Circulations east of Taiwan and in East China Sea and east of Ryukyu Islands during early summer 1985

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长江口拦门沙地区的泥沙运动规律

依据１９８８年７月和１２月水文观测资料，通过流，盐，沙的综合分析，认识到长江口拦门沙地区的泥沙运动有与河口其他地区不同的特点，泥沙输移在水平面上和垂直面上存在着多种循环，潮流和盐水截留大量泥沙积聚的拦门沙地区，河口在盐淡水交锋地带，除了涨，落急时段外，发现在转流时期泥沙也可能产生再悬浮，从而形成一个潮周期中出现３次或４次再悬浮的特殊规律。     

用新显色剂3-甲氧基-甲亚胺H光度测定海水中的硼

采用新试剂３－甲氧基－甲亚胺Ｈ测定海水中的硼，加入ＥＤＴＡ和酒石酸掩蔽各种干扰离子，不须分离可直接测定，方法简便、快速、准确。     

海水中液-固界面的台阶型动力学曲线 Ⅱ.液膜扩散-递进扩散-界面分级交换反应联合控制的复合模型理论

为定量解释海水中液-固界面的台阶型动力学曲线及其台阶的消长变化规律,在我们已提出的“液膜扩散和递进液膜扩散控制的复合模型”和“海水中液-固界面分级离子/配位子交换理论”基础上,吸取Crank的若干数学处理方法,进而提出适合于非稳态体系的“液膜扩散-递进扩散-界面分级交换反应联合控制的复合模型”。     

Dynamic Response Behaviors of Upright Breakwaters Under Breaking Wave Impact

- The dynamic response behaviors of upright breakwaters under broken wave impact are analysed based on the mass-damper-spring dynamic system model. The effects of the mass, damping, stiffness, natural period, and impulse duration (or oscillation period) on the translation, rotation, sliding force, overturning moment, and corresponding dynamic amplifying factors are studied. It is concluded that the ampli-ying factors only depend on the ratio of the system natural period to impulse duration (or oscillation period) under a certain damping ratio. Moreover, the equivalent static approach to breakwater design is also discussed.     

细基江蓠脂肪酸组成研究

研究表明,南海细基江蓠Gracilaria tenuistipitata中主要含有C_9—C_(30)一元饱和脂肪酸,其中n-十六酸含量占脂肪酸组分的40％以上。单烯和二烯酸的含量较低,缺乏多烯酸及前列腺素类化合物。此外,还含有少量二元酸类、4-及5-羰基羧酸,其中后两者是首次在红藻中发现。南海细基江蓠的脂肪酸组成特征与南海海域水质较清、光照充足及水温较高等环境因素有关。     

Vertical migration and mortality of benthos in dredged material: Part II—crustacea

Benthic invertebrates have many characteristics which make them prime candidates for burial studies in dredged material. A major concern in dredging and disposal projects is the effect of burial on the survival of benthic invertebrates. The purpose of the research reported in this paper was to determine the ability of estuarine benthos—in particular three species of molluscs (Mercenaria mercenaria, Nucula proxima and Ilyanassa obsoleta)—to migrate vertically in natural and exotic sediments and to determine the survival of benthos when exposed to particular amounts of simulated dredged material.Mortalities generally increased with increased sediment depth, with increased burial time and with overlying sediments whose particle size distribution differed from that of the species native sediment. Temperature affected mortalities and vertical migration. It was concluded that vertical migration is a viable process which can significantly affect rehabilitation of a dredged disposal area. Under certain conditions, vertical migration should be considered, together with larval settling and immigration from outside impacted areas, as a mechanism of recruiting a dredgedump site.     

耗散源函数及LAGFD-WAM海浪数值模式的改进

本文是在LAGFD-WAM海浪模式方法基础上,根据破碎波统计理论给出了LAGFD耗散源函数形式。同时对LAGFD-WAM模式进行了改进并与WAM模式作了三种典型风场下的对比实验和实测结果检验,取得了较好的结果。     

广西崇左三合巨猿大洞早更新世小哺乳动物群

最近在广西崇左三合大洞发现了步氏巨猿和似人似猿共生的新层位,与之伴生的有52种小哺乳动物,占三合大洞巨猿动物群总数的62%,其中苏门答腊兔（Nesolagus）是东南亚地区首次发现的化石。小哺乳动物群以南方早更新世常见的偏皮氏毛耳飞鼠（Belomys parapearsoni）、中间猪尾鼠（Typhlomys intermedius）、拟低冠竹鼠（Rhizomys brachyrhizomyoides）、硕豪猪（Hystrix magna）、先社鼠（Niviventer preconfucianus）、拟爱氏巨鼠（Leopoldamysedwardioidesi）等为代表,根据小哺乳动物群性质和与其他动物群对比以及磁性地层年代测定,表明其时代应是早更新世中期（约距今120¹60万年前）。该动物群由树鼩、扁颅蝠、小彩蝠、飞松鼠、笔尾树鼠、猪尾鼠等几乎是旧大陆热带-亚热带森林型动物组成,缺少北方类型,基本上属于热带森林动物群,这表明了当时的自然景观为温暖湿润的热带雨林环境。三合大洞小哺乳动物群是广西地区的首次发现,对华南早更新世巨猿动物群详细划分,探讨步氏巨猿演化和早期人类环境背景等目前科学界关注的问题具有重要的意义。     

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.