Assessment of perfluorinated compounds (PFCs) in plasma of bottlenose dolphins from two southeast US estuarine areas: relationship with age, sex and geographic locations

Plasma PFCs were measured in 157 bottlenose dolphins (Tursiops truncatus) sampled from two US southeast Atlantic sites (Charleston (CHS), SC and Indian River Lagoon (IRL), FL) during 2003-2005. ∑PFCs, perfluoroalkyl carboxylates (∑PFCAs), perfluoroalkyl sulfonates (∑PFSAs) and individual compounds were significantly higher in CHS dolphins for all age/sex categories compared to IRL dolphins. Highest ∑PFCs concentrations occurred in CHS juvenile dolphins (2340 ng/g w.w.); significantly higher than found in adults (1570 ng/g w.w. males; 1330 ng/g w.w. females). ∑PFCAs were much greater in CHS dolphins (≈ 21%) compared to IRL dolphins (≈ 7%); ∑PFSAs were 79% in CHS dolphins versus 93% in IRL dolphins. PFOS, the dominant compound, averaged 72% and 84%, respectively, in CHS and IRL dolphins. Decreasing PFC levels occurred with age on the bioaccumulation of PFCs in both sites. These observations suggest PFC accumulation in these two dolphin populations are influenced by site-specific exposures with significantly higher levels in CHS dolphins.     

Asymptotic giant branch stars in the Phoenix dwarf galaxy

JHK _s near-infrared photometry of stars in the Phoenix dwarf galaxy is presented and discussed. Combining these data with the optical photometry of Massey et al. allows a rather clean separation of field stars from Phoenix members. The discovery of a Mira variable ( P = 425 d), which is almost certainly a carbon star, leads to an estimate of the distance modulus of 23.10 ± 0.18 that is consistent with other estimates and indicates the existence of a significant population of age ∼2 Gyr. The two carbon stars of Da Costa have   M _bol=−3.8  and are consistent with belonging to a population of similar age; some other possible members of such a population are identified. A Da Costa non-carbon star is  Δ K _s∼ 0.3  mag brighter than these two carbon stars. It may be an asymptotic giant branch star of the dominant old population. The nature of other stars lying close to it in the   K _s, ( J − K _s)  diagram needs studying.     

Palaeoenvironmental evolution of Cenote Aktun Ha (Carwash) on the Yucatan Peninsula,Mexico and its response to Holocene sea-level rise

A 61-cm core was obtained from 4 m below the water table in Cenote Aktun Ha, on the Yucatan Peninsula, Mexico. The cenote is 8.6 km from the Caribbean coast and its formation and evolution have been largely affected by sea-level change. The base of the core dates to 6,940–6,740 cal year BP and overlying sediments were deposited rapidly over the subsequent ~200 years. The pollen record shows that the cenote evolved from a marsh dominated by red mangrove (Rhizophora mangle) and fern (Polypodiaceae) to an open-water system. These vegetation changes were controlled by water level and salinity and are thus useful indicators of past sea level. At the base, the δ¹³C_org isotopic ratios reveal the influence of terrestrial vegetation (−29‰ VPDB), but shift to more negative values up-core (−33‰), indicating an influence from particulate matter in the flooded cenote pool. Although microfossil populations were nearly absent through most of the core, the microfossil assemblage in the upper 6 cm of the core is dominated by the juvenile foraminifer Ammonia tepida and the thecamoebian genus Centropyxis. These populations indicate open-water conditions in the cenote and a major environmental shift around 6,600 cal year BP, which is related to sea-level rise in the Caribbean basin. These data fit well with previously established sea-level curves for the Caribbean Sea. Our reconstruction of the environmental history of Cenote Aktun Ha helps elucidate the floral and hydrological history of the region, and highlights the utility of cenote sediments for studying the Holocene sea-level history of the Caribbean Sea.     

Assessment of the UV camera sulfur dioxide retrieval for point source plumes

Digital cameras, sensitive to specific regions of the ultra-violet (UV) spectrum, have been employed for quantifying sulfur dioxide (SO₂) emissions in recent years. The instruments make use of the selective absorption of UV light by SO₂ molecules to determine pathlength concentration. Many monitoring advantages are gained by using this technique, but the accuracy and limitations have not been thoroughly investigated. The effect of some user-controlled parameters, including image exposure duration, the diameter of the lens aperture, the frequency of calibration cell imaging, and the use of the single or paired bandpass filters, have not yet been addressed. In order to clarify methodological consequences and quantify accuracy, laboratory and field experiments were conducted. Images were collected of calibration cells under varying observational conditions, and our conclusions provide guidance for enhanced image collection. Results indicate that the calibration cell response is reliably linear below 1500 ppm m, but that the response is significantly affected by changing light conditions. Exposure durations that produced maximum image digital numbers above 32 500 counts can reduce noise in plume images. Sulfur dioxide retrieval results from a coal-fired power plant plume were compared to direct sampling measurements and the results indicate that the accuracy of the UV camera retrieval method is within the range of current spectrometric methods.     

The surface archaeological record in arid Australia: Geomorphic controls on preservation,exposure, and visibility

The conventional approach to assessing the archaeological record in most parts of the world involves a combination of excavation of stratified deposits and extensive survey of surface deposits. Although widely applied in Australia, in both research‐based and management archaeology, the method does not conform well to the nature of the surface archaeological record here. Over much of semi‐arid and arid Australia, archaeological “sites” are, in fact, accretion phenomena that are not easily interpreted as the outcome of short‐term behavioral events. Using results from twelve years of geoarchaeological research in western New South Wales, we demonstrate that there is considerable variability in landsurface age, and hence the “availability” of archaeological surfaces, over relatively short distances. Therefore, it cannot be assumed that stone artifact deposits, for example, that appear to be similar in character are of similar age. Data are also presented that demonstrate that the presence of artifacts on the surface, their apparent absence in sediments buried beneath the surface, and the apparent recent ubiquity of the archaeological record are all a function of geomorphic processes that, at the same time, expose some artifact deposits at the surface and erode and bury others amid large volumes of sediment. Interpreting the surface artifact record within a spatial and temporal geomorphic framework is crucial to understanding the past human behavior that the artifact deposits represent. © 2009 Wiley Periodicals, Inc.     

Effect of water on the fluorine and chlorine partitioning behavior between olivine and silicate melt

Halogens show a range from moderate (F) to highly (Cl, Br, I) volatile and incompatible behavior, which makes them excellent tracers for volatile transport processes in the Earth’s mantle. Experimentally determined fluorine and chlorine partitioning data between mantle minerals and silicate melt enable us to estimate Mid Ocean Ridge Basalt (MORB) and Ocean Island Basalt (OIB) source region concentrations for these elements. This study investigates the effect of varying small amounts of water on the fluorine and chlorine partitioning behavior at 1280?°C and 0.3 GPa between olivine and silicate melt in the Fe-free CMAS+F–Cl–Br–I–H₂O model system. Results show that, within the uncertainty of the analyses, water has no effect on the chlorine partitioning behavior for bulk water contents ranging from 0.03 (2) wt% H₂O (D_Cl ^ol/melt = 1.6?±?0.9 × 10^?4) to 0.33 (6) wt% H₂O (D_Cl ^ol/melt = 2.2?±?1.1 × 10^?4). Consequently, with the effect of pressure being negligible in the uppermost mantle (Joachim et al. Chem Geol 416:65–78, 2015), temperature is the only parameter that needs to be considered for the determination of chlorine partition coefficients between olivine and melt at least in the simplified iron-free CMAS+F–Cl–Br–I–H₂O system. In contrast, the fluorine partition coefficient increases linearly in this range and may be described at 1280?°C and 0.3 GPa with (R ²?=?0.99): \(D_{F}^{\text{ol/melt}}\ =\ 3.6\pm 0.4\ \times \ {{10}^{-3}}\ \times \ {{X}_{{{\text{H}}_{\text{2}}}\text{O}}}\left( \text{wt }\!\!\%\!\!\text{ } \right)\ +\ 6\ \pm \ 0.4\times \,{{10}^{-4}}\). The observed fluorine partitioning behavior supports the theory suggested by Crépisson et al. (Earth Planet Sci Lett 390:287–295, 2014) that fluorine and water are incorporated as clumped OH/F defects in the olivine structure. Results of this study further suggest that fluorine concentration estimates in OIB source regions are at least 10% lower than previously expected (Joachim et al. Chem Geol 416:65–78, 2015), implying that consideration of the effect of water on the fluorine partitioning behavior between Earth’s mantle minerals and silicate melt is vital for a correct estimation of fluorine abundances in OIB source regions. Estimates for MORB source fluorine concentrations as well as chlorine abundances in both mantle source regions are within uncertainty not affected by the presence of water.     

Evaluation of community leaders’ perception regarding Alerta Rio,the warning system for landslides caused by heavy rains in Rio de Janeiro

Warning systems help reduce damage and save lives in disasters; however, there is a lack of research analyzing the population perception of these systems. In Rio de Janeiro (Brazil), because the city slums face the risk of landslides caused by heavy rains, a siren early warning system named “Alerta Rio” was installed in 102 areas. The purpose of this paper was to understand the perception of community leaders regarding this alert system. To this end, a survey was conducted with community leaders to collect data on whether and why the public do or do not attend to the alert. Results indicated that (1) public adherence to Alerta Rio is low despite the generally positive view of the system, (2) local violence was reported as the reason for staying at home to protect one’s property, and (3) problems with temporary shelters and the routes to them result in lack of people’s involvement in the system. Whereas these factors are similar to population perception regarding other warning systems, the community leaders also raised the public’s lack of trust in the city hall’s adopted concept of risk and in the politicians as a relevant factor in the population perception of Alerta Rio. These factors, together with the lack of prevention policies complementary with the alert system, led to perception of reduced importance of the system. For potential solutions to enhance alarm compliance, this study recommends improvement in communication, educational programs, and public engagement strategies tailored for each target group.     

New radiometric and petrological constraints on the evolution of the Pichincha volcanic complex (Ecuador)

Fieldwork, radiometric (⁴⁰Ar/³⁹Ar and ¹⁴C) ages and whole-rock geochemistry allow a reconstruction of eruptive stages at the active, mainly dacitic, Pichincha Volcanic Complex (PVC), whose eruptions have repeatedly threatened Quito, most recently from 1999 to 2001. After the emplacement of basal lavas dated at ∼1100 to 900 ka, the eruptive activity of the old Rucu Pichincha volcano lasted from ∼850 ka to ∼150 ka before present (BP) and resulted in a 15 × 20 km-wide edifice, which comprises three main building stages: (1) A lower stratocone (Lower Rucu, ∼160 km³ in volume) developed from ∼850 to 600 ka; (2) This edifice was capped by a steeper-sided and less voluminous cone (the Upper Rucu, 40–50 km³), the history of which started 450–430 ka ago and ended around 250 ka with a sector collapse; (3) A smaller (8–10 km³) but more explosive edifice grew in the avalanche amphitheatre and ended Rucu Pichincha's history about 150 ka ago. The Guagua Pichincha volcano (GGP) was developed from 60 ka on the western flank of Rucu with four growth stages separated by major catastrophic events. (1) From ∼60 to 47 ka, a basal effusive stratocone developed, terminating with a large ash-and-pumice flow event. (2) This basal volcano was followed by a long-lasting dome building stage and related explosive episodes, the latter occurring between 28–30 and 22–23 ka. These first two stages formed the main GGP (∼30 km³), a large part of which was removed by a major collapse 11 ka BP. (3) Sustained explosive activity and viscous lava extrusions gave rise to a new edifice, Toaza (4–5 km³ in volume), which in turn collapsed around 4 ka BP. (4) The ensuing amphitheatre was partly filled by the ∼1-km³ Cristal dome, which is the historically active centre of the Pichincha complex. The average output rate for the whole PVC is 0.29 km³/ka. Nevertheless, the chronostratigraphic resolution we obtained for Lower Rucu Pichincha and for the two main edifices of Guagua Pichincha (main GGP and Toaza), leads to eruptive rates of 0.60–0.65 km³/ka during these construction stages. These output rates are compared to those of other mainly dacitic volcanoes from continental arcs. Our study also supports an overall SiO₂ and large-ion lithophile elements enrichment as the PVC develops. In particular, distinctive geochemical signatures indicate the involvement of a new magma batch at the transition between Rucu and Guagua. At the GGP, the same phenomenon occurs at each major collapse event marking the onset of the ensuing magmatic stage. Since the 11-ka-BP collapse event, this magmatic behaviour has led to increasingly explosive activity. Four explosive cycles of between 100 and 200 years long have taken place at the Cristal dome in the past 3.7 ka, and repose intervals between these cycles have tended to decrease with time. As a consequence, we suggest that the 1999–2001 eruptive period may have initiated a new eruptive cycle that might pose a future hazard to Quito (∼2 million inhabitants).