Spatial distribution of nitrate and related factors in the High Plains Aquifer,Texas

Utilizing geographic information systems (GIS) and statistics, objectives of this study were to evaluate: (a) the spatial distribution of nitrate concentrations in groundwater, and (b) associations between nitrate concentrations and: proximity to playa lakes, hydraulic conductivity of soil, well depth, and land use in the High Plains Aquifer, Texas. Data were compiled from wells sampled during 2000–2008. Nitrate concentrations in approximately 9% of wells exceeded the maximum contaminant level for drinking water. Concentrations were generally higher beneath urban and agricultural land, under permeable soil, and in shallow wells (especially in the southern part of the study area). However, concentrations were lower near playa lakes. While playas focus recharge to groundwater, denitrification in reducing environments lower nitrate concentrations beneath them. This study identifies areas vulnerable to nitrate contamination that warrant continued monitoring and mitigation efforts.     

Interactive Web-Based Map: Applications to Large Data Sets in the Geosciences

Current advances in computer hardware, information technology and data collection techniques have produced very large data sets in a wide variety of scientific and engineering disciplines. We must harness this opportunity to visualize and extract useful information from geophysical and geological data. We have taken the task of data mining by implementing a map-like approach over a web server for interrogating the data, using a client-server paradigm. The spatial-data is mapped onto a two-dimensional grid from which the user (client) can quiz the data with the map-interface as a user extension. The data is stored on the server, while the computational gateway separating the client and the server can be the front-end of an electronic publication, electronic classroom, a survey, or an e-business. We have used a combination of Java, Java3D, and Perl for processing the data and communicating between the client and the server. The user can interrogate the geospatial data over any particular region with arbitrary dimensions and then receive back relevant statistical analysis, such as the histogram plots and local statistics. We have applied this method for the following data sets: (1.) distribution of prime numbers (2.) two-dimensional mantle convection (3.) three-dimensional mantle convection (4.) high-resolution satellite reflectance data over multiple wavelengths (5.) molecular dynamics describing the flow of blood in narrow vessels. Using the map-interface, one can actually interrogate this data over the Internet.     

Enhancing Microbial Sulfate Reduction of Hydrocarbons in Groundwater Using Permeable Filled Borings

At a service station closed in 1993, groundwater contained benzene that persisted above the cleanup goal of 1 mg/L in zones depleted of background sulfate. The benzene and other petroleum hydrocarbons (PHCs) were present as much as 36 feet (11 m) below the water table and therefore remediation of a thick saturated zone interval was required. Microcosms using site sediments demonstrated that anaerobic benzene biodegradation occurred only if sulfate was added, suggesting sulfate addition as a remediation approach. Twenty-four boreholes (9.1″ diameter and 56′ deep) were drilled around four monitoring wells, in which benzene concentrations exceeded 1 mg/L. The boreholes were backfilled with a mixture of gravel and 15,000 pounds of gypsum (which releases sulfate as it dissolves) to create “Permeable Filled Borings” (PFBs). Concurrently, nine high pressure injections (HPIs) of gypsum slurry were conducted in other site locations (312 pounds of gypsum total). PFBs were expected to release sulfate for up to 20 years, whereas HPIs were expected to produce a short-lived plume of sulfate. Concentrations of benzene and sulfate in groundwater were monitored over a 3-year period in six monitoring wells. In two wells near PFBs, benzene concentrations dropped below the cleanup goal by two to three orders of magnitude; in one well, sulfate concentrations exceeded 500 mg/L for the most recent 18 months. Benzene concentrations in two other PFB monitoring wells declined by a factor of 2 to 4, but remained above 1 mg/L, presumably due to high-dissolved PHC concentrations and possibly greater residual PHC mass in adjacent sediments, and therefore greater sulfate demand. However, hydrogen and sulfur isotopic enrichment in benzene and sulfate, respectively, confirmed biodegradation of benzene and stimulation of sulfate-reducing conditions. Thus, it is hypothesized that the PHC mass in adjacent sediments will decline over time, as will dissolved PHC concentrations, and eventually benzene concentrations will decrease below the cleanup goal. Benzene in two HPI monitoring wells was below the cleanup goal for all but one sampling event before HPIs were conducted and remained below the cleanup goal after HPIs; there was no stimulation of sulfate-reducing conditions. It is concluded that sulfate released from PFBs contributed to declining benzene concentrations.     

A non-hydrostatic model for the numerical study of landslide-generated waves

This paper proposes and demonstrates a two-layer depth-averaged model with non-hydrostatic pressure correction to simulate landslide-generated waves. Landslide (lower layer) and water (upper layer) motions are governed by the general shallow water equations derived from mass and momentum conservation laws. The landslide motion and wave generation/propagation are separately formulated, but they form a coupled system. Our model combines some features of the landslide analysis model DAN3D and the tsunami analysis model COMCOT and adds a non-hydrostatic pressure correction. We use the new model to simulate a 2007 rock avalanche-generated wave event at Chehalis Lake, British Columbia, Canada. The model results match both the observed distribution of the rock avalanche deposit in the lake and the wave run-up trimline along the shoreline. Sensitivity analyses demonstrate the importance of accounting for the non-hydrostatic dynamic pressure at the landslide-water interface, as well as the influence of the internal strength of the landslide on the size of the generated waves. Finally, we compare the numerical results of landslide-generated waves simulated with frictional and Voellmy rheologies. Similar maximum wave run-ups can be obtained using the two different rheologies, but the frictional model better reproduces the known limit of the rock avalanche deposit and is thus considered to yield the best overall results in this particular case.     

A Mass Balance Approach to Resolving LNAPL Stability

This article explores the hypothesis that natural losses of light nonaqueous phase liquids (LNAPLs) through dissolution and evaporation can control the overall extent of LNAPL bodies and LNAPL fluxes observed within LNAPL bodies. First, a proof‐of‐concept sand tank experiment is presented. An LNAPL (methyl tert‐butyl ether) was injected into a sand tank at five constant injection rates that were increased stepwise. Initially, for each injection rate the LNAPL bodies expanded quickly. With time the rate of expansion of the LNAPL bodies slowed and at extended times the extent of the LNAPL became constant. Attainment of a stable LNAPL extent is attributed to rates of LNAPL addition being equal to rates of LNAPL losses through dissolution and evaporation. Secondly, analytical solutions are developed to extrapolate the processes observed in the proof‐of‐concept experiment to dimensions and time frames that are consistent with field‐scale LNAPL bodies. Three LNAPL body geometries that are representative of common field conditions are considered including one‐dimensional, circular, and oblong shapes. Using idealized conditions, the solutions describe volumetric LNAPL fluxes as a function of position in LNAPL bodies and the overall extent of LNAPL bodies as a function of time. Results from both the proof‐of‐concept experiment and the mathematical developments illustrate that natural losses of LNAPL can play an important role in governing LNAPL fluxes within LNAPL bodies and the overall extent of LNAPL bodies.     

Influence of random heterogeneity of shear wave velocity on sliding mass response and seismic deformations of earth slopes

Soil shear wave velocity has been recognized as a governing parameter in the assessment of the seismic response of slopes. The spatial variability of soil shear wave velocity can influence the seismic response of sliding mass and seismic displacements. However, most analyses of sliding mass response have been carried out by deterministic models. This paper stochastically investigates the effect of random heterogeneity of shear wave velocity of soil on the dynamic response of sliding mass using the correlation matrix decomposition method and Monte Carlo simulation(MCS). The software FLAC 7.0 along with a Matlab code has been utilized for this purpose. The influence of statistical parameters on the seismic response of sliding mass and seismic displacements in earth slopes with different inclinations and stiffnesses subject to various earthquake shakings was investigated. The results indicated that, in general, the random heterogeneity of soil shear modulus can have a notable impact on the sliding mass response and that neglecting this phenomenon could lead to underestimation of sliding deformations.