Multi-cloud model (MCM) method and its applications to the study on asymmetric spectral profiles

A method of multi-cloud model (MCM) is proposed in this paper in order to research asymmetric profiles of spectral line formed by solar discrete active objects aligned along the line-of-sight difection. Based on the MCM method, under the conditions of certain assumptions and approximations, the line-of-sight velocityV and three other physical parameter approximation values, (i.e. Doppler width _D , source functionS and optical depth at line center ₀) within different clouds may be derived simultaneously by fitting both profiles theoretical and observational. An application example of the method withm=3 shows that MCM method is suitable to measure the velocity fields of multi-object at the same time from their non-Gaussian profiles of complex. TheV and _D derived from the method are reliable,S and ₀ are approximation. An influence of the variations of initial values in the parameter on the solution is given as well.     

RATIONAL UTILIZATION OF MOUNTAIN SOILS IN SOUTHEAST QINGHAI-XIZANG (TIBETAN)PLATEAU

ISoil-fo~gEnvironmentandMainSoilTrocsThesoLItheastQinghai-Xizang(Tibetan)PlateauwheretheHengduanMoUnains,eastempartoftheThmalayanandNyainqentanglhamoUnainsarelocatedextendsfrom25'to34"Nand92'to1O5'Ewithanareaof5OO,OOOkm',oraboutone-fiffooftheentireQinghai-XiZangPlateau.ItisatransitionalzoneofdeePdisseCtedmoUntainseXtendingsoutheastWardpenpherallowlandsandwichedin-betWeenSichuanBasinandcentralYunnanPlateau.Whletheterrainofthesmponinclinestosoutheast,thealtitudeofthevaIleysraises…     

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.     

热液脉动与岩浆涌动控制机理浅论

热液脉动与岩浆涌动的控制机理,是基础地质理论所涉及的两个重要议题。本文首先对当今流行的构造控制机理提出了质疑,其后借助＂间歇喷泉＂原理和＂吹气球＂机制,分别对热浪的脉动和岩浆的涌动进行了必要的探讨。     

热液成矿作用的地质地球化学动力学——以胶东牟平-乳山金矿带为例

通过对胶东牟平—乳山热液脉状金,铅锌矿床成矿动力学控制规律的研究,说明了建立热液成矿反应体系的方法,并得出以下认识:（1）区域断裂构造活动,通过影响成矿反应体系的热力学性质和条件,控制元素的富集和分散。（2）热液成矿过程中容矿断裂活动可划分为两种作用方式:脆性破裂和韧—脆性张开,构成热液成矿的两种构造动力学环境。（3）热液成矿反应体系是一种开放的动态的热力学体系。断裂的脆性破裂阶段,使体系处于强烈的过饱和状态,矿质在远离平衡状态下快速结晶,加剧物质分异;在脆—韧性张开阶段,矿质在接近平衡态体系中缓慢晶出。（4）热液演化晚期,金在残余溶液中富集;当断裂再次发生构造脉动震颤时,早期形成的块状黄铁矿矿石碎裂,富金溶液充填其中,形成含裂隙金和晶隙金的富矿石。成矿体系热力学演化与构造动力学条件有利的匹配控制着富矿石的形成。     

首都减灾圈的思考与建议

首都减灾圈,系首都减轻自然灾害预测防治圈。1991年12月20—21日在北京召开了《首都圈自然灾害及其减灾对策研讨会》。本文根据这次会议所提供的材料,在从整体上实现减灾的思想指导下,就首都减灾圈的“成灾背景”、“首都减灾圈的组成”、“首都减灾圈的灾害预测与防治状况”、“首都减灾圈的灾害关联性分析”、“首都减灾圈的减灾实效预估”和“首都减灾圈的减灾对策与实施”等六个带有共同性的问题,进行了讨论。供制定首都圈减灾方案时参考。     

重要找矿指示元素的野外快速分析法——金的野外快速分析

近年来,作者发展了七种以上重要找矿指示元素的野外快速分析法,此乃其一。文中提出一种新的金样冷浸技术,引进了新的光导光度检测方法,样品经溴化钠—硫酸—过氧化氢冷浸,用经丙酮—MIBK处理的泡沫塑料富集金,经混合解脱剂解脱并直接取解脱液用改进的微珠析出法或用光导光度法测定。取10g样品,可测定0.0005-50g/t范围内的金。方法简便、快速,可在普查分队驻地进行,每一工作日可测定80多个样品,由于废弃了王水分解样品和泡沫塑料的灰化,具有广阔的应用前景。     

地下水非稳定流的LTFAM算法

渗流域内应用拉普拉斯变换(LT)建立相应的有限分析(FAM)方程,顾及渗流域内地下水流的初始条件和边界条件,可在LT空间构成一个封闭的以水头像函数为变量的线性方程组。将此方程组所得的解,通过Stehfest数值反演公式,可归化为时间域的解(水头)。由于时间t被隐含在数值方程内,从而克服了传统数值法按时段(△t)逐步迭代的缺陷,提高了计算效率,也为用嵌入法建立地下水流管理模型提供了一条捷径。     

Intrinsic sample methods for mineral exploration and resource assessment

We report on an objective methodology, referred to as intrinsic sample methodology, for the delineation of exploration target areas or resource areas for assessment. Important features of the methodology include (1) identification of recognition criteria for critical genetic factors, (2) synthesis of new variables from enhanced geodata, (3) estimation of logit probability models, and (4) cutting of estimated logit probabilities to delineate exploration targets or resource areas. The methodology is demonstrated on the Walker Lake quadrangle of Nevada and California.     

流体在岩浆型铬铁矿和铂族元素成矿过程中的作用及意义

镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口，也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同：蛇绿岩以产出铬铁矿床为特征，阿拉斯加型岩体主要赋含铂族元素(PGE)矿床，大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关，但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程，而极少关注流体作用。近年来，实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用，同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为，刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素，已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题，总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录，提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用，强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。