Physicochemical characteristics for adsorption of MTBE and cadmium on clay minerals

Physicochemical characteristics relevant to the adsorption of MTBE and Cd on three types of clay minerals were investigated. The characteristics were examined through batch adsorption tests conducted under various experimental conditions such as adsorption time, ratio of solution-to soil, concentration of solutes, concentration of organic matters, pH, and zeta potential. The adsorption efficiency of MTBE or Cd on three types of clays decreased in response to an increase of the ratio of solution-to-soil; nevertheless, the adsorbed amounts inversely increased. MTBE was adsorbed on clays in an increasing order of vermiculite, bentonite, and CTAB-bentonite. However, Cd was adsorbed in a different order of bentonite, vermiculite, and CTAB-bentonite. The adsorption of MTBE was well fitted with the Freundlich model, whereas the Cd was more closely suited to a Langmuir equation. By adding humic acids of 1 and 5%, MTBE was significantly adsorbed on bentonite and vermiculite, respectively, but beyond that, its adsorption was diminished. In comparison, the adsorption on CTAB-bentonite was increased in proportion to the humic acids addition. Likewise, the addition of humic acids acted to increase the adsorption of Cd regardless of the types of adsorbent, where up to 90% of Cd was removed at pH 10. Further increase of pH declined the degree of zeta potential, while increasing Cd concentration also lowered the zeta potential, which consequently contributes in enhancing the adsorption efficiency of Cd on clays.     

Genetic Implications of Two Different Ultramafic Rocks from Hongseong Area in the Southwestern Gyeonggi Massif, South Korea

Two distinct ultramafic bodies occur in Baekdong and Bibong in the Hongseong area within Gyeonggi massif of South Korea. The Hongseong area is now extensively documented as an extension of the Dabie-Sulu collision belt in China. The Baekdong ultramafic body has a NWW elongation direction. This elongation trend is similar to the general trend of the Dabie-Sulu collision belt. The Bibong ultramafic body is elongated in a NNE direction and runs parallel to the direction of the main fault in the study area. The Baekdong ultramafic bodies show porphyroclastic and mylonitic textures while those at Bibong exhibit a mosaic texture. Both were grouped into peridotite and serpentinite based on their modal abundance of serpentine. In the olivine (Fo) vs. spinel [Cr# = Cr/ (Cr+Al)] diagram, both ultramafic rocks fall with in olivine spinel mantle array. The compositions of olivine, orthopyroxene and spinel indicate that the Baekdong ultramafic rock formed in deeper parts of the upper-mantle under passive margin tectonic setting. The SREE content of Baekdong ultramafic rock vary from 0.19 to 5.7, exhibits a flat REE pattern in the chondrite-normalized diagram, and underwent 5% partial melting. Conversely, large variation in SREE (0.5 21.53) was observed for Bibong ultramafic rocks with an enrichment of LREE with a negative slope and underwent 17 24% partial melting. The Baekdong ultramafic rocks experienced three stages of metamorphism after a high pressure residual mantle stage. The first stage of metamorphism occurred under the eclogite-granulite transitional facies (1123 911°C, >16.3 kb) the second under the granulite facies (825 740°C, 16.3 11.8 kb) and the third is the retrogressive metamorphism under amphibolite facies (782 718°C, 8.2 8.7 kb) metamorphism. The Baekdong ultramafic rocks had undergone high-P/T metamorphism during subduction of the South China Block, and experienced a fast isothermal uplift, and finally cooled down isobarically. Evidences for metamorphism were not identified in Bibong ultramafic rocks. Hence, the Baekdong ultramafic rocks with in the Hongseong area may indicate a link on the Korean counterpart of Dabie-Sulu collision belt between North and South China Blocks.     

闽江口拦门沙整治工程建议

本文根据闽江口内、外拦门沙悬沙动态相关分析的基本结论,提出成套的整治工程建议包括壶江锁坝、五虎-川石锁坝、川石顺坝和梅花顺坝,文中记述各项工程的主要机制和具体的工程效益,供设计部门参考。     

Development of statistical prediction models for Changma precipitation: An ensemble approach

An ensemble statistical forecast scheme with a one-month lead is developed to predict year-to-year variations of Changma rainfall over the Korean peninsula. Spring sea surface temperature (SST) anomalies over the North Atlantic, the North Pacific and the tropical Pacific Ocean have been proposed as useful predictors in a previous study. Through a forward-stepwise regression method, four additional springtime predictors are selected: the northern Indian Ocean (NIO) SST, the North Atlantic SST change (NAC), the snow cover anomaly over the Eurasian continent (EUSC), and the western North Pacific outgoing longwave radiation anomaly (WNP (OLR)). Using these, three new prediction models are developed. A simple arithmetic ensemble mean produces much improved forecast skills compared to the original prediction model of Lee and Seo (2013). Skill scores measured by temporal correlation and MSSS (mean square error skill score) are improved by about 9% and 17%, respectively. The GMSS (Gerrity skill score) and hit rate based on a tercile prediction validation scheme are also enhanced by about 19% and 13%, respectively. The reversed NIO, reversed WNP (OLR), and reversed NAC are all related to the enhancement of a cyclonic circulation anomaly to the south or southwest of the Korean peninsula, which induces southeasterly moisture flux into the peninsula and increasing Changma precipitation. The EUSC predictor induces an enhancement of the Okhotsk Sea high downstream and thus strengthening of Changma front.     

North Atlantic winter eddy-driven jet and atmospheric blocking variability in the Community Earth System Model version 1 Large Ensemble simulations

Climate Dynamics - The atmospheric jet and blocking distributions, especially in the North Atlantic sector, have been challenging features for a climate model to realistically reproduce. This study...     

Rapid and Accurate Method for Determining 234Th in Seawater: Fe Co-precipitation,UTEVA Extraction,and Micro-precipitation

Ocean Science Journal - Thorium-234 (234Th; t1/2 = 24.1 days) has been widely used as a tracer of particle settling and organic carbon export in the ocean. However, the use of...     

Synthetic high-resolution near-IR spectra of the Sun for planetary data reductions made from ATMOS/Spacelab-3 and Atlas-3 data

We have constructed synthetic solar spectra for the 2302-4800 cm⁻¹ (2.08-4.34 μm) range, a spectral range where planetary objects mainly emit reflected sunlight, using ATMOS (Atmospheric Trace Molecule Spectroscopy)/Spacelab-3 and Atlas-3 spectra, of which resolution is 0.01 cm⁻¹. We adopted Voigt line profiles for the modeling of line shapes based on an atlas of line identifications compiled by Geller [Geller, M., 1992. Key to Identification of Solar Features. A High-Resolution Atlas of the Infrared Spectrum of the Sun and the Earth Atmosphere from Space. NASA Reference Publ. 1224, vol. III. NASA, Washington, DC, pp. 1-22], who derived solar line positions and intensities from contaminated high-resolution solar spectra obtained by ATMOS/Spacelab-3. Because the ATMOS spectra in these wavelength ranges are compromised by absorption lines of molecules existing in Earth's high-altitude atmosphere and in the compartment of the spacecraft, the direct use of these high-resolution solar spectra has been inconvenient for the data reductions of planetary spectra. We compared the synthetic solar spectra with the ATMOS spectra, and obtained satisfactory fits for the majority of the solar lines with the exception of abnormal lines, which do not fit with Voigt line profiles. From the model fits, we were able to determine Voigt line parameters for the majority of solar lines; and we made a list of the abnormal lines. We also constructed telluric-line-free solar spectra by manually eliminating telluric lines from the ATMOS spectra and filling the gaps with adjacent continua. These synthetic solar spectra will be useful to eliminate solar continua from spectra of planetary objects to extract their own intrinsic spectral features.     

Assimilation of streamflow and in situ soil moisture data into operational distributed hydrologic models: Effects of uncertainties in the data and initial model soil moisture states

We assess the potential of updating soil moisture states of a distributed hydrologic model by assimilating streamflow and in situ soil moisture data for high-resolution analysis and prediction of streamflow and soil moisture. The model used is the gridded Sacramento (SAC) and kinematic-wave routing models of the National Weather Service (NWS) Hydrology Laboratory’s Research Distributed Hydrologic Model (HL-RDHM) operating at an hourly time step. The data assimilation (DA) technique used is variational assimilation (VAR). Assimilating streamflow and soil moisture data into distributed hydrologic models is new and particularly challenging due to the large degrees of freedom associated with the inverse problem. This paper reports findings from the first phase of the research in which we assume, among others, perfectly known hydrometeorological forcing. The motivation for the simplification is to reduce the complexity of the problem in favour of improved understanding and easier interpretation even if it may compromise the goodness of the results. To assess the potential, two types of experiments, synthetic and real-world, were carried out for Eldon (ELDO2), a 795-km² headwater catchment located near the Oklahoma (OK) and Arkansas (AR) border in the U.S. The synthetic experiment assesses the upper bound of the performance of the assimilation procedure under the idealized conditions of no structural or parametric errors in the models, a full dynamic range and no microscale variability in the in situ observations of soil moisture, and perfectly known univariate statistics of the observational errors. The results show that assimilating in situ soil moisture data in addition to streamflow data significantly improves analysis and prediction of soil moisture and streamflow, and that assimilating streamflow observations at interior locations in addition to those at the outlet improves analysis and prediction of soil moisture within the drainage areas of the interior stream gauges and of streamflow at downstream cells along the channel network. To assess performance under more realistic conditions, but still under the assumption of perfectly known hydrometeorological forcing to allow comparisons with the synthetic experiment, an exploratory real-world experiment was carried out in which all other assumptions were lifted. The results show that, expectedly, assimilating interior flows in addition to outlet flow improves analysis as well as prediction of streamflow at stream gauge locations, but that assimilating in situ soil moisture data in addition to streamflow data provides little improvement in streamflow analysis and prediction though it reduces systematic biases in soil moisture simulation.     

The MJO and global warming: a study in CCSM4

The change in Madden–Julian oscillation (MJO) amplitude and variance in response to anthropogenic climate change is assessed in the 1° nominal resolution community climate system model, version 4 (CCSM4), which has a reasonable representation of the MJO characteristics both dynamically and statistically. The twentieth century CCSM4 run is compared with the warmest twenty-first century projection (representative concentration pathway 8.5, or RCP8.5). The last 20 years of each simulation are compared in their MJO characteristics, including spatial variance distributions of winds, precipitation and outgoing longwave radiation, histograms of event amplitude, phase and duration, and composite maps of phases. The RCP8.5 run exhibits increased variance in intraseasonal precipitation, larger-amplitude MJO events, stronger MJO rainfall in the central and eastern tropical Pacific, and a greater frequency of MJO occurrence for phases corresponding to enhanced rainfall in the Indian Ocean sector. These features are consistent with the concept of an increased magnitude for the hydrological cycle under greenhouse warming conditions. Conversely, the number of active MJO days decreases and fewer weak MJO events occur in the future climate state. These results motivate further study of these changes since tropical rainfall variability plays such an important role in the region’s socio-economic well being.