Particulate organic carbon–Th relationships in particles separated by settling velocity in the northwest Mediterranean Sea

In order to better understand the relationship between the natural radionuclide ²³⁴Th and particulate organic carbon (POC), marine particles were collected in the northwestern Mediterranean Sea (spring/summer, 2003 and 2005) by sediment traps that separated them according to their in situ settling velocities. Particles also were collected in time-series sediment traps. Particles settling at rates of >100 m d⁻¹ carried 50% and 60% of the POC and ²³⁴Th fluxes, respectively, in both sampling years. The POC flux decreased with depth for all particle settling velocity intervals, with the greatest decrease (factor of 2.3) in the slowly settling intervals (0.68–49 m d⁻¹) over trap depths of 524–1918 m, likely due to dissolution and decomposition of material. In contrast the flux of ²³⁴Th associated with the slowly settling particles remained constant with depth, while ²³⁴Th fluxes on the rapidly settling particles increased. Taking into account decay of ²³⁴Th on the settling particles, the patterns of ²³⁴Th flux with depth suggest that either both slow and fast settling particles scavenge additional ²³⁴Th during their descent or there is significant exchange between the particle classes. The observed changes in POC and ²³⁴Th flux produce a general decrease in POC/²³⁴Th of the settling particles with depth. There is no consistent trend in POC/²³⁴Th with settling velocity, such as might be expected from surface area and volume considerations. Good correlations are observed between ²³⁴Th and POC, lithogenic material and CaCO₃ for all settling velocity intervals. Pseudo-K_ds calculated for ²³⁴Th in the shallow traps (2005) are ranked as lithogenic material opal <calcium carbonate <organic carbon. Organic carbon contributes 33% to the bulk K_d, and for lithogenic material, opal and CaCO₃, the fraction is 22% each. Decreases in POC/²³⁴Th with depth are accompanied by increases in the ratio of ²³⁴Th to lithogenic material and opal. No change in the relationship between ²³⁴Th and CaCO₃ was evident with depth. These patterns are consistent with loss of POC through decomposition, opal through dissolution and additional scavenging of ²³⁴Th onto lithogenic material as the particles sink.     

Antenna phase center calibration for precise positioning of LEO satellites

Phase center variations of the receiver and transmitter antenna constitute a remaining uncertainty in the high precision orbit determination (POD) of low Earth orbit (LEO) satellites using GPS measurements. Triggered by the adoption of absolute phase patterns in the IGS processing standards, a calibration of the Sensor Systems S67-1575-14 antenna with GFZ choke ring has been conducted that serves as POD antenna on various geodetic satellites such as CHAMP, GRACE and TerraSAR-X. Nominal phase patterns have been obtained with a robotic measurement system in a field campaign and the results were used to assess the impact of receiver antenna phase patterns on the achievable positioning accuracy. Along with this, phase center distortions in the actual spacecraft environment were characterized based on POD carrier phase residuals for the GRACE and TerraSAR-X missions. It is shown that the combined ground and in-flight calibration can improve the carrier phase modeling accuracy to a level of 4 mm which is close to the pure receiver noise. A 3.5 cm (3D rms) consistency of kinematic and reduced dynamic orbit determination solutions is achieved for TerraSAR-X, which presumably reflects the limitations of presently available GPS ephemeris products. The reduced dynamic solutions themselves match the observations of high grade satellite laser ranging stations to 1.5 cm but are potentially affected by cross-track biases at the cm-level. With respect to the GPS based relative navigation of TerraSAR-X/TanDEM-X formation, the in-flight calibration of the antenna phase patterns is considered essential for an accurate modeling of differential carrier phase measurements and a mm level baseline reconstruction.

Experimental studies of sublimation of highly volatile ices in relevance to the ices of the solar system

Studies of sublimation of complex ices prepared by deposition of gaseous CO, CH₄, N₂, and NH₃ molecules on a cold plate have been performed. The low pressure and low temperature system was used: 10^?9–10^?5 mbar and the lowermost temperature 10 K. Diagnostic of composition of evaporates (at an actual temperature) was done by means of the mass spectrometer. The latter allowed following simultaneously the partial pressure of five different ions or radicals escaping from the substrate. It has been found that highly volatile molecules that were used simultaneously with the low volatile ones to form the complex ices (mixtures or clathrates) present a different sublimation pattern than the sublimation of pure high-volatile ices. In particular, the high-volatile component sublimes at two or even three different temperature regimes: At low temperature that is typical for sublimation of this component, as well as at much higher temperatures. This effect seems to be important when degassing and outbursts from cometary nuclei are considered. It can be also important for modeling of cryovolcanic processes on the icy satellites.     

Long-Term Amateur Ccd Monitoring Of Comet C/1999 S4 (Linear)

The results from the analysis of the extensive CCD photometry that we haveobtained during the long-term monitoring (from its discovery until its break-up)of comet C/1999 S4 (linear) are presented here. Our observations showthat the comet did not always behave as expected: it showed activity ahead oftime and in the end became fainter instead of brighter as it approached perihelion.A sequence of images and a lightcurve are shown.     

Study of the interaction between U(VI) and the anoxic corrosion products of carbon steel

The objective of this study was to investigate the removal mechanism of U(VI) from groundwater by magnetite as the main product of anoxic steel corrosion. For this purpose, a systematic sequence of batch experiments was conducted to focus the active role of magnetite in the reduction of U under different conditions. Results indicated that under anoxic conditions U(VI) was sorbed at the magnetite surface, whereas under reducing conditions at different H₂(g) pressures, U was present in tetravalent form as amorphous UO₂.     

Characterization and provenance of the slabs of the Puigseslloses Megalith,Barcelona, Spain

The Puigseslloses megalith tomb (Barcelona, Spain) is located on the summit of a hill in the Vic Plain where the sedimentary rocks that were used in its construction do not crop out. A sedimentological and petrological characterization of the monument's slabs and a multidisciplinary analysis of the outcropping materials in nearby areas has allowed the identification of three possible source areas associated with the Paleogene Banyoles Marls Formation and the Folgueroles Sandstone Formation and allows us to propose possible routes by which the slabs were transported from the catchment site to the place where the monument was built. In addition, the lithology and position of different slabs within the megalith denote the intention to separate the chamber from the corridor by using different types of slab. The position of the monument also reveals that tomb location was more of a priority than proximity to the slab sources. © 2010 Wiley Periodicals, Inc.     

Some manifolds of periodic orbits in the restricted three-body problem

In the present paper we give some numerical results about natural families of periodic orbits, which emanate from limiting orbits around the equilateral equilibrium points of the Restricted Three-Body Problem, when the mass ratio is greater than Routh's critical one.     

Biogeochemical characterization of particulate organic matter from a coastal hydrothermal vent zone in the Aegean Sea

Three particle interceptor traps were moored from June to September 1996 along the SE coast of Milos Island (Aegean Sea), in an area known for its extensive seabed geothermal activity. The settling particles collected differed between sites not only in quantity but also in their geochemical composition. In the area directly influenced by warm water vents, the vertical flux of particulate material was almost one order of magnitude higher than that observed at the reference sites 6.5 km away from the vents, with a higher contribution of biogenic material in the former. The neutral lipid fractions exhibited a significant zooplankton biomarker signature (e.g. cholesterol and wax esters), followed by those of microalgal and terrigenous remains. The biogeochemical cycle of sterols included the formation of steroidal ketones, thiols and stanols, the latter two particularly associated with the venting activity. Moreover, the aliphatic and aromatic hydrocarbons in the particles from the venting area reflected a locally enhanced maturity of the organic matter. Although part of the material collected in the traps may have been exported in the vent waters, the higher fluxes observed in the vicinity of the hydrothermal plumes are mainly the result of an assemblage of zooplankton which, in turn, may contribute significantly to the sedimentation, through fast sinking faecal pellets, of the petrogenic hydrocarbons possibly generated in the vents.     

An assessment of particulate organic carbon to thorium-234 ratios in the ocean and their impact on the application of Th as a POC flux proxy

Thorium-234 is increasingly used as a tracer of ocean particle flux, primarily as a means to estimate particulate organic carbon export from the surface ocean. This requires determination of both the ²³⁴Th activity distribution (in order to calculate ²³⁴Th fluxes) and an estimate of the C / ²³⁴Th ratio on sinking particles, to empirically derive C fluxes. In reviewing C / ²³⁴Th variability, results obtained using a single sampling method show the most predictable behavior. For example, in most studies that employ in situ pumps to collect size fractionated particles, C / ²³⁴Th either increases or is relatively invariant with increasing particle size (size classes > 1 to 100s μm). Observations also suggest that C / ²³⁴Th decreases with depth and can vary significantly between regions (highest in blooms of large diatoms and highly productive coastal settings). Comparisons of C fluxes derived from ²³⁴Th show good agreement with independent estimates of C flux, including mass balances of C and nutrients over appropriate space and time scales (within factors of 2–3). We recommend sampling for C / ²³⁴Th from a standard depth of 100 m, or at least one depth below the mixed layer using either large volume size fractionated filtration to capture the rarer large particles, or a sediment trap or other device to collect sinking particles. We also recommend collection of multiple ²³⁴Th profiles and C / ²³⁴Th samples during the course of longer observation periods to better sample temporal variations in both ²³⁴Th flux and the characteristic of sinking particles. We are encouraged by new technologies which are optimized to more reliably sample truly settling particles, and expect the utility of this tracer to increase, not just for upper ocean C fluxes but for other elements and processes deeper in the water column.     

A Deep-sea Channel in the Northwestern Mediterranean Sea: Morphology and seismic structure of the Valencia Channel and its surroundings

The 400 km long Valencia Channel occupies the axis of the Valencia Trough in the Northwestern Mediterranean. Four different types of seismic reflection profiles were used to analyze the morphology and structure of the Valencia Channel with regard to the role played by both margins, Balearic and Iberian, of the Valencia Trough. From a detailed morphoseismic analysis of the Valencia Channel, its upper, middle, and lower courses can be characterized as follows: (1) in the upper course, tributaries are short and only slightly incised, with recent mass-transport deposits occurring on the adjacent continental slopes; (2) in the middle course, the channel deepens, and tributary valleys merge into it; and (3) the lower course begins after a sudden change in the direction of the channel, has a meandering path, is flanked by levees, and is fed by some valleys.During the Pliocene and Quaternary, at least four erosional and filling phases are observed in seismic profiles of the lower course of the Valencia Channel. The varying intensity of mass-transport processes and associated retrogressive slumping, which are related with fluctuations in sediment supply and relative sea-level changes, have played a major role in the formation, maintenance and deepening of the Valencia Channel. In addition to these sedimentary processes, a basement tectonic control and some morphostructural features affect the direction of the Valencia Channel locally.