Guagua Pichincha, located 14 km west of Quito, Ecuador, is a stratovolcano bisected by a horseshoe-shaped caldera. In 1999, after some months of phreatic activity, Guagua Pichincha entered into an eruptive period characterized by the extrusion of several dacitic domes, vulcanian eruptions, and pyroclastic flows. We estimated the three-dimensional (3-D) P-wave velocity structure beneath Guagua Pichincha using a tomographic inversion method based on finite-difference calculations of first-arrival times. Hypocenters of volcano-tectonic (VT) earthquakes and long-period (LP) events were relocated using the 3-D P-wave velocity model. A low-velocity anomaly exists beneath the caldera and may represent an active volcanic conduit. Petrologic analysis of eruptive products indicates a magma storage region beneath the caldera, having a vertical extent of 7–8 km with the upper boundary at about sea level. This zone coincides with the source region of deeper VT earthquakes, indicating that a primary magma body exists in this region. LP swarms occurred in a cyclic pattern synchronous with ground deformation during magma extrusions. The correlation between seismicity and ground deformation suggests that both respond to pressure changes caused by the cyclic eruptive behavior of lava domes. 相似文献
— We discuss and illustrate graphically with simple 2-D problems, four common pitfalls in geophysical nonlinear inversion. The first one establishes that the Lagrange multiplier, used to incorporate a priori information in the geophysical inverse problem, should be the largest value still compatible with a reasonable data fitting. This procedure should be used only when the interpreter is sure about the importance of the a priori information used to stabilize the inverse problem relative to the geophysical observations. Because this is rarely the case, the user should use the smallest Lagrange multiplier still producing stable solutions. The second pitfall is an attempt to automatically estimate the Lagrange multiplier by decreasing it along the iterative process used to solve the nonlinear optimization problem. Consequently, at the last iteration, the Lagrange multiplier may be so small that the problem may become ill-posed and any computed solution in this case is meaningless. The third pitfall is related to the incorporation of a priori information by a technique known as “Jumping.” This formulation, from the viewpoint of the class of Acceptable Gradient Methods, is incomplete and may lead to a premature halt in the iteration, and, consequently, to solutions far from the true one. Finally, the fourth pitfall is an inadequate convergence criterion which stops the iteration when the data misfit drops just below the noise level, irrespective of the fact that the functional to be minimized may not have attained its minimum. This means that the a priori information has not been completely incorporated, so that this stopping criterion partially neutralizes the effect of the stabilizing functional, and opens the possibility of obtaining unstable, meaningless estimates. 相似文献
Volcán Huaynaputina is a group of four vents located at 16°36'S, 70°51'W in southern Peru that produced one of the largest eruptions of historical times when ~11 km3 of magma was erupted during the period 19 February to 6 March 1600. The main eruptive vents are located at 4200 m within an erosion-modified amphitheater of a significantly older stratovolcano. The eruption proceeded in three stages. Stage I was an ~20-h sustained plinian eruption on 19-20 February that produced an extensive dacite pumice fall deposit (magma volume ~2.6 km3). Throughout medial-distal and distal parts of the dispersal area, a fine-grained plinian ashfall unit overlies the pumice fall deposit. This very widespread ash (magma volume ~6.2 km3) has been recognized in Antarctic ice cores. A short period of quiescence allowed local erosion of the uppermost stage-I deposits and was followed by renewed but intermittent explosive activity between 22 and 26 February (stage II). This activity resulted in intercalated pyroclastic flow and pumice fall deposits (~1 km3). The flow deposits are valley confined, whereas associated co-ignimbrite ash fall is found overlying the plinian ash deposit. Following another period of quiescence, vulcanian-type explosions of stage III commenced on 28 February and produced crudely bedded ash, lapilli, and bombs of dense dacite (~1 km3). Activity ceased on 6 March. Compositions erupted are predominantly high-K dacites with a phenocryst assemblage of plagioclase>hornblende>biotite>Fe-Ti oxides-apatite. Major elements are broadly similar in all three stages, but there are a few important differences. Stage-I pumice has less evolved glass compositions (~73% SiO2), lower crystal contents (17-20%), lower density (1.0-1.3 g/cm3), and phase equilibria suggest higher temperature and volatile contents. Stage-II and stage-III juvenile clasts have more evolved glass (~76% SiO2) compositions, higher crystal contents (25-35%), higher densities (up to 2.2 g/cm3), and lower temperature and volatile contents. All juvenile clasts show mineralogical evidence for thermal disequilibrium. Inflections on a plot of log thickness vs area1/2 for the fall deposits suggest that the pumice fall and the plinian ash fall were dispersed under different conditions and may have been derived from different parts of the eruption column system. The ash appears to have been dispersed mainly from the uppermost parts of the umbrella cloud by upper-level winds, whereas the pumice fall may have been derived from the lower parts of the umbrella cloud and vertical part of the eruption column and transported by a lower-altitude wind field. Thickness half distances and clast half distances for the pumice fall deposit suggests a column neutral buoyancy height of 24-32 km and a total column height of 34-46 km. The estimated mass discharge rate for the ~20-h-long stage-I eruption is 2.4᎒8 kg/s and the volumetric discharge rate is ~3.6᎒5 m3/s. The pumice fall deposit has a dispersal index (Hildreth and Drake 1992) of 4.4, and its index of fragmentation is at least 89%, reflecting the dominant volume of fines produced. Of the 11 km3 total volume of dacite magma erupted in 1600, approximately 85% was evacuated during stage 1. The three main vents range in size from ~70 to ~400 m. Alignment of these vents and a late-stage dyke parallel to the NNW-SSE trend defined by older volcanics suggest that the eruption initiated along a fissure that developed along pre-existing weaknesses. During stage I this fissure evolved into a large flared vent, vent 2, with a diameter of approximately 400 m. This vent was active throughout stage II, at the end of which a dome was emplaced within it. During stage III this dome was eviscerated forming the youngest vent in the group, vent 3. A minor extra-amphitheater vent was produced during the final event of the eruptive sequence. Recharge may have induced magma to rise away from a deep zone of magma generation and storage. Subsequently, vesiculation in the rising magma batch, possibly enhanced by interaction with an ancient hydrothermal system, triggered and fueled the sustained Plinian eruption of stage I. A lower volatile content in the stage-II and stage-III magma led to transitional column behavior and pyroclastic flow generation in stage II. Continued magma uprise led to emplacement of a dome which was subsequently destroyed during stage III. No caldera collapse occurred because no shallow magma chamber developed beneath this volcano. 相似文献
The application of the ground penetrating radar (GPR) at two archaeological sites, Serrano and Morro Grande, situated in Araruama County, Rio de Janeiro, Brazil, aids the study of a prehistoric indigenous culture, associated with the “Tupinambá” that inhabited the region during prehistoric times.The archaeological remains of the study area are mainly characterized by pottery artifacts for several uses, including funerary urns, which were buried within layers of sand and clay. Several profiles were acquired using a RAMAC system, with a 200 and 400 MHz frequency antennae. At the Serrano site, the profiles were acquired around some partially exposed pottery shards, due to sand exploitation. The resultant profiles provided a response model to guide the interpretation of new profiles acquired at other sites in the area, which present similar characteristics.The results showed the great importance of the dielectric permittivity contrast which exists between the targets and the host media, in order for possibly significant features to be identified in radar data. 相似文献
Geometric and kinematic analysis was performed in an area located in the central part of the Seridó Belt (NE Brazil), where supracrustal rocks affected by polyphase deformation are well exposed. The first event recognized in this area (and regionally known as the D2 deformation) is characterized by top to the south thrust tectonics while a second one (D3 deformation) is marked by upright folds, strike-slip or transpressive shear zones and the development of flower structures. Major pegmatite swarms were emplaced during and late as regards the second event (dated ca. 580 Ma), being part of the Brasiliano orogeny; similar dyke swarms are known from the Nigerian Shield. These pegmatite swarms provide reliable kinematic markers of the late evolutionary stage of the Neoproterozoic Trans-Sahara-Borborema collisional belt. Mineralogical, geometric and kinematic features support two stages of pegmatite emplacement during the strike-slip event: (i) older, syn-D3 homogeneous pegmatites intruded mostly along lithological and structural discontinuities, such as foliation surfaces; (ii) late, D3 heterogeneous pegmatites were emplaced along tension gashes and other dilation structures. The heterogeneous pegmatites are economically more important, being exploited for precious metals and stones, as well as industrial minerals. 相似文献
Previous research by our group (e.g., [Chem. Geol. 132 (1996) 25; Geochim. Cosmochim. Acta 64 (2000) 1363]) has shown that an aerobic Pseudomonas mendocina bacterium enhances Fe(hydr)oxide dissolution in order to obtain Fe under Fe-limited conditions. The P. mendocina is incapable of utilizing Fe as a terminal electron acceptor and requires several orders of magnitude lower Fe concentrations than do dissimilatory Fe reducing bacteria. The research reported here compared the effects of the P. mendocina on dissolution of well and poorly ordered Clay Minerals Society Source Clay kaolinites KGa-1b and KGa-2, respectively, under Fe-limited conditions. KGa-1b and KGa-2 contain 0.04 and 0.94 bulk wt.% Fe, respectively, and their surface Fe/Si atomic RATIOS=0.008 and 0.012. Following strong cleaning of the kaolinites in 5.8 M HCl at 85 °C, the surface Fe/Si atomic ratios decreased to 0.004 and 0.008, respectively. Both kaolinites also developed a Si-enriched surface precipitate upon strong cleaning.
Because the P. mendocina take up Fe, we could not measure Fe release from the kaolinite directly, but rather had to monitor it indirectly by comparing microbial populations sizes under Fe-limited growth conditions. We found that microbial growth on uncleaned, weakly cleaned, and strongly cleaned kaolinites increased with the amount of Fe readily available to organic ligands as estimated by dissolution in 0.001 M oxalate (pH 3). This suggests that it is the amount of readily accessible Fe that controls Fe acquisition and hence microbial growth. The trend is based on only a relatively small range of kaolinite Fe contents, and the research thus needs to be expanded to include kaolinites with a broader range of bulk and surface Fe concentrations.
Significant enhancement of Al release was observed in the presence of the bacteria, along with generally some enhancement of Si release. This enhancement of kaolinite dissolution could be related to an observed pH increase from 7–8 to 9 in the presence of the bacteria and/or to production of Al chelating agents. The P. mendocina produce a variety of organic exudates, including siderophores [Chem. Geol. 132 (1996) 25; Geomicrobiology (2001b)], and further studies into the effects of the siderophores on Al complexation and on kaolinite dissolution are ongoing. 相似文献
A comprehensive study of fine sediment transport in the macrotidal Seine estuary has been conducted, including observations of suspended particulate matter (SPM), surficial sediment, and bathymetric data, as well as use of a three dimensional mathematical model. Tide, river regime, wind, and wave forcings are accounted. The simulated turbidity maximum (TM) is described in terms of concentration and location according to tidal amplitude and the discharge of the Seine River. The TM is mainly generated by tidal pumping, but can be concentrated or stretched by the salinity front. The computed deposition patterns depend on the TM location and are seasonally dependent. The agreement with observations is reasonable, although resuspension by waves may be overestimated. Although wave resuspension is likely to increase the TM mass, it generally occurs simultaneously with westerly winds that induce a transverse circulation at the mouth of the estuary and then disperse the suspended material. The resulting effect is an output of material related to wind and wave events, more than to high river discharge. The mass of the computed TM remains stable over 6 months and independent of the river regime, depending mainly on the spring tide amplitude. Computed fluxes at different cross-sections of the lower estuary show the shift to the TM according to the river flow and point out the rapidity of the TM adjustment to any change of river discharge. The time for renewing the TM by riverine particles has been estimated to be one year. 相似文献
Late- to post-orogenic basins formed on both sides of the Pan-African – Brasiliano orogen when the Congo and Kalahari Cratons collided with the Rio de la Plata Craton during the formation of western Gondwana. Trace fossil evidence and radiometric age dating indicate that deposits on both sides are coeval and span the Cambrian–Precambrian boundary. A peripheral foreland basin, the Nama Basin, developed on the subducting southern African plate. Lower, craton-derived fluviomarine clastics are overlain by marine platform carbonates and deltaic flysch derived in part from the rising subduction complex along the northern (Damara Belt) and western (Gariep Belt) orogenic margins. Rare, thin volcanic ash layers (tuffs and cherts) are present. Upper sediments consist of unconformable red molasse related to collisional orogenesis. Orogenic loading from the north and west led to crustal flexure and the formation of a remnant ocean that drained to the south and closed progressively from north to south. During final collision SE-, E- and NE-verging nappes overrode the active basin margins. Although younger than most of the post-orogenic magmatism, its setting on the cratonic edge of the subducting plate precluded marked volcanism or granitic intrusion, the only exception being the youngest intrusions of the Kuboos-Bremen Suite dated at 521±6 Ma to 491±8 Ma. Two foreland-type basins, perhaps faulted remnants of a much larger NE–SW elongated retroarc foreland basin, are found west of the Dom Feliciano Belt on the edge of the Rio de la Plata Craton in southern Brazil. In the southern Camaqua Basin, basal fluvial deposits are followed by cyclical marine and coarsening-up deltaic deposits with a notable volcanic and volcaniclastic component. This lower deformed succession, comprising mainly red beds, contain stratabound Cu and Pb–Zn deposits and is overlain unconformably by a fluviodeltaic to aeolian succession of sandstones and conglomerates (with minor andesitic volcanics), derived primarily from an eastern orogenic source and showing southerly longitudinal transport. In the northern Itajaí Basin, sediments range from basal fluvial and platform sediments to fining-up submarine fan and turbidite deposits with intercalated acid tuffs. The Brazilian basins had faulted margins off which alluvial fans were shed. They also overlie parts of the Ribeira Belt. Thrust deformation along the orogenic margin bordering the Dom Feliciano Belt was directed westward in the Camaqua and Itajaí basins, but reactivated strike-slip and normal faults are also present. Late- to post-orogenic granitoids and volcanics of the Dom Feliciano Belt, ranging in age from 568±6 Ma to 529±4 Ma, occur in the foreland basins and are geochemically related to some of the synsedimentary volcanics. 相似文献
The scales on which phytoplankton biomass vary in response to variable nutrient inputs depend on the nutrient status of the plankton community and on the capacity of consumers to respond to increases in phytoplankton productivity. Overenrichment and associated declines in water quality occur when phytoplankton growth rate becomes nutrient-saturated, the production and consumption of phytoplankton biomass become uncoupled in time and space, and phytoplankton biomass becomes high and varies on scales longer than phytoplankton generation times. In Chesapeake Bay, phytoplankton growth rates appear to be limited by dissolved inorganic phosphorus (DIP) during spring when biomass reaches its annual maximum and by dissolved inorganic nitrogen (DIN) during summer when phytoplankton growth rates are highest. However, despite high inputs of DIN and dissolved silicate (DSi) relative to DIP (molar ratios of N∶P and Si∶P>100), seasonal accumulations of phytoplankton biomass within the salt-intruded-reach of the bay appear to be limited by riverine DIN supply while the magnitude of the spring diatom bloom is governed by DSi supply. Seasonal imbalances between biomass production and consumption lead to massive accumulations of phytoplankton biomass (often>1,000 mg Chl-a m?2) during spring, to spring-summer oxygen depletion (summer bottom water <20% saturation), and to exceptionally high levels of annual phytoplankton production (>400 g m?2 yr?1). Nitrogen-dependent seasonal accumulations of phytoplankton biomass and annual production occur as a consequence of differences in the rates and pathways of nitrogen and phosphorus cycling within the bay and underscore the importance of controlling nitrogen inputs to the mesohaline and lower reaches of the bay. 相似文献
East-northeastern Brazil has a wave-dominated, micro- to meso-tidal coast, lying entirely within the southern Atlantic trade wind belt. Integration of geologic mapping, radiocarbon dating and vibracoring data shows that the Quaternary coastal evolution of this area was controlled by three major factors: (1) sea-level history; (2) trade winds; and (3) climate change.
Sea-level history. Along the east-northeastern coast of Brazil, relative sea level has fallen approximately 5 m during the last 5000 y. Correlation of this sea-level history with the evolution of beach-ridge, lagoonal and coastal plain deposits shows that: (1) sea-level rise favours the formation of barrier island—lagoonal systems and the construction of intralagoonal deltas; (2) sea-level lowering is not conductive to barrier island formation. Rather, lagoons and bays become emergent and beach-ridge plains rapidly prograde.
Trade winds. Sediment dispersal systems along the coastal zone of east-northeastern Brazil have been highly persistent since Pleistocene time, as deduced from beach-ridge orientation. This persistence results from the fact that sediment dispersal in wave-dominated settings is ultimately controlled by atmospheric circulation which, for the east-northeastern coast of Brazil is associated with the South Atlantic high-pressure cell. The remarkable stability of this cell through time, has allowed the accumulation of extensive beach-ridge plains at the longshore drift sinks located along the coast.
Climate change. Effects of Quaternary climate changes on coastal sedimentation are twofold. Climate changes may affect rainfall patterns, thus exerting an important control on coastal dune development. Along the coast of northeastern Brazil, active coastal dunes are only present in those areas in which at least four consecutive dry months occur during the year. Mapping of these areas has shown that dune development during the Holocene has been episodic, these episodes being probably controlled by variations in rainfall patterns associated with climate changes. Secondly, despite its overall stability, the position of the high-pressure cell has experienced small shifts in position during the Holocene in response to climate changes. Changes in wind direction associated with these shifts have induced modifications in the coastal dispersion system, which are recorded in the strandplains as small truncations in the beach-ridge alignments.
These results have important implications in understanding accumulation of ancient sandstone shoreline sequences. 相似文献