Trace elements in organic- and iron-rich surficial fluids of the boreal zone: Assessing colloidal forms via dialysis and ultrafiltration

On-site size fractionation of about 40 major and trace elements (TE) was performed on waters from boreal small rivers and their estuaries in the Karelia region of North-West Russia around the “Vetreny Belt” mountain range and in Paanajärvi National Park (Northern Karelia). Samples were filtered in the field using a progressively decreasing pore size (5 μm, 2.5 (3) μm, 0.22 (0.45) μm, 100 kDa, 10 and 1 kDa) by means of frontal filtration and ultrafiltration (UF) techniques and employing in-situ dialysis with 10 and 1 kDa membranes followed by ICP-MS analysis. For most samples, dialysis yields a systematically higher (factor of 2-3) proportion of colloidal forms compared to UF. Nevertheless, dialysis is able to provide a fast and artefact-free in-situ separation of colloidal and dissolved components.Similar to previous studies in European subarctic zones, poor correlation of iron concentration with that of organic carbon (OC) in (ultra)filtrates and dialysates reflect the presence of two pools of colloids composed of organic-rich and Fe-rich particles. All major anions and silica are present as dissolved species (or solutes) passing through the 1-kDa membrane. Size-separation ultrafiltration experiments show the existence of larger or smaller pools of colloidal particles different for each of the considered elements.The effect of rock lithology (acidic versus basic) on the colloidal speciation of TE is seen solely in the increase of Fe and some accompanying TE concentrations in catchment areas dominated by basic rocks compared to granitic catchments. Neither the ultrafiltration pattern nor the relative proportions of colloidal versus truly dissolved TE are affected by the lithology of the underlying rocks: within ±10% uncertainty, the two colloidal (10 kDa-0.22 μm and 1-10 kDa) and the truly dissolved (<1 kDa) pools show no difference in percentage of TE distribution between two types of bedrock lithology. The same conclusion is held for organic- and Fe-rich waters. In contrast, landscape context analysis demonstrated slight dominance, for most TE affected by UF, of large-size colloids (10 kDa-0.22 μm) in rivers and streams and small-size colloids and truly dissolved fractions in swamp stagnant surface waters. This supports the existence of two pathways of colloids formation: during the plant litter degradation in wetland zones and at the redox front in river riparian zone.     

The variability of the large-amplitude internal wave field on the Australian North West Shelf

Observations are presented of large-amplitude internal waves (LAIWs) generated by the steepening of the internal tide on the Australian North West Shelf (NWS) over a 4-month period extending from strongly stratified summer conditions to weakly stratified winter conditions. The observations are from a site in water depth of 124 m where current and temperature measurements were made from a fixed vertical mooring and a benthic L-shaped spatial array. The observations show the LAIWs at this site to be characterized by strong seasonal variability, with energetic LAIWs of depression being dominant during summer and weaker LAIWs of elevation being dominant during the winter months as the stratification weakens, the upper mixed layer deepens, and the thermocline is close to the bottom. Waves were also seen to propagate from a range of directions towards the observation site. Modeling using the Regional Ocean Modeling System (ROMS v2.1) revealed that internal tide generation in the area occurred at water depths of between 400 and 600 m along an arc of approximately 120 km in length, some 70 km to the northwest of our experimental site. The results demonstrate both the 3D nature as well as the seasonal variation of the LAIW field.     

Sediment budget of the Napo River,Amazon basin,Ecuador and Peru

The upstream‐downstream sediment budget along the Napo River (100 520 km², 6300 m³ s^?1) was studied in the Andean foothills of Ecuador, at the west of the Amazon basin. A comparative study was made during four hydrological cycles (2001–2005) for three hydrological stations located upstream, and during one hydrological cycle (2004–2005) for the fourth one located near the mouth of the Napo River (region of Iquitos in Peru). This analysis showed an unusual increase in the concentration of suspended sediment recorded for the western part of the Amazon plain. Like the runoff (81 l s^?1 km²), which is a world's maximum, the erosion rate (1160 t km^?2 year^?1, i.e. 47% of total suspended solid (TSS) export at the exit of Ecuador), one of the highest for a floodplain basin is the result of a stepper slope than in the rest of the Andean foothills, where typically sedimentation phenomena are predominant, and can be explained in part by a greater tectonic activity. Similar phenomenes were evidenced in small mountainous rivers in New Guinea (Milliman and Syvitski, 1992; Milliman, 1995). On the headwaters of the Napo River drainage basin, the tectonic uplift causes the Pastaza Megafan's existence. This progressively diverts the course of Napo River towards north and also provokes the remobilization of fine fluvial deposits. Moreover, this geodynamic trend is completed by the impact of volcanic eruption, earthquakes and landslides. The combination of these phenomena, so common in the region, has provided a large sediment transfer, not only at present but also in the past, as can be confirmed by the presence of incised terraces, mainly formed by volcanic materials. Then, these results were compared with a similar study carried out further south in the Madeira basin at the Bolivian foothills. These studies show the spatio‐temporal variability of the relation between sediment transfer and geodynamic processes at the Andean Piedmont. Copyright © 2009 John Wiley & Sons, Ltd.     

Exploring seven hundred years of transhumance,climate dynamic,fire and human activity through a historical mountain pass in central Spain

A high-altitude peat sequence from the heart of the Spanish Central System (Gredos range) was analysed through a multi-proxy approach to determine the sensitivity of high-mountain habitats to climate, fire and land use changes during the last seven hundred years, providing valuable insight into our understanding of the vegetation history and environmental changes in a mountain pass close to a traditional route of transhumance. The pollen data indicate that the vegetation was dominated by shrublands and grasslands with scattered pines in high-mountain areas, while in the valleys cereals, chestnut and olive trees were cultivated. Strong declines of high-mountain pines percentages are recorded at 1540, 1675, 1765, 1835 and 1925 cal AD, which may be related to increasing grazing activities and/or the occurrence of anthropogenic fires. The practice of mountain summer farming and transhumance deeply changed and redesigned the landscape of the high altitudes in central Spain (Gredos range) since the Middle Ages, although its dynamics was influenced in some way by climate variability of the past seven centuries.     

Hydro-hypsometric analysis of tropical river basins,Southwest Coast of India using geospatial technology

The key aspect in planning and management of water resources is to analyze the runoff potential and erosion status of the river basin. For the detailed investigation of hydrological response, freely available Cartosat-1 (IRS-P5) data was used for the preparation of digital elevation model (DEM). The runoff potential and type of erosive process of 22 river basins originating in the global biodiversity hotspot of Western Ghats, was inferred through hypsometric analysis. Several parameters like Hypsometric integral (HI), maximum concavity (Eh), coordinates of slope inflection point (I) given by a* and h* and normalized height of hypsometric curve (h) were extracted from the hypsometric curves and used for understanding the hydrological responses. From the hypsometric curves, the landform evolution processes were inferred. Contribution of diffusive and fluvial processes in slope degradation of the river basins was understood. Basins with lesser area (<100 km²) were found to have a positive correlation between hypsometric integral and basin area, whereas for large basins no such correlation exists. Based on the study, river basins can be prioritized for the appropriate conservation measures.     

Complementary Notes on a ‘Well-known’ Marine Heterotrichous Ciliate, Folliculinopsis producta (Wright, 1859) Frauré-Fremiet, 1936 (Protozoa, Ciliophora)

1　Introduction　Folliculina likeciliatesarecommonlyfoundinlit toralzonesandareeasilyrecognizedbytheirlargesi zesandspecialstructures (i.e.vase shapedloricaandperistomiallobe) .Tillnow ,dozensofspecieshavebeenreportedworldwide (Kahl,1 932 ;Faur啨Fremiet,1…     

Variations in stratigraphic and reservoir properties adjacent to the Mid-Paleocene sequence boundary, Campo section, Pyrenees, Spain

The Paleocene of the Campo section, Spain has different sedimentological characteristics above and below the Mid-Paleocene Unconformity. Beneath the unconformity sediments are dominated by evaporitic carbonates and collapse breccias. Above it they are characterized by continental detrital beds alternating with paleosols. Different subaerial features are observed and correspond to different porosity values, pore–throat sizes and micrite morphologies. Unexposed or intertidal facies have low porosity, low throat–pore size (mesoporosity) and well preserved rhombic crystals. Intermediate exposed facies (paleosols) possess medium porosity, medium pore–throat size (microporosity) and mainly micro-rhombic crystals. Finally, the facies corresponding to high exposure intensity and to evaporitic original facies presents high porosity, permeability, large pore–throat size and rounded micritic crystals. These observations show that the emersion phase caused important dissolution, especially when associated with an easily dissolved original lithofacies.     

Spatial Variability of Mass Movements in the Satluj Valley,Himachal Pradesh during 1990～2006

Satluj Valley is known to have a history of landslides and related mass movement activities since the geological times. Geological and geomorphological settings combined with anthropogenic activities constitute a propensity towards slope failure. During the last two decades,the area witnessed substantial increase in athropogenic pressure,mainly due to the exploitation of hydropower potential,changing landuse pattern and population growth. In addition,a shift of the climatic patterns in the form of larger area falling under the influence of rains was observed. These natural as well as anthropogenic changes in the area have resulted in increased spatial coverage of landslide in the area. This paper documents these changes during 1990～2006.     

Petrography and mineral chemistry of neovolcanics occurring between Pacific and Nazca Plate boundaries

Mid-Oceanic Ridge Basalt (MORB) samples collected from southern East Pacific Rise (SEPR) have been investigated. These highly phyric plagioclase basalts (HPPB) and moderately phyric plagioclase basalts (MOPB) show rare cumulate and vitrophyric textures with plagioclase (>10% as phenocryst) and abundant glass (>72%). Electron Probe Micro Analysis (EPMA) showed large compositional variations in the megacrysts as well as microcrysts of plagioclase (An₆₂ to An₈₂), olivine (Fo₇₈ to Fo₈₇), pyroxene (ferroaugite to augite) and iron oxides, mostly titaniferous magnetite. Olivine grains show high Mg# (>80%) and distinctly low in NiO (0.01–0.2%). Ferroan trevorite (NiO =16.22 and FeO_(t) =83.06) a characteristic meteoritic mineral has been identified from the olivine megacrysts of MORB, possibly attributed to Ni-enrichment, resulted from heterogeneity of the lower mantle. Wide range of An composition in plagioclase is indicative of large pressure range of crystal nucleation under decompression at a depth of ∼70 km (An₈₂) up to the ocean spreading centre. Absence of zoning observed in all the minerals present in the MORB samples, possibly attributed to unmixing and dominant fractionation process.