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221.
PAUL F. KARROW 《Boreas: An International Journal of Quaternary Research》1992,21(4):379-391
Till containing over 10% matrix carbonate extends in a belt 200–300 km wide south of the Hudson Bay Paleozoic basin source. The southern boundary is represented by the 'carbonate line', extending from Wawa to near Timmins and Cochrane in the study area. Higher silt content and lighter color are associated with the higher carbonate till. The carbonate tine corresponds approximately to the Chapleau moraine and correlative moraines to the northwest and may signify a discrete stratigraphic unit (possibly identifiable with the Matheson Till) formed by a glacial readvance. Glaciolacustrine sediments have higher carbonate content than nearby till and similarly form widespread sediment blankets even beyond that of the carbonate-rich till. Radiocarbon dating of amorphous organic sediments may be at risk because of old carbon error on such terrain and there may be some risk even in areas of much smaller carbonate content. A greater effort should be made to establish chronologies based on terrestrial plant matter, now more often possible with AMS radiocarbon dating. 相似文献
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Images can contain chemical information and many chemical methods can generate image data. For anefficient extraction of chemical data from images, data analysis techniques are necessary, It is a greatadvantage to be able to work on multivariate images. Many imaging techniques allow the extraction ofchemical information. Inorganic analytical chemistry seems to have the longest tradition here, butorganic chemistry and biochemistry may soon be catching up. Also large data arrays from non-imagingtechniques can be combined with image analysis in a useful way, provided certain conditions are fulfilled. 相似文献
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226.
PAUL BENJAMIN CRILLY 《地理学报(英文版)》1990,(4)
The use of a cross-correlation prefiltering technique to enhance the ability of Jansson's iterativedeconvolution procedure to deconvolve extremely noisy chromatographic data is investigated.Test casesinclude peaks whose resolutions are as low as 0.35 and whose signal-to-noise ratios are as low as 1:1.Evaluation criteria include RMS error,relative peak error and peak area repeatability.For comparisonpurposes,relative peak area errors and peak area variances are also evaluated for noisy but well resolvedpeaks that have only been prefiltered with the cross-correlation filter.Jansson's method in conjunctionwith cross-correlation prefiltering is shown not only to resolve overlapped peaks but in some cases toimprove their signal-to-noise ratios.The study also establishes some limits to the capabilities of Jansson'smethod will regard to adverse data conditions. 相似文献
227.
Pivoting analyses of the selective entrainment of sediments by shape and size with application to gravel threshold 总被引:1,自引:0,他引:1
Measured variations of pivoting angles with grain size, shape (‘reliability’ and angularity) and imbrication are employed in analyses of grain threshold to examine how these factors influence selective grain entrainment and sorting. With a bed of uniform grain sizes, as employed experimentally to establish the standard threshold curves such as that of Shields, the threshold condition depends on grain shape and fabric. The analysis demonstrates quantitatively that there should be a series of nearly-parallel threshold curves depending on grain pivoting angles. For a given grain size, the order of increasing flow strength required for entrainment is spheres, smooth ellipsoids (depending on their ‘reliability’), angular grains, and imbricated ellipsoids (depending on their imbrication angles). The relative threshold values for these different grain shapes and fabric are predicted according to their respective pivoting angles, but remain to be directly tested by actual threshold measurements. The pivoting angle of a grain also depends on the ratio of its size to those it rests upon. This dependence permits an evaluation of selective entrainment by size of grains from a bed of mixed sizes, the condition generally found in natural sediments. The pivoting model predicts systematic departures from the standard threshold curves for uniform grain sizes. Such departures have been found in recent studies of gravel threshold in rivers and offshore tidal currents. The pivoting model is compared with those threshold data with reasonable agreement. However, more controlled measurements are required for a satisfactory test of the model. It is concluded that variations in pivoting angles for grain entrainment are significant to the processes of selective sorting by grain size and shape. 相似文献
228.
PAUL D. KOMAR 《Sedimentology》1987,34(6):1165-1176
The concept of flow competence is generally employed to evaluate velocities and bed stresses of river floods from the sizes of the largest sediment particles transported. For the most part, this evaluation has been empirical, combining data from a number of separate flood events in different river systems. Those data are re-examined and compared with empirical equations for the selective entrainment of gravel from deposits of mixed sizes. It is found that the competence relationships trend counter to those obtained for selective entrainment, indicating that the competence evaluations are affected by varying degrees of selective size entrainment. Individual data sets which have been employed to establish the flow-competence relationships either show no trend on their own or yield a trend which runs counter to the competence equation, instead being more compatible with the selective-entrainment relationships. In most instances, the empirical competence equations greatly overestimate the hydraulics of flood flows, and it is suggested that the better established selective entrainment equations be used for competence evaluations as well. Empirical equations are available for this purpose, relating the dimensionless Shields entrainment function or the bed shear stress to the diameter of the largest grain moved and to the median diameter of the deposit as a whole. 相似文献
229.
REE and PGE Geochemical Constraints on the Formation of Dunites in the Luobusa Ophiolite, Southern Tibet 总被引:19,自引:0,他引:19
ZHOU MEI-FU; ROBINSON PAUL T.; MALPAS JOHN; EDWARDS STEPHEN J.; QI LIANG 《Journal of Petrology》2005,46(3):615-639
The Luobusa ophiolite, Southern Tibet, lies in the IndusYarlungZangbo suture zone that separates Eurasia to the north fromthe Indian continent to the south. The ophiolite contains awell-preserved mantle sequence consisting of harzburgite, clinopyroxene(cpx)-bearing harzburgite and dunite. The harzburgite containsabundant pods of chromitite, most of which have dunite envelopes,and the cpx-bearing harzburgites host numerous dunite dykes.Dunite also exists as a massive unit similar to those of themantlecrust transition zones in other ophiolites. Allof the dunites in the ophiolite have a similar mineralogy, comprisingmainly olivine with minor orthopyroxene and chromite and tracesof clinopyroxene. They also display similar chemical compositions,including U-shaped chondrite-normalized REE patterns. Mantle-normalizedPGE patterns show variable negative Pt anomalies. Detailed analysisof a chromite-bearing dunite dyke, which grades into the hostcpx-bearing harzburgite, indicates that LREE and Ir decrease,whereas HREE, Pd and Pt increase away from the dunite. Thesefeatures are consistent with formation of the dunite dykes byinteraction of MORB peridotites with boninitic melts from whichthe chromitites were formed. Because the transition-zone dunitesare mineralogically and chemically identical to those formedby such meltrock reaction, we infer that they are ofsimilar origin. The Luobusa ultramafic rocks originally formedas MORB-source upper mantle, which was subsequently trappedas part of a mantle wedge above a subduction zone. Hydrous meltsgenerated under the influence of the subducted slab at depthmigrated upward and reacted with the cpx-bearing harzburgitesto form the dunite dykes. The modified melts ponded in smallpockets higher in the section, where they produced podiformchromitites with dunite envelopes. At the top of the mantlesection, pervasive reaction between melts and harzburgite producedthe transition-zone dunites. KEY WORDS: meltrock interaction; REE; PGE; hydrous melt; mantle; ophiolite; Tibet 相似文献
230.
Noble Metal Enrichment Processes in the Merensky Reef, Bushveld Complex 总被引:14,自引:7,他引:14
We have analysed sulphides, silicates, and chromites of theMerensky Reef for platinum-group elements (PGEs), Re and Auusing laser ablation-inductively coupled plasma mass spectrometryand synthetic pyrrhotite standards annealed with known quantitiesof noble metals. Os, Ir and Ru reside in solid solution in pyrrhotiteand pentlandite, Rh and part of the Reefs Pd in pentlandite,whereas Pt, Au, Re and some Pd form discrete phases. Olivineand chromite, often suspected to carry Os, Ir and Ru, are PGEfree. All phases analysed contain noble metals as discrete micro-inclusionswith diameters typically <100 nm. Inclusions in sulphidescommonly have the element combinations OsIrPtand PtPdAu. Inclusions in olivine and chromiteare dominated by Pt ± AuPd. Few inclusion spectracan be related to discrete noble metal phases, and few inclusionshave formed by sub-solidus exsolution. Rather, some PGE inclusions,notably those in olivine and chromite, are early-magmatic nuggetstrapped when their host phases crystallized. We suggest thatthe silicate melt layer that preceded the Merensky Reef wasPGE oversaturated at early cumulus times. Experiments combinedwith available sulphidesilicate partition coefficientssuggest that a silicate melt in equilibrium with a sulphidemelt containing the PGE spectrum of the Merensky ore would indeedbe oversaturated with respect to the least soluble noble metals.Sulphide melt apparently played little role in enriching thenoble metals in the Merensky Reef; rather, its role was to immobilizea pre-existing in situ stratiform PGE anomaly in the liquid-stratifiedmagma chamber. KEY WORDS: Bushveld Complex; Merensky Reef; laser-ablation ICP-MS; platinum-group mineralization 相似文献