Dissolved organic nitrogen dynamics in the North Sea: A time series analysis (1995–2005)

Dissolved organic nitrogen (DON) dynamics in the North Sea was explored by means of long-term time series of nitrogen parameters from the Dutch national monitoring program. Generally, the data quality was good with little missing data points. Different imputation methods were used to verify the robustness of the patterns against these missing data. No long-term trends in DON concentrations were found over the sampling period (1995–2005). Inter-annual variability in the different time series showed both common and station-specific behavior. The stations could be divided into two regions, based on absolute concentrations and the dominant times scales of variability. Average DON concentrations were 11 μmol l⁻¹ in the coastal region and 5 μmol l⁻¹ in the open sea. Organic fractions of total dissolved nitrogen (TDN) averaged 38 and 71% in the coastal zone and open sea, respectively, but increased over time due to decreasing dissolved inorganic nitrogen (DIN) concentrations. In both regions intra-annual variability dominated over inter-annual variability, but DON variation in the open sea was markedly shifted towards shorter time scales relative to coastal stations. In the coastal zone a consistent seasonal DON cycle existed with high values in spring–summer and low values in autumn–winter. In the open sea seasonality was weak. A marked shift in the seasonality was found at the Dogger Bank, with DON accumulation towards summer and low values in winter prior to 1999, and accumulation in spring and decline throughout summer after 1999. This study clearly shows that DON is a dynamic actor in the North Sea and should be monitored systematically to enable us to understand fully the functioning of this ecosystem.     

Marine protected areas—substantiating their worth

With the UK Marine Bill promoting the creation of a network of marine protected areas and similar commitments in other countries there is a need for tools to assist in their design and management. Although physical science often drives designation, the implementation of marine protected areas also encompasses political and socio-economic issues. This paper focuses on one tool in the armoury of decision-makers: choice experiments. It illustrates its application to the quantification of aspects of socio-economic value not readily incorporated into the evaluation of the costs and benefits of marine protected areas utilising cold-water deep coral reefs off the Republic of Ireland.     

Experimental investigation of water impact on axisymmetric bodies

The results of an elaborate experimental investigation on bottom slamming of axisymmetric objects are presented. Drop tests have been performed on a hemisphere and two conical shapes with different deadrise angles. The test setup is designed so as to prevent small rotations of the test objects which cause scatter in the measurement data. The pressure distribution and evolution as well as the body motion parameters are measured during impact. By means of a high speed camera the water uprise is visualized and the wetting factor is determined for the cones. The results are compared with a three-dimensional asymptotic theory for axisymmetric rigid bodies with constant entry velocity. The ratio between the registered peak pressures and the asymptotic theory are in accordance with comparable experiments in the literature. The asymptotic theory, however, is found to be quite conservative, since the measured peak pressure levels appear to be approximately 50% to 75% of the theoretical levels.     

High-resolution record of tectonic and sedimentary processes in growth strata

Growth strata are used to determine the kinematics of synsedimentary structures such as faults. Classical methods of analysis such as thickness versus throw plot consider that the available space created by fault slip in the hanging wall of faults is instantaneously filled up by sediments. This has lead many previous works to identify a cyclic activity for growth faults. Here we perform a careful analysis of the variation of strata thicknesses on each side of a very well documented normal growth fault in the Niger delta. We show that these thickness variations are induced by the alternation of sedimentary processes during continuous fault slip. Suspended-load processes induce either uniform or slightly variable thickness of a large majority of mudstone layers. Bedload processes result in a preferential thickening of sand layers in the hanging wall. These high quality data thus provide strong grounds for doubting the polycyclic growth diagnosed for some faults at the scale of sedimentary cycles and supports the notion that fault displacement rates can be very well behaved. Our study emphasizes the important conclusion that stable fault growth, and related displacement rates, can appear to be punctuated when viewed at the scale of sedimentary cycles. It follows that care should be taken when attempting to derive displacement rates on temporal scales equivalent to those of alternating sedimentological cycles.     

A protocol for classifying ecologically relevant marine zones,a statistical approach

Mapping ecologically relevant zones in the marine environment has become increasingly important. Biological data are however often scarce and alternatives are being sought in optimal classifications of abiotic variables. The concept of ‘marine landscapes’ is based on a hierarchical classification of geological, hydrographic and other physical data. This approach is however subject to many assumptions and subjective decisions.     

Barred Spirals,Double Galaxies and massive Halos1

It is shown that there is no significant dependence of the frequency with which barred spirals occur on environment. Therefore, the difference between normal and barred spirals must be largely due to initial conditions. The excess of early type galaxie (in particular ellipticals and SO's) among the statistically selected binary samples is probably caused by a contamination by cluster members and will therefore result in a systematic overestimate of the masses of binary galaxies. The large fraction of multiple first-ranked galaxies found in rich clusters of BAUTZ -MORGAN type I is surprising in view of tidal effects and dynamical friction, which should lead to the destruction of such massive binary systems on a time scale much shorter than the age of the Universe.     

Fe and O isotope composition of meteorite fusion crusts: Possible natural analogues to chondrule formation?

Meteorite fusion crust formation is a brief event in a high‐temperature (2000–12,000 K) and high‐pressure (2–5 MPa) regime. We studied fusion crusts and bulk samples of 10 ordinary chondrite falls and 10 ordinary chondrite finds. The fusion crusts show a typical layering and most contain vesicles. All fusion crusts are enriched in heavy Fe isotopes, with δ⁵⁶Fe values up to +0.35‰ relative to the solar system mean. On average, the δ⁵⁶Fe of fusion crusts from finds is +0.23‰, which is 0.08‰ higher than the average from falls (+0.15‰). Higher δ⁵⁶Fe in fusion crusts of finds correlate with bulk chondrite enrichments in mobile elements such as Ba and Sr. The δ⁵⁶Fe signature of meteorite fusion crusts was produced by two processes (1) evaporation during atmospheric entry and (2) terrestrial weathering. Fusion crusts have either the same or higher δ¹⁸O (0.9–1.5‰) than their host chondrites, and the same is true for Δ¹⁷O. The differences in bulk chondrite and fusion crust oxygen isotope composition are explained by exchange of oxygen between the molten surface of the meteorites with the atmosphere and weathering. Meteorite fusion crust formation is qualitatively similar to conditions of chondrule formation. Therefore, fusion crusts may, at least to some extent, serve as a natural analogue to chondrule formation processes. Meteorite fusion crust and chondrules exhibit a similar extent of Fe isotope fractionation, supporting the idea that the Fe isotope signature of chondrules was established in a high‐pressure environment that prevented large isotope fractionations. The exchange of O between a chondrule melt and an ¹⁶O‐poor nebula as the cause for the observed nonmass dependent O isotope compositions in chondrules is supported by the same process, although to a much lower extent, in meteorite fusion crusts.     

An analytical solution for describing the transient temperature distribution in an aquifer thermal energy storage system

A mathematical model is developed for predicting the temperature distribution in an aquifer thermal energy storage (ATES) system, which consists of a confined aquifer bounded from above and below by the rocks of different geological properties. The main transfer processes of heat include the conduction and advection in the aquifer and the conduction in the rocks. The semi‐analytical solution in dimensionless form for the model is developed by Laplace transforms and its corresponding time‐domain solution is evaluated by the modified Crump method. Field geothermal property data are used to simulate the temperature distribution in an ATES system. The results show that the heat transfer in the aquifer is fast and has a vast effect on the vicinity of the wellbore. However, the aquifer temperature decreases with increasing radial and vertical distances. The temperature in the aquifer may be overestimated when ignoring the effect of thermal conductivity. The temperature distribution in an ATES system depends on the vertical thermal conduction in the rocks and the horizontal advection and thermal conduction in the aquifer. The present solution is useful in designing and simulating the heat injection facility in the ATES systems. Copyright © 2010 John Wiley & Sons, Ltd.     

Can 234U–230Th dating be used to date large semi‐arid tufas? Challenges from a study in the Naukluft Mountains,Namibia

The large, extensive tufa deposits of the semi‐arid Naukluft Mountains, Namibia are potentially important palaeoenvironmental indicators in an area with few proxy records. Tufas are reliable indicators of increased moisture availability, and have been shown to be amenable to ²³⁴U–²³⁰Th dating, although two challenges are detrital contamination and open‐system behaviour. Densely cemented tufa facies are good candidates for dating, minimising these problems. We report attempts to date five densely‐cemented units, which are only found rarely within the Naukluft deposits. We applied a detailed methodology using multiple subsample analysis, measurement of insoluble residues, application of ‘isochron’ mixing lines, and attempted open‐systems modelling, alongside observations of micromorphology and cathodoluminescence in order to assess the validity of any obtained dates. Surprisingly, densely cemented tufas were found not always to be suitable for dating. Two units contained detrital contamination, which could not be corrected for using a single leachate correction or ‘isochron’ methods. Two units contained ‘excess ²³⁰Th’. This could result under a closed‐system if initial (²³⁴U/²³⁸U) was sufficiently high. Alternatively this may be the result of open‐system behaviour, and loss of uranium, or incorporation of initial unsupported ²³⁰Th, which render samples unsuitable for ²³⁴U–²³⁰Th dating. Micromorphological appearance and cathodoluminescence behaviour are used to explore these possibilities. This study exemplifies the need for careful sample selection, and highlights the importance of analysing multiple subsamples from any tufa sample. The detailed methodology applied proves to be a powerful tool for identifying the range of problems that can be encountered when selecting suitable candidate samples for successful dating. It also shows that semi‐arid tufa sequences may contain very little material suitable for dating. A reliable age of c 80 ka was obtained for a banded unit within a large fluvial barrage, with less reliable dates suggesting tufa deposition during times since >350 ka through to the late Holocene. Copyright © 2010 John Wiley & Sons, Ltd.