Search for nucleosynthetic and radiogenic tellurium isotope anomalies in carbonaceous chondrites

Tellurium isotope data acquired by multiple-collector inductively coupled plasma-mass spectrometry (MC-ICPMS) are presented for sequential acid leachates of the carbonaceous chondrites Orgueil, Murchison, and Allende. Tellurium isotopes are produced by a broad range of nucleosynthetic pathways and they are therefore of particular interest given the isotopic anomalies previously identified for other elements in these meteorites. In addition, the data provide new constraints on the initial solar system abundance of the r-process nuclide ¹²⁶Sn, which decays to ¹²⁶Te with a half-life of 234,500 years. The ¹²⁶Te/¹²⁸Te ratios of all leachates were found to be identical, within uncertainty, despite variations in ¹²⁴Sn/¹²⁸Te of between about 0.002 and 1.4. The data define a ¹²⁶Sn/¹²⁴Sn ratio of <7.7 × 10⁻⁵ at the time of last isotopic closure, consistent with the value of <18 × 10⁻⁵ previously reported for bulk carbonaceous chondrites. How close this is to the initial ¹²⁶Sn/¹²⁴Sn ratio of the solar system depends on when the investigated samples last experienced redistribution of Sn and Te. No clear evidence is found for nucleosynthetic anomalies in the abundances of p-, s-, and r-process nuclides. The largest effect detected in this study is a small excess of the r-process nuclide ¹³⁰Te in a nitric acid leachate of Murchison. This fraction displays an anomalous ε¹³⁰Te of +3.5 ± 2.5. Although barely resolvable given the analytical uncertainties, this is consistent with the presence of a small excess r-process component or an s-process deficit. The general absence of anomalies contrasts with previous results obtained for K, Cr, Zr, Mo, and Ba isotopes in similar leachates, which display nucleosynthetic anomalies of up to 3.8%. The reason for this discrepancy is unclear but it may reflect volatility and more efficient mixing of Te in the solar nebula.     

Diffusion induced Li isotopic fractionation during the cooling of magmatic rocks: The case of pyroxene phenocrysts from nakhlite meteorites

Ion-microprobe was used to measure Li abundances and isotopic compositions in pyroxenes from three Martian meteorites belonging to the nakhlite family. The profiles performed across augite crystals from Northwest Africa 817 show a large isotopic zoning from crystal cores (δ⁷Li ∼ 0‰) to rims (δ⁷Li ∼ +20‰) while Li abundances are almost constant (∼9.2 μg/g). Unlike NWA 817, the pyroxene studied in the Miller Range 03346 nakhlite shows a zoning in Li abundance, with concentrations increasing from ∼2.5 μg/g in the core to ∼9 μg/g in the rim. The augite rim (δ⁷Li = +7‰) is slightly enriched in ⁷Li with regard to the core (δ⁷Li = +4‰), but most of the isotopic variations observed occur at an intermediate position along the profile, where δ⁷Li falls down to ∼−11‰. In the case of Nakhla, Li concentrations in augite increase from cores (∼3.5 μg/g) to rims (∼6.5 μg/g), while the δ⁷Li variation is restricted (i.e., between δ⁷Li = +6.0 and +12.6‰). For the three meteorites the Li abundances were also measured in the groundmass, which was found to be enriched in lithium (∼10 μg/g). Conventional magmatic and post-magmatic processes such as alteration and fractional crystallization, fail to explain the dataset obtained on nakhlites. Degassing processes, which were previously proposed to explain the Li distribution in shergottite crystals, cannot result in the strong decoupling between Li abundances and isotopic composition observed in nakhlites. We suggest that the original magmatic Li distributions (concentrations and isotopic compositions) in nakhlites have been modified by diffusion of Li from the Li-rich groundmass towards the pyroxene crystals during sub-solidus cooling. Diffusion appears to have been efficient for NWA 817 and MIL 03346 but, apparently, did not produce a significant migration of Li in Nakhla, possibly because of the lower abundance of groundmass in the latter. Diffusion induced Li redistributions may also affect terrestrial porphyric rocks but very specific cooling rates are required to quench the diffusion profiles as observed in two of the present nakhlites.     

Magnetostratigraphic evidence from the Cold Creek bar for onset of ice-age cataclysmic floods in eastern Washington during the Early Pleistocene

This study provides a detailed magnetostratigraphy of sediments composing the Cold Creek cataclysmic flood bar in the Pasco Basin, Washington. Our interpretation suggests onset of Missoula floods or similar events prior to 1.1 myr, later than previously suggested by Bjornstad et al. [Bjornstad, B.N., Fecht, K.R., Pluhar, C.J., 2001. Long history of pre-Wisconsin, Ice Age cataclysmic floods: evidence from southeastern Washington State. Journal of Geology 109 (6), 695-713]. Nonetheless these data suggest that Channeled Scabland features formed over a much longer timespan than commonly cited, that continental ice sheets of the early Pleistocene reached as far south as those of the late Pleistocene, and that similar physiography existed in eastern Washington and perhaps Montana to both generate and route Missoula-flood-like events. This study adds paleomagnetic polarity results from 213 new samples of silts and sands derived from nine new drill cores penetrating the Cold Creek cataclysmic flood bar to our previous database of 53 samples from four boreholes, resulting in a much more robust and detailed magnetostratigraphy. Rock magnetic studies on these sediments show pure magnetite to be the predominant remanence-carrying magnetic mineral, ruling out widespread remagnetization by secondary mineralization. The magnetostratigraphy at eastern Cold Creek bar is characterized by a normal polarity interval bracketed by reversed polarities. Equating the normal zone with the Jaramillo subchron (0.99-1.07 myr) affords the simplest correlation to the magnetic polarity timescale. Western Cold Creek bar was likely deposited during the Brunhes chron (0-0.78 myr) since it exhibits mainly normal polarities with only two thin reversed-polarity horizons that we interpret as magnetic excursions during the Brunhes.     

Evaluation of twenty four new Gossypium hirsutum strains for growth, yield, fibre quality and ClCuV resistance under environment of Punjab, Pakistan

Twenty four new strains were tested for their yield, quality and Leaf Curl Virus (ClCuV) resistance. NIAB-111/S, NIAB-98 and NIAB-999 were significantly high fruit bearing varieties at 90 days completing 59.54, 48.26 and 46.00% fruiting respectively. Seed cotton yield of VH-142 was highest with 5417 kgha^?1 and 52 per plant boll bearing, DNH-57 and NIAB-999 remained second and third with 5234 and 5095 kg ha^?1 seed cotton yield, respectively. BH-160 and CRIS-467 were found to be second and third highest boll bearing varieties with 50.97 and 40.20 per plant average bolls respectively. Plant height in CRIS-467, MNH-642 and SLH-224 was significantly higher in comparison to other varieties.NIAB-98, CIM-499 and CIM-506 were found short stature varieties in comparison with other but out of these NIAB-98 and CIM-506 were in high yielding position and CIM-499 was found medium yielder variety. GOT% of MNH-642 remained highest having value of 45.00%. While GOT%. of NIBGE-1, CRIS-168 and CRIS-467 was at lowest position with 35.73, 35.89 and 36.62% respectively. NIAB-111, CIM-499 and BH-160 were at first position in terms of fibre fineness with micronaire values 3.98, 4.00 and 4.07 ìg/inch having fibre length 28.53, 31.38 and 30.23 mm respectively. Out of 26 varieties, 16 varieties resulted maturity index in the range of 85.03% and 90.30% with highest maturity index in case of NIBGE-1 (i.e. 90.30%) followed by NIAB-999 and MNH-642 with 89.55 and 85.5% respectively.CRIS-168, CRIS-468 and CRIS-467 were found viral susceptible.     

Assessment of the mycoflora of commercial poultry feeds sold in the humid tropical environment of Imo State, Nigeria

This study was carried out to identify the common moulds growing in selected commercial poultry feed sold in Owerri, Imo State, Nigeria. Forty-eight bulk samples derived froml92 bags of feeds were collected from broiler starter (BS), broiler finishers (BF), grower mash (GM) and layer mash (LM) across 4 different brands of ommercial poultry feeds, which included Livestock (LF), Top (TF) Guinea (GF) and Vital (VF) feeds. The feed samples were collected during the rainy season months of June, July and August. The common moulds isolated from these feeds were Aspergillus sp., Peicillium sp.,Mucor sp., Yeast sp., Rhizopus sp., Epicoecum sp., Gymnoaseus sp., Cladosporium sp., Mortierella sp. as well as Bacteria. Generally, more organisms were isolated in June than the other months with Mortierella sp. being the only one not isolated in that month. Vital feed with 8 different isolates had the highest diversity of fungal species while the others had between 4 and 5 species. Prevalence rates across the feed types, generally ranged from 18.76% in layer mash to 30.03% in broiler finisher. The four Aspergillus sp. isolated came from GM and BF. This study highlights the need for constant monitoring of moulds in commercial feedstuff produced in the humid tropical environments such as Imo state, Nigeria. There is also the need to routinely include fungal growth nhibitors in commercial feeds since moulds are capable of reducing the nutritional values of feedstuff as well as elaborating pathogenic toxins.     

Total organic carbon in soils and its relation with manganese concentrations in soils and vegetation close to an abandoned manganese mine

This study aimed at quantifying the total organic carbon (TOC) present in soils within the proximity of the Kgwakgwe Mn oxide ore abandoned mine, Botswana, and establish its relationship with Mn concentrations in soils and vegetation based on multivariate and Geographical Information Systems (GIS) analytical techniques. Four hundred soil samples and 200 vegetation set samples were obtained from a 4 km² area close to the abandoned mine. The TOC in soil samples were determined using a carbon/hydrogen/moisture determinator, and Mn concentrations in soils and vegetation by atomic absorption spectrophotometry. Results were processed using the statistical package for social science (SPSS), GIS, and Remote Sensing (RS) techniques with the Integrated Land and Water Information System (ILWIS), Geosoft Oasis Montaj and ArcGIS software packages. The values for TOC in the soil samples from the study area ranged from 0 wt % to 7.91 wt %, with a mean of 1.90 wt %, and at the control area, from 4.07 wt % to 4.86 wt %. The range of concentrations of Mn in soils was from 36 mg/g to 24908 mg/g and for Mn concentrations in the vegetation samples from 26 mg/g to 3611 mg/g with a mean of 598 mg/g. Results of correlation coefficients depicted very weak negative association except Mn in soils/Mn in leaves which was weak but positive. The statistical data yielded four clusters as follows: cluster one consisted mainly of Mn in leaves, cluster two was constituted of Mn in soils, and cluster four had TOC. Cluster three was dominated by the three parameters but with negative t statistic. The spatial presentation of data presented revealed little or no vegetation in the south eastern area and those close to the mine workings, and some significant vegetation in the north western part of the study area. The low TOC in the soils is associated to low vegetation cover which is considered to have been influenced by the soil clay fraction mineralogy and high concentrations of Mn.     

Effect of aluminum and chromium on the germination and growth of two Vigna species

The study deals with the effect of metal toxicity (aluminum, chromium and combination of both the metals) on seed germination, root length, shoot length, seedling length and dry biomass of Vigna radiata and V. sinensis. Chromium adversely affected the seedling by significantly reducing the growth whereas aluminum did not show such effect in both the species. Percentage of germination was good in both the species at different concentration of treatment (aluminum, chromium and combined treatment). Shoot length was also not much affected in V. sinensis as it was greatly inhibited in V. radiata. Both the species showed the purpling of stem. Dry biomass of V. radiata showed positive effect than V. sinensis. However, dry biomass decreased to a lesser extent when treated with aluminum, chromium and combined treatment as compared to control.     

Large eddy simulation of hydrocyclone—prediction of air-core diameter and shape

Hydrocyclones are widely used in the mining and chemical industries. An attempt has been made in this study, to develop a CFD (computational fluid dynamics) model, which is capable of predicting the flow patterns inside the hydrocyclone, including accurate prediction of flow split as well as the size of the air-core. The flow velocities and air-core diameters are predicted by DRSM (differential Reynolds stress model) and LES (large eddy simulations) models were compared to experimental results. The predicted water splits and air-core diameter with LES and RSM turbulence models along with VOF (volume of fluid) model for the air phase, through the outlets for various inlet pressures were also analyzed. The LES turbulence model led to an improved turbulence field prediction and thereby to more accurate prediction of pressure and velocity fields. This improvement was distinctive for the axial profile of pressure, indicating that air-core development is principally a transport effect rather than a pressure effect.     

Paleoproterozoic (2155–1970 Ma) evolution of the Guiana Shield (Transamazonian event) in the light of new paleomagnetic data from French Guiana

We present a comprehensive paleomagnetic study on Paleoproterozoic (2173–2060 Ma) plutonic and metamorphic rocks from French Guiana, representative of the full range of the main Transamazonian tectonothermal steps. Twenty-seven groups of directions and poles were obtained from combination of 102 sites (613 samples) based on age constraint, similar lithology and/or geographical proximity. Paleomagnetic results show variations between rocks of different ages which are supposed to be characteristic of magnetizations acquired during uplift and cooling of successive plutonic pulses and metamorphic phases. This is also reinforced by positive field tests (baked contact and reversal tests). Recent U/Pb and Pb/Pb on zircon and complementary ⁴⁰Ar/³⁹Ar on amphibole and biotite allow questioning the problem of magnetic ages relative to rock formation ages. Estimated magnetic ages, based on amphibole dating as a proxy, enable us to construct a Guiana Shield apparent polar wander path for the 2155–1970 Ma period. It is also possible to present paleolatidudinal evolution and continental drift rates related to specific Transamazonian tectonic regimes.French Guiana and probably the Guiana Shield were located at the Equator from ca. 2155 to 2130 Ma during the Meso-Rhyacian D1 magmatic accretion phase, related to subduction of Eorhyacian oceanic crust. After closure of the Eorhyacian Ocean and collision of West African and Amazonian plates, the Guiana Shield moved. The first evolution towards 60° latitude, occurs after 2080 Ma, during the Neorhyacian D2a post collisional sinistral transcurrent phase. During the Late Rhyacian D2b phase, up to 2050 Ma, the Guiana Shield reaches the pole and starts to move to lower latitudes on an opposite meridian. By the Orosirian D2c phase, from ca. 2050 to 1970 Ma, the Guiana Shield reaches the Equator.Based on the amphibole ⁴⁰Ar/³⁹Ar dates, we estimate the continental drift between 12 and 16 cm/y for the Meso to Late Rhyacian period followed by a lower rate between 9 and 14 cm/y up to Orosirian time. This study highlights rock ages and magnetic ages are prerequisite to any continental reconstruction especially when it is shown continental drift is important for a 100–200 Ma time period. Our results confirm the possibility of APWP construction on Paleoproterozoic plutonic rocks but suggest improvement will rely on the combination with multidisciplinary approaches such as structural geology and multi-method radiometric dating.