rates.     

Effects of oil pollution on breeding Grey Seals

Marine mammals are probably frequently exposed to floating oil but little is known about the effect oil pollution has on them. Oil stranded on the shore in Pembrokeshire, West Wales in September 1974 coincided with the start of the Grey Seal breeding season there. Observations have been made on the effect the oil had on the newborn pups and their mothers.