Partitioning of polycyclic aromatic hydrocarbons between water and particles compared to bioaccumulation in mussels: a harbour case

Water and particles from three sites located in Halifax Harbour, near and further away from combined municipal sewage effluents (CMSE) were analysed for parental and alkylated polycyclic aromatic hydrocarbons (par and alkPAH). Bioavailability of PAH was compared for inter-tidal mussels collected at the same sites in April and November. The PAH fingerprint determined over 9 sampling times covering a period of 19 months differed more between phases (water and particles) and seasons, than between sites. In the spring, more alkPAH associated with diesel and gasoline were detected in the soluble phase, along with more bioaccumulation of alkPAH in inter-tidal mussels. A broader number of parPAH were detected in mussels collected in the fall. The mean sum of dissolved alkPAH concentrations was higher in water at the site closer to raw CMSE than at the other two sites and particles of that site. However, lowest bioconcentration factors (BCF) were determined in mussels of this more contaminated site. Similar biota-particle accumulation factors (BPAF) were determined for parPAH in mussels from the three sites, all lower than the BCF of alkPAH. The study indicates that sewage treatment plants will reduce the amount of parPAH especially larger than fluoranthene and pyrene from being deposited in the harbour; that alk naphthalenes and fluorenes present in water will continue to be discharged; that the disturbance of sediments can make particle-bound PAH available to mussels.     

Combined numerical model of currents, waves, and sediment transport in Lake Donuzlav

We present a numerical model of the dynamics of Lake Donuzlav, which enables one to perform simultaneous numerical analyses of the currents, sea level, waves, and sediment transport. The model is based on the hydrodynamic block and the spectral wave model. For typical storm situations, we study the specific features of the integral circulation of waters and the three-dimensional structure of currents, investigate the wind-induced wave fields, and evaluate the flows of sediments and deformations of the bottom. The presence of intense eddy structures is revealed in the field of currents caused by the bottom topography. A significant intensification of waves in the south part of the lake is established in the case of penetration of storm waves through the strait. It is shown that the account of waves leads to qualitative changes in the structure of circulation in the lake and to the formation of well-pronounced areas of wave-induced elevations and lowerings of the sea level. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 2, pp. 43–65, March–April, 2006.     

A Pull-Up Shallow Water Seismometer

An inexpensive Pull-Up Shallow Water Seismometer (PUSS) has been designed and built to conduct long range seismic refraction experiments in the North Sea and the continental shelf around Britain, with the particular goal of studying the crustal and lithospheric structure under the epeirogenic basin of the North Sea. Signals from a gimbal-mounted 3-component geophone and a hydrophone are frequency modulated and mixed with clock and flutter correction signals before being recorded on a standard speed cassette tape recorder, with one hour of recording time. A 100 hour programmable timer allows the interval between the time of reset of the clock and each shot window of optional 5 or 10 min duration, to be preselected. The PUSS is launched and recovered using a pull-up technique originally developed for current meters. The replay system is also described.In May 1976 sea trials of 5 PUSSes were conducted along a 200 km refraction line in the North Sea. The encouraging performance of the equipment resulted in the decision to build a further 10 units and to proceed with a 400 km refraction line planned for the summer of 1977.     

Sea-structure interaction for tripod-type steel gravity platform

The paper deals with a numerical integrated procedure to calculate the effects of the interaction between sea waves and a tripod-type steel gravity platform. The main aspects to be taken into account for a reliable wave loading analysis of such a new type of platform are emphasized. Among them, the field perturbation effect due to the large bodies presence is analysed. Finally, some principal results in terms of structure global loads obtained by the numerical integrated procedure are presented.     

Multi-bioindicator study of a small estuary in Vendée (France)

Surficial sediment (about 5 mm) was scraped off in 15 stations selected in the Vie Estuary, a small estuary on the French Atlantic coast. The samples, prepared using the suitable methods, were used for comparing the behaviour of periphytic algae, sporopollinic and other palynologic material, ostracoda and foraminifera for proposing a synthetic evaluation of the information provided by each of them. Dinoflagellate cysts, which are found in an almost monospecific assemblage in low-salinity water, are dispersed by tidal currents, but the location of tintinnids in only the lower reaches shows a limited inward transport. Sporopollinic material is clearly related to the adjacent vegetation, indicating a local origin, and then little influence of transport on the microbenthos, even if fragments of freshwater crustaceans and of Pediastrum alga are found down to the mouth in the sporopollinic deposits. This limited transport of microbenthos allows the use of periphytic algae, benthic ostracoda and benthic foraminifera as indicators of local environmental conditions. It was then possible to determine the extent of marine influence in the estuary, to discriminate between the main channel and adjacent basins, and between different stages of evolution of the basins, from a recently dug basin to a eutrophicated one.     

Interaction of Surface Waves in a Basin with Floating Broken Ice

The multiscale method is used to obtain asymptotic expansions up to the quantities of the third order for the elevations of the surface of the basin and the velocity potential of motion of liquid particles in the wave disturbances formed in the process of nonlinear interaction of periodic running waves of the first and second harmonics in a homogeneous ideal incompressible liquid of constant finite depth covered with broken ice. The dependences of the amplitude-phase structure of disturbances on the ice thickness, depth of the basin, and the parameters of interacting harmonics are investigated. We estimate the error of evaluation of the characteristics of the formed vertical displacement of the surface of the basin and nonlinear mass transfer introduced by neglecting the curvature of the wave profile in the expression for the velocity potential in deducing the kinematic and dynamic surface boundary conditions for nonlinear approximations.     

Effect of core porosity on stability and run-up of breakwaters

The commonly used formulae like Hudson's [(1959), Laboratory investigations of rubblemound breakwaters. WES report, Vicksburg], Iribarren's or Vander meer's [(1988), Rockslopes and gravel beaches under wave attack. Ph.D. thesis, Delft University of Technology, The Netherlands], do not give us the design cross section of a rubblemound breakwater for varying core porosity values. The paper presents the results of the experimental study carried out to compute the effects of core porosity on the stability and run-up characteristics of rubblemound breakwaters. Regular waves were made to attack the structure, with different core porosity values in a normal direction. The porosity of the armour and the secondary layers was neglected. It was observed that as core porosity increased the stability also increased considerably within the limits of the experimental data values. This may be due to large inflow and energy dissipation within the core of the structure. The run-up on the rubblemound slope was found to decrease with the increase in the porosity for the same reason.     

Isolation and characterisation of pristane metabolites formed in vivo by rainbow trout

Pristane (2,6,10,14 -tetramethylpentadecane) occurs ubiquitously in the marine environment. This hydrocarbon may be of biogenic or petrogenic origin.¹ Recently it has been shown that residual amounts of this branched alkane increased in marine organisms after an oil spill.^2,3 The lack of data on the fate of pristane in fish, added with the fact that this compound was considered by some authors as a non-metabolisable substance in vertebrates, including man,⁴ led us to investigate the capability of fish to metabolise pristane. In this study, urinary and fecal excretion, tissue distribution and metabolism of ³H-pristane were analysed in Salmo gairdneri R. after a single intragastric dose. In addition to unchanged hydrocarbon, various labelled compounds have been isolated and identified in liver, bile, faeces, urine and surrounding water, demonstrating that pristane was first oxidised to alcohols (pristanol and pristane-diol) and to acid (pristanic acid). The elimination of these compounds occurred in the form of conjugated products (primarily glucuronides) as well as free metabolites.     

Low-frequency damping of a moored semisubmersible obtained from simulated extinction tests and mean wave drift forces

Low-frequency damping of a moored semisubmersible drilling platform was obtained from numerical extinction tests simulated in still water and in regular waves and from mean wave drift forces calculated at zero forward speed. The influence of drag forces was represented by the modified Morison equation. The platform as used for the 18th ITTC Comparative Mooring Study was analyzed in irregular beam waves. The computed time series of sway as well as the corresponding sway response spectrum compared favourably with model test measurements, demonstrating that this procedure to determine low-frequency damping can be effective.