Strontium in coral aragonite: 2. Sr coordination and the long-term stability of coral environmental records

We have used X-ray Diffraction (XRD) and Sr K-edge Extended X-ray Absorption Fine Structure (EXAFS) to determine the structural state of Sr in a suite of coral aragonite samples. Our samples encompassed a selection of coral species (Porites lobata, Porites lutea, Pocillopora eydouxi, Montastrea annularis, Pavona gigantea and Pavona clavus) including some commonly used for palaeoenvironmental reconstruction. Aragonite was the only carbonate observed by XRD. We refined the isolated EXAFS against structural models for Sr in aragonite and two-phase strontianite/aragonite mixes. Our data are indistinguishable from Sr ideally substituted in aragonite and strontianite was present below detection levels (estimated at <5% of Sr present). Comparisons of recent and ancient coral aragonite show no sign of exsolution, either by spinodal decomposition or by the direct nucleation of strontianite domains. Published diffusion rates of Sr in ionic solids support the view that exsolution would occur prohibitively slowly. Coral aragonites are metastable materials with slow diffusion kinetics that have the potential to encode environments over timescales of millions of years.     

6: Classification of VMS deposits: Lessons from the South Uralides

VMS deposits of the South Urals developed within the evolving Urals palaeo-ocean between Silurian and Late Devonian times. Arc-continent collision between Baltica and the Magnitogorsk Zone (arc) in the south-western Urals effectively terminated submarine volcanism in the Magnitogorsk Zone with which the bulk of the VMS deposits are associated. The majority of the Urals VMS deposits formed within volcanic-dominated sequences in deep seawater settings. Preservation of macro and micro vent fauna in the sulphide bodies is both testament to the seafloor setting for much of the sulphides but also the exceptional degree of preservation and lack of metamorphic overprint of the deposits and host rocks. The deposits in the Urals have previously been classified in terms of tectonic setting, host rock associations and metal ratios in line with recent tectono-stratigraphic classifications. In addition to these broad classes, it is clear that in a number of the Urals settings, an evolution of the host volcanic stratigraphy is accompanied by an associated change in the metal ratios of the VMS deposits, a situation previously discussed, for example, in the Noranda district of Canada.Two key structural settings are implicated in the South Urals. The first is seen in a preserved marginal allochthon west of the Main Urals Fault where early arc tholeiites host Cu–Zn mineralization in deposits including Yaman Kasy, which is host to the oldest macro vent fauna assembly known to science. The second tectonic setting for the South Urals VMS is the Magnitogorsk arc where study has highlighted the presence of a preserved early forearc assemblage, arc tholeiite to calc-alkaline sequences and rifted arc bimodal tholeiite sequences. The boninitc rocks of the forearc host Cu–(Zn) and Cu–Co VMS deposits, the latter hosted in fragments within the Main Urals Fault Zone (MUFZ) which marks the line of arc-continent collision in Late Devonian times. The arc tholeiites host Cu–Zn deposits with an evolution to more calc-alkaline felsic volcanic sequences matched with a change to Zn–Pb–Cu polymetallic deposits, often gold-rich. Large rifts in the arc sequence are filled by thick bimodal tholeiite sequences, themselves often showing an evolution to a more calc-alkaline nature. These thick bimodal sequences are host to the largest of the Cu–Zn VMS deposits.The exceptional degree of preservation in the Urals has permitted the identification of early seafloor clastic and hydrolytic modification (here termed halmyrolysis sensu lato) to the sulphide assemblages prior to diagenesis and this results in large-scale modification to the primary VMS body, resulting in distinctive morphological and mineralogical sub-types of sulphide body superimposed upon the tectonic association classification.It is proposed that a better classification of seafloor VMS systems is thus achievable using a three stage classification based on (a) tectonic (hence bulk volcanic chemistry) association, (b) local volcanic chemical evolution within a single edifice and (c) seafloor reworking and halmyrolysis.     

Stability at high-pressure,elastic behaviour and pressure-induced structural evolution of CsAlSi<Subscript>5</Subscript>O<Subscript>12</Subscript>, a potential host for nuclear waste

The elastic and structural behaviour of the synthetic zeolite CsAlSi₅O₁₂ (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V ₀ = 1,155(4) ų, K _T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a ³, b ³, c ³) for the volume. The refined axial-EoS parameters are: a ₀ = 16.701(44) Å, K _T0a = 14(2) GPa (β_a = 0.024(3) GPa^?1), K′ _a = 6.2(8) for the a-axis; b ₀ = 13.778(20) Å, K _T0b = 21(3) GPa (β_b = 0.016(2) GPa^?1), K′ _b = 10(2) for the b-axis; c ₀ = 5.018(7) Å, K _T0c = 33(3) GPa (β_c = 0.010(1) GPa^?1), K′ _c = 3.2(8) for the c-axis (K _T0a:K _T0b:K _T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi₅O_12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi₅O₁₂ allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes.     

Structural evolution of a 2M 1 phengite mica up to 11 GPa: an in situ single-crystal X-ray diffraction study

The structural evolution at high pressure of a natural 2M ₁-phengite [(K_0.98Na_0.02)_Σ=1.00(Al_1.55Mg_0.24Fe_0.21Ti_0.02)_Σ=2.01(Si_3.38Al_0.62)O₁₀(OH)₂; a = 5.228(2), b = 9.057(3), c = 19.971(6)Å, β = 95.76(2)°; space group: C2/c] from the metamorphic complex of Cima Pal (Sesia Zone, Western Alps, Italy) was studied by single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions up to ~11 GPa. A series of 12 structure refinements were performed at selected pressures within the P range investigated. The compressional behaviour of the same phengite sample was previously studied up to ~25 GPa by synchrotron X-ray powder diffraction, showing an irreversible transformation with a drastic decrease of the crystallinity at P > 15–17 GPa. The elastic behaviour between 0.0001 and 17 GPa was modelled by a third-order Birch–Murnaghan Equation of State (BM-EoS), yielding to K _T0 = 57.3(10) GPa and K′ = ?K _T0/?P = 6.97(24). The single-crystal structure refinements showed that the significant elastic anisotropy of the 2M ₁-phengite (with β(a):β(b):β(c) = 1:1.17:4.60) is mainly controlled by the anisotropic compression of the K-polyhedra. The evolution of the volume of the inter-layer K-polyhedron as a function of P shows a negative slope, Fitting the P–V(K-polyhedron) data with a truncated second-order BM-EoS we obtain a bulk modulus value of K _T0(K-polyhedron) = 26(1) GPa. Tetrahedra and octahedra are significantly stiffer than the K-polyhedron. Tetrahedra behave as quasi-rigid units within the P range investigated. In contrast, a monotonic decrease is observed for the octahedron volume, with K _T0 = 120(10) GPa derived by a BM-EoS. The anisotropic response to pressure of the K-polyhedron affects the P-induced deformation mechanism on the tetrahedral sheet, consisting in a cooperative rotation of the tetrahedra and producing a significant ditrigonalization of the six-membered rings. The volume of the K-polyhedron and the value of the ditrigonal rotation parameter (α) show a high negative correlation (about 93%), though a slight discontinuity is observed at P >8 GPa. α increases linearly with P up to 7–8 GPa (with ?α/?P ≈ 0.7°/GPa), whereas at higher Ps a “saturation plateau” is visible. A comparison between the main deformation mechanisms as a function of pressure observed in 2M ₁- and 3T-phengite is discussed.     

Water‐bottom multiple attenuation by Kirchhoff extrapolation

Despite being less general than 3D surface‐related multiple elimination (3D‐SRME), multiple prediction based on wavefield extrapolation can still be of interest, because it is less CPU and I/O demanding than 3D‐SRME and moreover it does not require any prior data regularization. Here we propose a fast implementation of water‐bottom multiple prediction that uses the Kirchhoff formulation of wavefield extrapolation. With wavefield extrapolation multiple prediction is usually obtained through the cascade of two extrapolation steps. Actually by applying the Fermat’s principle (i.e., minimum reflection traveltime) we show that the cascade of two operators can be replaced by a single approximated extrapolation step. The approximation holds as long as the water bottom is not too complex. Indeed the proposed approach has proved to work well on synthetic and field data when the water bottom is such that wavefront triplications are negligible, as happens in many practical situations.     

Analysis of climatic trends in data from the agrometeorological station of Bologna-Cadriano, Italy (1952–2007)

Agriculture is highly exposed to climate change, as farming activities directly depend on climatic conditions. Knowledge of the extent of such change and of related phenomena will help to answer the questions posed by society about adaptation strategies. The global situation is well described by the Fourth IPCC assessment report (IPCC 2007), but local studies are important to understand the impact and the priorities to adopt in adaptation strategies. In this study a historical set of meteorological data, collected during the period 1952–2007 at the University of Bologna (Italy) agrometeorological station, was analysed. Several indexes, such as Frost Severity Index, number of hot days, number of rainy days, etc., were calculated, and their trends in time were analysed. The results show a scenario of increasing temperatures and evapotranspiration, a decrease in rainy days and a deepening of the watertable. The effect of these changes on agriculture will be a decrease in water availability, an increase in heat stress in plants and an increase in drought risk.     

Development and Pull-through of Climate Science to Services in China

正1.Introduction The impacts arising from climate change and climate variability pose major challenges to global and regional security and economic prosperity(UNFCCC,2015).Some regions are more at risk than others,through heightened exposure to climatic hazards,and high vulnerability and exposure to such hazards.China,with its rapid economic development,large     

Modeling of the Guagua Pichincha volcano (Ecuador) lahars

Lahars, here defined as debris flows of volcanic origin, are rapid mass movements that pose a serious threat to cities located in the vicinity of many volcanoes. Quito, capital city of Ecuador and placed at the foot of the Pichincha volcano complex, is exposed to serious inundation hazard as part of the city is built on numerous deposits of large lahars that have occurred in the last 10,000 years.The objective of this paper is to model the potential lahars of the Pichincha volcano to predict inundation areas within the city of Quito. For this purpose two models that apply different approaches were utilized and their results were compared.The programs used were LAHARZ, a semi-empirical model conceived by the United States Geological Survey (USGS), and FLO-2D, a hydraulic model distributed by FLO Software Inc. LAHARZ is designed as a rapid, objective and reproducible automated method for mapping areas of potential lahar inundation (Proc. First Int. Conf. on Debris Flow Hazards Mitigation, San Francisco, USA, ASCE, 1998, p. 176). FLO-2D is a two-dimensional flood routing model for simulating overland flow on complex surfaces such as floodplains, alluvial fans or urbanized areas (FLO-2D Users manual, version 99.2). Both models run within geographical information systems (GIS).Fieldwork was focused on collecting all available information involved in lahar modeling. A total of 49 channel cross-sections were measured along the two main streams and stratigraphic investigations were carried out on the fans to estimate the volume of previous events. A global positioning system was utilized to determine the coordinates of each cross-section. Further data collection concerned topography, rainfall characteristics and ashfall thicknesses. All fieldwork was carried out in cooperation with the Instituto Geofisico of the Escuela Politecnica Nacional.Modeling in a GIS environment greatly aided the exportation of results for the creation of thematic maps and facilitated model comparison. Evaluation of the models was performed by comparing simulation results against each other and against the geometry of existing lahar deposits.     

Long-Term RST Analysis of Anomalous TIR Sequences in Relation with Earthquakes Occurred in Greece in the Period 2004–2013

Real-time integration of multi-parametric observations is expected to accelerate the process toward improved, and operationally more effective, systems for time-Dependent Assessment of Seismic Hazard (t-DASH) and earthquake short-term (from days to weeks) forecast. However, a very preliminary step in this direction is the identification of those parameters (chemical, physical, biological, etc.) whose anomalous variations can be, to some extent, associated with the complex process of preparation for major earthquakes. In this paper one of these parameters (the Earth’s emitted radiation in the Thermal InfraRed spectral region) is considered for its possible correlation with M ≥ 4 earthquakes occurred in Greece in between 2004 and 2013. The Robust Satellite Technique (RST) data analysis approach and Robust Estimator of TIR Anomalies (RETIRA) index were used to preliminarily define, and then to identify, significant sequences of TIR anomalies (SSTAs) in 10 years (2004–2013) of daily TIR images acquired by the Spinning Enhanced Visible and Infrared Imager on board the Meteosat Second Generation satellite. Taking into account the physical models proposed for justifying the existence of a correlation among TIR anomalies and earthquake occurrences, specific validation rules (in line with the ones used by the Collaboratory for the Study of Earthquake Predictability—CSEP—Project) have been defined to drive a retrospective correlation analysis process. The analysis shows that more than 93 % of all identified SSTAs occur in the prefixed space–time window around (M ≥ 4) earthquake's time and location of occurrence with a false positive rate smaller than 7 %. Molchan error diagram analysis shows that such a correlation is far to be achievable by chance notwithstanding the huge amount of missed events due to frequent space/time data gaps produced by the presence of clouds over the scene. Achieved results, and particularly the very low rate of false positives registered on a so long testing period, seems already sufficient (at least) to qualify TIR anomalies (identified by RST approach and RETIRA index) among the parameters to be considered in the framework of a multi-parametric approach to t-DASH.     

Vegetation turnover in a braided river: frequency and effectiveness of floods of different magnitude

This work addresses the temporal dynamics of riparian vegetation in large braided rivers, exploring the relationship between vegetation erosion and flood magnitude. In particular, it investigates the existence of a threshold discharge, or a range of discharges, above which erosion of vegetated patches within the channel occurs. The research was conducted on a 14 km long reach of the Tagliamento River, a braided river in north‐eastern Italy. Ten sets of aerial photographs were used to investigate vegetation dynamics in the period 1954–2011. By using different geographic information system (GIS) procedures, three aspects of geomorphic‐vegetation dynamics and interactions were addressed: (i) long‐term (1954–2011) channel evolution and vegetation dynamics; (ii) the relationship between vegetation erosion/establishment and flow regime; (iii) vegetation turnover, in the period 1986–2011. Results show that vegetation turnover is remarkably rapid in the study reach with 50% of in‐channel vegetation persisting for less than 5–6 years and only 10% of vegetation persisting for more than 18–19 years. The analysis shows that significant vegetation erosion is determined by relatively frequent floods, i.e. floods with a recurrence interval of c. 1–2.5 years, although some differences exist between sub‐reaches with different densities of vegetation cover. These findings suggest that the erosion of riparian vegetation in braided rivers may not be controlled solely by very large floods, as is the case for lower energy gravel‐bed rivers. Besides flow regime, other factors seem to play a significant role for in‐channel vegetation cover over long time spans. In particular, erosion of marginal vegetation, which supplies large wood elements to the channel, increased notably over the study period and was an important factor for in‐channel vegetation trends. Copyright © 2014 John Wiley & Sons, Ltd.