Policies and Practices for an Antiracist Geography at the Millennium

As we enter the new millennium, geographers have a momentous opportunity to reflect upon the historical development of our discipline and the academic culture within which it thrives, with the aim of setting out an antiracist agenda. We advocate a fundamental refashioning of the discipline, not simply an extension of its research agenda; for racism, like gender, is not just another item in the lexicon of geographical subjects. The agenda includes, but is not limited to: clarifying relations between racism and law; racism and immigration policy; racism and poverty; and mobilizing racialized groups around policy issues. These items need to be addressed both through scholarship and through activism, as centering geographical practices in the streets rather than in the academy impels not only more effective social change, but also new theoretical understanding of geographies of engagement. Our agenda for antiracist geography also involves three aspects of institutional change: to build up on and extend traditional geographical scholarship; to change the basis of the discipline by extending the principles of antiracism throughout our institutional practices, particularly in the classroom; and to change the face of the discipline by increasing the participation and contributions of geographers of color.     

Fluctuation in proteinaceous labile organic matter verified with degradation rate constants of terrestrial biochemical indicators

Biogenic amino acids, taken as representative of organic matter, were analyzed to determine the apparent degradation rate constant in boreal terrestrial sediment. Age determination using ¹⁴C dating gave two rate constants: the initial degradation rate constant for glycine (k_{GLY 1}), the simplest amino acid, was 1.5 × 10⁻³ yr⁻¹ (r = 0.97) until about 2200 yr BP. After the inflection point, the rate constant k_{GLY 2} was 9.1 × 10⁻⁵ yr⁻¹ (r = 0.73). The degradation of amino acids in the labile organic matter in the sediment was markedly affected by rapid processes. After the inflection point, the rate constant profiles for sub-surface amino acids were shown to have discontinuous relationships with sediment age. One pattern which emerged in the vertical distribution is that the biogenic amino acid degradation rate constant k was far greater in the labile organic matter phase than that in the refractory organic matter over the past 10,000 years.     

Luminescence spectra of chabazite-Ca,a zeolite mineral

Chabazite-Ca deposited on dacite laccolith from Osódi Hill, Dunabogdány, Hungary, exhibited bluish-white luminescence under ultraviolet (UV) light. The photoluminescence (PL) and optical excitation spectra of chabazite-Ca were obtained at 300 K. The PL spectrum under 300-nm excitation consists of (1) a Ce³⁺ band with a peak at 340 nm, (2) a broad main band with a peak at 453 nm and (3) five narrow bands at 592, 616, 650, 700 and 734 nm due to Eu³⁺. The main band is spread over the entire visible-wavelength region. The excitation spectrum obtained by monitoring green luminescence at 520 nm consists of a band at wavelengths shorter than 200 nm and an extremely broad band with a peak at 385 nm. The extremely broad band is spread over not only the UV region but also the blue region. The features of PL and excitation spectra suggest that the origin of bluish-white luminescence is luminescent organic matter incorporated into chabazite-Ca crystals during growth.     

Boron cycling by subducted lithosphere; insights from diamondiferous tourmaline from the Kokchetav ultrahigh-pressure metamorphic belt

Subduction of lithosphere, involving surficial materials, into the deep mantle is fundamental to the chemical evolution of the Earth. However, the chemical evolution of the lithosphere during subduction to depth remains equivocal. In order to identify materials subjected to geological processes near the surface and at depths in subduction zones, we examined B and Li isotopes behavior in a unique diamondiferous, K-rich tourmaline (K-tourmaline) from the Kokchetav ultrahigh-pressure metamorphic belt. The K-tourmaline, which includes microdiamonds in its core, is enriched in ¹¹B relative to ¹⁰B (δ¹¹B = −1.2 to +7.7) and ⁷Li relative to ⁶Li (δ⁷Li = −1.1 to +3.1). It is suggested that the K-tourmaline crystallized at high-pressure in the diamond stability field from a silicate melt generated at high-pressure and temperature conditions of the Kokchetav peak metamorphism. The heavy isotope signature of this K-tourmaline differs from that of ordinary Na-tourmalines in crustal rocks, enriched in the light B isotope (δ¹¹B = −16.6 to −2.3), which experienced isotope fractionation through metamorphic dehydration reactions. A possible source of the heavy B-isotope signature is serpentine in the subducted lithospheric mantle. Serpentinization of the lithospheric mantle, with enrichment of heavy B-isotope, can be produced by normal faulting at trench-outer rise or trench slope regions, followed by penetration of seawater into the lithospheric mantle. Serpentine breakdown in the lithospheric mantle subducted in subarc regions likely provided fluids with the heavy B-isotope signature, which was acquired during the serpentinization prior to subduction. The fluids could ascend and cause partial melting of the overlying crustal layer, and the resultant silicate melt could inherit the heavy B-isotope signature. The subducting lithospheric mantle is a key repository for modeling the flux of fluids and associated elements acquired at a near the surface into the deep mantle.     

Vortex structures around a hemispheric hump

The vortex structure formed in front of and behind a hemispheric surface hump has been studied in a water recirculating flume. In the recirculation zone behind the hemisphere, arched vortex tubes were formed. Up to a certain critical Reynolds number, each tube was shed individually from the recirculation zone. However, when the Reynolds number exceeded a critical value, several of the tubes coalesced in the recirculation zone before shedding. In front of the hemisphere, some parabolic vortex tubes formed. Their number increased with Reynolds number below its critical value and decreased above this value. The dimensionless height of the parabolic vortex tube decreased with Reynolds number.     

Effects of new antifouling compounds on the development of sea urchin

Tributyltin oxide (TBTO) has been used worldwide in marine antifouling paints as a biocide for some time. However, it produced toxic effects, especially in marine water/sediment ecosystems. Consequently, its use in antifouling paints has been prohibited in many countries. In this study, the toxicity of alternative and/or new antifouling biocides compared with TBTO is assessed by a biological method. The effects of these chemicals on marine species have not been well studied. This paper assesses, comparatively, the effects of eight biocides on sea urchin eggs and embryos. The chemicals assessed were TBTO, Irgarol 1051, M1 (the persistent degradation product of Irgarol), Diuron, zinc pyrithione, 'KH101', 'Sea-Nine 211', and copper pyrithione. For these chemicals, toxicity appears to be in the order zinc pyrithione > Sea-Nine 211 > KH101 > copper pyrithione > TBTO > Diuron approximately = Irgarol 1051 > M1. Here, we show that zinc pyrithione, Sea-Nine 211, KH101, and copper pyrithione are much more toxic to sea urchins than TBTO or the other chemicals.     

Dust ring formation due to ice sublimation of radially drifting dust particles under the Poynting-Robertson effect in debris disks

In a disk with a low optical depth, dust particles drift radially inward by the Poynting-Robertson (P-R) drag rather than are blown out by stellar radiation pressure following destructive collisions. We investigate the radial distribution of icy dust composed of pure ice and refractory materials in dust-debris disks taking into account the P-R drag and ice sublimation. We find that icy dust particles form a dust ring by their pile-ups at the edge of their sublimation zone, where they sublime substantially at the temperature 100-110 K. The distance of the dust ring is 20-35 AU from the central star with its luminosity L_??30L_⊙ and 65(L_?/100L_⊙)^1/2 AU for L_??30L_⊙, where L_⊙ is the solar luminosity. The effective optical depth is enhanced by a factor of 2 for L_??100L_⊙ and more than 10 for L_??100L_⊙. The optical depth of the outer icy dust disk exceeds that of the inner disk filled with refractory particles, namely, the residue of ice sublimation, which are further subjected to the P-R effect. As a result, an inner hole is formed inside the sublimation zone together with a dust ring along the outer edge of the hole.     

The 10 ka multiple vent pyroclastic eruption sequence at Tongariro Volcanic Centre, Taupo Volcanic Zone, New Zealand: Part 2. Petrological insights into magma storage and transport during regional extension

The six eruption episodes of the 10 ka Pahoka–Mangamate (PM) sequence (see companion paper) occurred over a ?200–400-year period from a 15-km-long zone of multiple vents within the Tongariro Volcanic Centre (TgVC), located at the southern end of the Taupo Volcanic Zone (TVZ). Most TgVC eruptives are plagioclase-dominant pyroxene andesites and dacites, with strongly porphyritic textures indicating their derivation from magmas that ascended slowly and stagnated at shallow depths. In contrast, the PM pyroclastic eruptives show petrographic features (presence of phenocrystic and groundmass hornblende, and the coexistence of olivine and augite without plagioclase during crystallisation of phenocrysts and microphenocrysts) which suggest that their crystallisation occurred at depth. Depths exceeding 8 km are indicated for the dacitic magmas, and >20 km for the andesitic and basaltic andesitic magmas. Other petrographic features (aphyric nature, lack of reaction rims around hornblende, and the common occurrence of skeletal microphenocrystic to groundmass olivine in the andesites and basaltic andesites) suggest the PM magmas ascended rapidly immediately prior to their eruption, without any significant stagnation at shallow depths in the crust. The PM eruptives show three distinct linear trends in many oxide–oxide diagrams, suggesting geochemical division of the six episodes into three chronologically-sequential groups, early, middle and late. Disequilibrium features on a variety of scales (banded pumice, heterogeneous glassy matrix and presence of reversely zoned phenocrysts) suggest that each group contains the mixing products of two end-member magmas. Both of these end-member magmas are clearly different in each of the three groups, showing that the PM magma system was completely renewed at least three times during the eruption sequence. Minor compositional diversity within the eruptives of each group also allows the PM magmas to be distinguished in terms of their source vents. Because petrography suggests that the PM magmas did not stagnate at shallow levels during their ascent, the minor diversity in magmas from different vents indicates that magmas ascended from depth through separate conduits/dikes to erupt at different vents either simultaneously or sequentially. These unique modes of magma transport and eruption support the inferred simultaneous or sequential tapping of small separate magma bodies by regional rifting in the southern Taupo Volcanic Zone during the PM eruption sequence (see companion paper).