Formation of CmSn compounds by photopolymerization of CS2 in the atmosphere of Jupiter

Abstract— Toluene extracts from two (CS_n)_x photopolymers were examined with high‐performance liquid chromatography (HPLC), matrix‐assisted laser desorption ionization time‐of‐flight (MALDI‐TOF) mass spectrometry, particle‐induced x‐ray emission (PIXE), and ¹²C(d,p)¹³C nuclear microprobing. the extracts contained elemental s and at least from 17 to 20 distinct c_ms_n compounds with m/z less than ～500 amu. Whereas H₂S is the dominant S‐bearing compound of the normal jovian atmosphere, elemental S, CS, and CS₂ were observed at Shoemaker‐Levy 9 cometary impact sites and at altitudes of the transiently disturbed jovian atmosphere where photodissociation and photopolymerization occur. It is uncertain whether the CS₂ molecular densities were sufficiently large for both to occur, but photopolymerization could have occurred during larger impacts of Jupiter's history. Because the known stable C_mS_n compounds are yellow, orange and deep red, they could contribute significantly to the colors of the jovian clouds.     

Upslope-climbing shelf-edge clinoforms and the stepwise evolution of the northern European glaciation (lower Pleistocene Eridanos Delta system,U.K. North Sea): When sediment supply overwhelms accommodation

Clinoforms are basinward-dipping and accreting palaeo-bathymetric profiles that record palaeo-environmental conditions and processes; thus, clinothems represent natural palaeo-archives. Here, we document shelf-edge scale clinoform sets which prograded through the entire width of an epicontinental marine basin (ca. 400 km), eventually encroaching onto the opposite basin flank, where they started to prograde upslope and landward, in defiance of gravity (“upslope-climbing clinoforms”). The giant westward-prograding Eridanos muddy shelf-edge clinothem originated from the Baltic hinterland in the Oligocene and achieved maximum regression in the Early Pleistocene, on the UK Central Graben (CG) and Mid North Sea High (MNSH), after crossing the whole North Sea mesopelagic depocentre and causing near complete basin infill. Here we integrate well and seismic data through the MNSH and CG and examine the Eridanos final heyday and demise, identifying five clinothem complexes (A1, A2, A3, B and C) and six depositional sequence boundaries (SB1 to SB6) in the Miocene-Recent section. Tectonic and climatic events drove the recent evolution of this system. Early Pleistocene climate cooling, in particular, resulted in a stepwise increase in sediment supply. This climaxed in the earliest Calabrian, following a likely Eburonian eustatic fall (=SB3) when the Eridanos clastic wedge was restructured from a 100–300 m thick compound shelf-edge and delta system to a “hybrid” shelf-edge delta at sequence boundary SB3 (ca. 1.75 Ma). In the ca. 40 kyr that followed SB3, a progradation rate peak (>1,000 m/kyr) is associated with clinoforms starting to accrete upslope, onto the east-dipping slope between CG and MNSH. This “upslope-climbing clinoform” phase was quickly followed by the maximum regression and final retreat of the Eridanos system in the Early Calabrian (=SB4), likely as the result of climate-driven changes in the Baltic hinterland and/or delta auto-retreat. To our knowledge, this contributions represents the first documentation of “upslope-climbing clinoforms” recorded in the stratigraphic record.     

Attribute trajectory analysis: a framework to analyse attribute changes using trajectory analysis techniques

Trajectory analysis has attracted growing attention in the research field of geography. Beyond traditional moving object trajectories, another type of trajectory exists in which the coordinates are object attributes rather than geographical coordinates. In this paper, a framework to analyse these so-called attribute trajectories is proposed that uses four techniques typically employed in the analysis of moving object trajectories: the Reeb graph, the similarity matrix, the convoy and the mega-convoy. The Reeb graph provides the ability to visualise the temporal dynamics of attribute similarities. The similarity matrix is a supplement of the Reeb graph whose purpose is to visualise the pairwise similarities among the attributes. Moreover, the similarity matrix forms a basis for clustering. The convoy highlights objects whose attributes remain similar for a sufficiently long period. The mega-convoy reduces the number of convoys and reveals their evolutionary histories by merging overlapping convoys. A small real-world meteorological dataset is used as an example to illustrate the attribute trajectory analysis framework and the techniques. This paper aims to form a starting point for applying trajectory analysis techniques in many research fields.     

Review: From multi-scale conceptualization to a classification system for inland groundwater-dependent ecosystems

Aquifers provide water, nutrients and energy with various patterns for many aquatic and terrestrial ecosystems. Groundwater-dependent ecosystems (GDEs) are increasingly recognized for their ecological and socio-economic values. The current knowledge of the processes governing the ecohydrological functioning of inland GDEs is reviewed, in order to assess the key drivers constraining their viability. These processes occur both at the watershed and emergence scale. Recharge patterns, geomorphology, internal geometry and geochemistry of aquifers control water availability and nutritive status of groundwater. The interface structure between the groundwater system and the biocenoses may modify the groundwater features by physicochemical or biological processes, for which biocenoses need to adapt. Four major types of aquifer-GDE interface have been described: springs, surface waters, peatlands and terrestrial ecosystems. The ecological roles of groundwater are conditioned by morphological characteristics for spring GDEs, by the hyporheic zone structure for surface waters, by the organic soil structure and volume for peatland GDEs, and by water-table fluctuation and surface floods in terrestrial GDEs. Based on these considerations, an ecohydrological classification system for GDEs is proposed and applied to Central and Western-Central Europe, as a basis for modeling approaches for GDEs and as a tool for groundwater and landscape management.     

Mumbai 2005, Bihar 2008 Flood Reflected in Mass Changes Seen by GRACE Satellites

Gravity Recovery And Climate Experiment (GRACE) satellites were launched on March 17 2002 to derive with unprecedented accuracy, estimates of the global high resolution model of the earth’s gravity field. Local gravity changes with change in mass or mass redistribution. The mass changes can be due to hydrological events, seismic events or postglacial rebound, majorly. GRACE is sensitive to changes at large spatial scale since the resolution of GRACE is 400 km. Hydrological activities over basins provide sufficient mass changes to be detected by GRACE. In this research paper the discussion would be about two major flooding events in India, one being the 2005 monsoon flooding in Mumbai and nearby states and other being flood experienced by Bihar in 2008. The GRACE data is in the form of matrix consisting spherical harmonic coefficients. These coefficients are processed to obtain mass changes in terms of equivalent water height at a spatial scale of 400 km. The strategy of analysis is also discussed which need to be followed depending upon limitations of GRACE observation and requirement of application, here in this case application is flood induced mass change detection. Time-series and residual plots are generated and they show the flooding events for the concerned area as outliers. Better visualisation is obtained by residual plot, if there is a trend or systematic behaviour in time-series. This work points towards the qualitative capability of GRACE to detect flooding events at large spatial scale. Quantitative analysis requires in-situ data over the period of GRACE which is not possible for the cases discussed here.     

Anomalous behaviour of specific electrical conductivity at a karst spring induced by variable catchment boundaries: the case of the Podstenjšek spring,Slovenia

Anomalous behaviour of specific electrical conductivity (SEC) was observed at a karst spring in Slovenia during 26 high‐flow events in an 18‐month monitoring period. A conceptual model explaining this anomalous SEC variability is presented and reproduced by numerical modelling, and the practical relevance for source protection zoning is discussed. After storm rainfall, discharge increases rapidly, which is typical for karst springs. SEC displays a first maximum during the rising limb of the spring hydrograph, followed by a minimum indicating the arrival of freshly infiltrated water, often confirmed by increased levels of total organic carbon (TOC). The anomalous behaviour starts after this SEC minimum, when SEC rises again and remains elevated during the entire high‐flow period, typically 20–40 µS/cm above the baseflow value. This is explained by variable catchment boundaries: When the water level in the aquifer rises, the catchment expands, incorporating zones of groundwater with higher SEC, caused by higher unsaturated zone thickness and subtle lithologic changes. This conceptual model has been checked by numerical investigations. A generalized finite‐difference model including high‐conductivity cells representing the conduit network (“discrete‐continuum approach”) was set up to simulate the observed behaviour of the karst system. The model reproduces the shifting groundwater divide and the nearly simultaneous increase of discharge and SEC during high‐flow periods. The observed behaviour is relevant for groundwater source protection zoning, which requires reliable delineation of catchment areas. Anomalous behaviour of SEC can point to variable catchment boundaries that can be checked by tracer tests during different hydrologic conditions. Copyright © 2011 John Wiley & Sons, Ltd.     

Numerical study on the mixed model in the GOCE polar gap problem

Gravity gradients acquired by the Gravity field and steady-state Ocean Circulation Explorer(GOCE) do not cover the entire earth because of its sun-synchronous orbit leaving data gaps with a radius of about 6.5° in the polar regions.Previous studies showed that the loss of data in the polar regions deteriorates the accuracy of the low order(or near zonal) coefficients of the earth gravity model,which is the so-called polar gap problem in geodesy.In order to find a stable solution for the earth gravity model from the GOCE gravity gradients,three models,i.e.the Gauss-Markov model,light constraint model and the mixed model,are compared and evaluated numerically with the gravity gradient simulated with the EGM2008.The comparison shows that the Best Linear Uniformly Unbiased Estimation(BLUUE) estimator of the mixed model can solve the polar gap problem as effectively as the light constraint model;furthermore,the mixed model is more rigorous in dealing with the supplementary information and leads to a better accuracy in determining the global geoid.     

Use of artificial and natural tracers to assess groundwater transit-time distribution and flow systems in a high-alpine karst system (Wetterstein Mountains,Germany)

Groundwater in mountainous karst regions is vital for regional water budgets and freshwater supply. Owing to increasing water demand and climate change, detailed knowledge of the highly heterogeneous alpine aquifer systems is required. Multi-tracer analyses have been conducted in the steep karstic Wetterstein Mountains, which includes Germany’s highest summit, Zugspitze (2,962 m asl). Results of artificial tracer tests demonstrate well-developed flow paths through the unsaturated zone (up to 1,000 m thickness). Flow paths cross topographic divides and contribute to deep drainage systems underneath alpine valleys. Cross-formational flow has been identified. Quantitative analysis of tailing-dominated breakthrough curves and stable isotopes (¹⁸O) has enabled determination of the mean transit-time distribution. A fast-flow component with transit times between 3 and 13 days was found in karst conduits and open fissures, dependent on flow conditions. An intermediate-flow component, showing mean transit times of about 2.9–4.9 months, was found in well-drained fissures and fractures. A slow-flow component with mean transit times greater than 1 year is attributable to slow flow and low storage in the poorly drained fissures and rock matrix. The conceptual model enables a better understanding of drainage, water resources and vulnerability of the high-alpine karst system.