Crystal chemistry of selenates with mineral-like structures: V. Crystal structures of (H3O)2[(UO2)(SeO4)2(H2O)](H2O)2 and (H3O)2[(UO2)(SeO4)2(H2O)](H2O), new compounds with rhomboclase and goldichite topology

The crystal structures of two new compounds (H₃O)₂[(UO₂)(SeO₄)₂(H₂O)](H₂O)₂ (1, orthorhombic, Pnma, a = 14.0328(18), b = 11.6412(13), c = 8.2146(13) Å, V = 134.9(3) ų) and (H₃O)₂[(UO₂)(SeO₄)₂(H₂O)](H₂O) (2, monoclinic, P2₁/c, a = 7.8670(12), b = 7.5357(7), c = 21.386(3) Å, β = 101.484(12)°, V = 1242.5(3) ų) have been solved by direct methods and refined to R ₁ = 0.076 and 0.080, respectively. The structures of both compounds contain sheet complexes [(UO₂)(SeO₄)₂]^2? formed by cornershared [(UO₂)O₄(H₂O)] bipyramids and SeO₄ tetrahedrons. The sheets are parallel to the (100) plane in structure 1 and to (?102) in structure 2. The [(UO₂)(SeO₄)₂(H₂O)]^2? layers are linked by hydrogen bonds via interlayer groups H₂O and H₃O⁺. The sheet topologies in structures 1 and 2 are different and correspond to the topologies of octahedral and tetrahedral complexes in rhomboclase (H₂O₂)⁺[Fe(SO₄)₂(H₂O)₂] and goldichite K[Fe(SO₄)₂(H₂O)₂](H₂O)₂, respectively.     

The population of cosmic voids

We consider the main population of cosmic voids in a heirarchical clustering model. Based on the Press-Schechter formalism modified for regions in the Universe with reduced or enhanced matter densities, we construct the mass functions for gravitationally bound objects of dark matter occupying voids or superclusters. We show that the halo mass functions in voids and superclusters differ substantially. In particular, the spatial density of massive (M ～ 10¹² M _⊙) halos is appreciably lower in voids than in superclusters, with the difference in the mass functions being greater for larger masses. According to our computations, an appreciable fraction of the mass of matter in voids should be preserved to the present epoch in the form of primordial gravitationally bound objects (POs) with modest masses (to 10% for M _PO < 10⁹ M _⊙) keeping baryons. These primordial objects represent “primary blocks” in the heirarchical clustering model. We argue that the oldest globular clusters in the central regions of massive galaxies are the stellar remnants of these primordial objects: they can form in molecular clouds in these objects, only later being captured in the central regions of massive galaxies in the process of gravitational clustering. Primordial objects in voids can be observed as weak dwarf galaxies or Lyα absorption systems.     

The development and structure of bright active regions at 2.8 cm

The development of three intense active centers during their appearance on the solar disk is examined using high resolution observations at 2.8 cm. Each region shows a very bright component with brightness temperature > 10⁶ K and size smaller than 20.The development of the bright components have been investigated on different time scales. Intensity fluctuations on a time scale of minutes are within the instrumental accuracy while the evolution over periods of days shows a variation of the flux density up to 30–40% per day.The problem of the bright cores height is discussed. Heights within 10 × 10³ and 40 × 10³ km are found using their apparent displacement on the disk.     

On the motion around the centre of mass of a viscously elastic sphere in the restricted elliptic three-body problem

In the restricted three-body problem we consider the motion of a viscously elastic sphere (planet) with its centre of mass moving in a conditionally-periodic orbit. The approximate equations describing the rotational motion of the sphere in terms of the Andoyer variables are obtained by the method of the separation of motion and averaging; the evolution of the motion is also analysed.     

RAGLAND,AN LL3.4 CHONDRITE FIND FROM NEW MEXICO

The Ragland, New Mexico chondrite was found in 1978, and consists of a single stone of 12.16 kg that broke into three pieces. The stone is moderately weathered and has a pronounced chondritic texture. Bulk composition favors an LL classification, and modal analysis and oxygen isotopic composition are consistent with this. The thermoluminescence sensitivity of 0.056 ± 0.020 normalized to Dhajala, compositional variability of olivine (mean Fa 18.3, σ = 10.1) and low-Ca pyroxene (mean Fs 14.6, σ = 6.7), and Ca concentrations in olivine indicate metamorphic subtype 3.4 ± 0.1. The isotopically heavy oxygen composition, which is characteristic of subtypes 3.0–3.1, may be a primary characteristic and not a result of weathering. Low concentrations of radiogenic ⁴⁰Ar and planetary ³⁶Ar suggest noble gas loss.     

New insights on the QSO radio-loud/radio-quiet dichotomy: SDSS spectra in the context of the 4D eigenvector1 parameter space

We search for a dichotomy/bimodality between radio-loud (RL) and radio-quiet (RQ) type 1 active galactic nuclei (AGN). We examine several samples of Slogan Digital Sky Survey (SDSS) quasi-stellar objects (QSOs) with high signal-to-noise ratio optical spectra and matching Faint Images of the Radio Sky at Twenty-cm/NRAO VLA Sky Survey (FIRST/NVSS) radio observations. We use the radio data to identify the weakest RL sources with a Fanaroff–Riley type II (FR II) structure to define a RL/RQ boundary which corresponds to log   L _1.4 GHz= 31.6  erg s⁻¹ Hz⁻¹. We measure the properties of broad-line Hβ and Fe  ii emission to define the optical plane of a 4DE1 spectroscopic diagnostic space. The RL quasars occupy a much more restricted domain in this optical plane compared to the RQ sources, which a 2D Kolmogorov–Smirnov test finds to be highly significant. This tells us that the range of broad-line region kinematics and structure for RL sources is more restricted than for the RQ QSOs, which supports the notion of dichotomy. FR II and CD RL sources also show significant 4DE1 domain differences that likely reflect differences in line-of-sight orientation (inclined versus face-on, respectively) for these two classes. The possibility of a distinct radio-intermediate (RI) population between RQ and RL source is disfavoured because a 4DE1 diagnostic space comparison shows no difference between RI and RQ sources. We show that searches for dichotomy in radio versus bolometric luminosity diagrams will yield ambiguous results mainly because in a reasonably complete sample, the radio brightest RQ sources will be numerous enough to blur the gap between RQ and RL sources. Within resolution constraints of NVSS and FIRST, we find no FR I sources among the broad-line quasar population.     

Detection of a star escaping from the Orion Trapezium

During studies of spectra of the star Θ¹ Ori C with high photometric and spectral resolution we have discovered a system of spectral lines indicating a large negative radial velocity (RV). We designate this star as Θ¹ Ori C3.     

Boltysh,another end‐Cretaceous impact

Abstract— The Chixculub impact occurred at the Cretaceous/Tertiary (K/T) boundary, and although several other Late Cretaceous and Paleogene impact craters have, at times, been linked with the K/T boundary, isotope geochronology has demonstrated that all have significantly different ages. The currently accepted age of the 24 km diameter Boltysh crater, a K‐Ar whole‐rock age, places it in the Coniacian at 88 ± 3 Ma. However, comprehensive Ar‐Ar dating of a range of melt samples yields a mean age of 65.17 ± 0.64 Ma, within errors of the K/T boundary. Several of the fresh samples exhibit signs of excess argon but this seems to be concentrated in rapidly crystallized glass‐rich samples. The Ar‐Ar age confirms an earlier fission track measurement and thus two dating techniques have yielded an age within errors of the K/T boundary for this crater. Crucially, although the ages of Boltysh and Chixculub are within errors, they may not have formed synchronously. Craters of 24 km diameter occur much more commonly than impacts of Chixculub dimensions, but their proximity does raise the important question of how many impacts there might have been close to the K/T boundary.     

Crash-testing the cauldron code for joint lensing and dynamics analysis of early-type galaxies

We apply the joint lensing and dynamics code for the analysis of early-type galaxies, 'Combined Algorithm for Unified Lensing and Dynamics ReconstructiON ( cauldron )', to a rotating N -body stellar system with dark matter halo which significantly violates the two major assumptions of the method, i.e. axial symmetry supported by a two-integral distribution function. The goal is to study how cauldron performs in an extreme case, and to determine which galaxy properties can still be robustly recovered. Three data sets, corresponding to orthogonal lines of sight, are generated from the N -body system and analysed with the identical procedure followed in the study of real lens galaxies, adopting an axisymmetric power-law total density distribution. We find that several global properties of the N -body system are recovered with remarkable accuracy, despite the fact that the adopted power-law model is too simple to account for the lack of symmetry of the true density distribution. In particular, the logarithmic slope of the total density distribution is robustly recovered to within less than 10 per cent (with the exception of the ill-constrained very inner regions), the inferred angle-averaged radial profile of the total mass closely follows the true distribution, and the dark matter fraction of the system (inside the effective radius) is correctly determined within ∼10 per cent of the total mass. Unless the line-of-sight direction is almost parallel to the total angular momentum vector of the system, reliably recovered quantities also include the angular momentum, the   V /σ  ratio and the anisotropy parameter δ. We conclude that the cauldron code can be safely and effectively applied to real early-type lens galaxies, also providing reliable information for the systems that depart significantly from the method's assumptions.