The removal kinetics of dissolved organic matter and the optical clarity of groundwater

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d^?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d^?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L^?1) and ultraviolet absorption coefficient values (a ₂₅₄?<?5 m^?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.     

Tide-Induced Variations in the Fatty Acid Composition of Estuarine Particulate Organic Matter

The particulate organic matter (POM) in hydrodynamically variable habitats such as the lower reaches of estuaries can change in its content and quality on very short time scales (example, hourly), and these changes can potentially influence higher-level consumers in river-estuary-marine systems. Estuarine water samples were collected hourly for 12 h downstream in a small river to evaluate the fatty acid composition of POM over a tidal cycle. Fatty acid constituents of POM collected during the flood tide were dominated by the saturated, higher plant and bacterial fatty acids, whereas unsaturated, polyunsaturated, essential, and diatom-associated fatty acids dominated the POM collected during the ebb tide. Elevated algal biomass (as indicated by high chlorophyll a concentrations), diatom, and freshness indices in the POM indicated enhanced fresh autochthonous-origin materials that dominated the mixed organic pool during the ebb tide compared to more degraded detritus during the flood tide. Tidal retention of organic matter and algal primary production were the most influential factors that differentiated the fatty acid composition of estuarine POM over the short time scale. The results of this study have important implications on the quality of POM at the time of sampling, especially in estuaries where mixed organic pools have multiple inputs and are strongly influenced by tidal cycles.     

Three-dimensional stability of landslides based on local safety factor

Unlike the limit equilibrium method (LEM), with which only the global safety factor of the landslide can be calculated, a local safety factor (LSF) method is proposed to evaluate the stability of different sections of a landslide in this paper. Based on three-dimensional (3D) numerical simulation results, the local safety factor is defined as the ratio of the shear strength of the soil at an element on the slip zone to the shear stress parallel to the sliding direction at that element. The global safety factor of the landslide is defined as the weighted average of all local safety factors based on the area of the slip surface. Some example analyses show that the results computed by the LSF method agree well with those calculated by the General Limit Equilibrium (GLE) method in two-dimensional (2D) models and the distribution of the LSF in the 3D slip zone is consistent with that indicated by the observed deformation pattern of an actual landslide in China.     

Overcoming Trade Impediments: Considering SME Exporters from Nova Scotia

Firms often encounter location-based impediments that hinder them from engaging with international markets. These challenges can be exacerbated for smaller firms, which often have limited resources and exposure to global markets. This article examines successful small and medium-sized exporters from Nova Scotia, a province with decreased export activity in recent years. It explores these firms’ trade-related motivations, their impediments, and the strategies that they have used to address possible location-related problems. Although geographical distance does not appear to be a competitive challenge, other issues emerge, including travel expenditures and the costs of export intelligence gathering. Successful exporters have overcome many potential impediments by using government trade programs, establishing and maintaining face-to-face contacts, and working with international partners.     

New results concerning the pedo- and chronostratigraphy of the loess–palaeosol sequence Attenfeld (Bavaria,Germany) derived from a multi-methodological approach

Loess–palaeosol sequences (LPS) represent important records of palaeoenvironmental dynamics throughout the Quaternary. During the Pleistocene's dry and cold phases, the Danube's riverbed was one of the major sources for loess sediments that built up LPS in southern Germany and southeastern Europe. Surprisingly, studies addressing Bavarian LPS along the Danube River often lack actuality. The Attenfeld site was one of them and is often cited as a typical LPS. Nevertheless, the site's previous interpretations are based on a few empirical data and field observations. Considering the site's closeness to the sediment's source area, the Alps, and the region's importance in Middle and Upper Palaeolithic migrational movements, those former renditions needed an evaluation. Therefore, we applied a multi-proxy approach (including analyses of grain-size distribution, element composition, and sediment colour attributes) combined with optically stimulated luminescence. Based on our findings, we conclude that the Attenfeld site's former interpretations might be too generalised. We identified units that were not mentioned by previous studies (e.g. Early Glacial dark greyish horizon). Field observations, sediment characteristics, and age estimates indicate sediment deposition of the dated units partly before MIS 4, which contrasts with previous interpretations. The results further demonstrate how sensitive LPS are to environmental settings and dynamics.     

Quantitative 3D imaging of partially saturated granular materials under uniaxial compression

Acta Geotechnica - Gauging the mechanical effect of partial saturation in granular materials is experimentally challenging due to the very low suctions resulting from large pores. To this end, a...     

Clinoform growth and sediment flux into late Cenozoic Qiongdongnan shelf margin,South China Sea

The South China Sea continental margin in the Qiongdongnan Basin (QDNB) area has incrementally prograded since 10.5 Ma generating a margin sediment prism more than 4km-thick and 150–200 km wide above the well-dated T40 stratigraphic surface. Core and well log data, as well as clinoform morphology and growth patterns along 28 2D seismic reflection lines, illustrate the evolving architecture and margin morphology; through five main seismic-stratigraphic surfaces (T40, T30, T27, T20 and T0) frame 15 clinothems in the southwest that reduce over some 200 km to 8 clinoforms in the northeast. The overall margin geometry shows a remarkable change from sigmoidal, strongly progradational and aggradational in the west to weakly progradational in the east. Vertical sediment accumulation rate increased significantly across the entire margin after 2.4 Ma, with a marked increase in mud content in the succession. Furthermore, an estimate of sediment flux across successive clinoforms on each of the three selected seismic cross sections indicate an overall decrease in sediment discharge west to east, away from the Red River depocenter, as well as a decrease in the percentage of total discharge crossing the shelf break in this same direction. The QDNB Late Cenozoic continental margin growth, with its overall increased sediment flux, responded to the climate-induced, gradual cooling and falling global sea level during this icehouse period.     

Climatically controlled lacustrine clinoforms: Theory and modelling results

Lacustrine basins and their deposits are good paleoclimate recorders and contain rich energy resources. Shelf-margin clinoforms do exist in deep lacustrine basins, but with striking differences from those in deep marine basins, caused by a correlation between the river-derived sediment supply and the lake level. This study uses empirical relationships to calculate the water and sediment discharge from rivers and coeval lake level during wet–dry cycles at 10 s of ky time scale. Sediment supply and lake-level changes are used for a stratigraphic forward model to understand how lacustrine clinoforms develop under different climate conditions. The results show that both wet and dry cycles can be associated with thick deep-water fan deposits, supporting the existing climate-driven lacustrine model proposed based on field data (e.g. Neogene Pannonian Basin and Eocene Uinta Basin). The wet period with high sediment supply and rising lake level creates the highly aggradational shelf, progradational slope and thick bottomset deposits. This is contrary from marine basin settings where the presence of rising shelf-margin trajectory commonly indicates limited deep-water fan deposits. This work suggests marine-based stratigraphic models cannot be directly applied to lacustrine basins.     

AMS 14C age constraints on geoglyphs in the lower colorado river region,arizona and california

Giant ground figures are widespread in the lower Colorado River area of southwestern North America, yet their chronology has remained unconstrained by numerical ages. Thirteen AMS ¹⁴C measurements reported here indicate that geoglyphs were made from before ˜A. D. 1200 to before ˜900 B. C. We account for potential contamination from prior organics in weathering rinds. All other potential errors point to ¹⁴C dates being minimum-limiting ages for the manufacturing of geoglyphs. Although these ages indicate considerable chronological complexity among geoglyphs, our data are consistent with the linguistic hypothesis that the Yuman people in the desert of southeastern California migrated from Baja California—rather than from the north. These results must, however, be placed under the cloud of uncertainty that hangs over the entire field of AMS dating of rock art: the untested assumption surrounding contemporeneity of organics in a surface context. © 1995 John Wiley & Sons, Inc.