Detection of interstellar hydrogen sulfide in cold, dark clouds

We have detected interstellar hydrogen sulfide (H2S) toward the cold, dark clouds L134N and TMC 1. We derive total column densities of approximately 2.6 x 10(13) cm-2 and approximately 7.0 x 10(12) cm-2 at the SO peak of L134N and at the NH3 peak of TMC 1, respectively. Since the expected gas phase reactions leading to the formation of H2S are thought to be endothermic, grain surface reactions may play a major role in the synthesis of this species in cold, dark clouds. If the carbon abundance is high and grain surface reactions are the dominant formation route, H2CS would be expected to form instead of H2S, and the abundances of H2CS have been observed to be high where those of H2S are low in L134N and TMC 1.     

Velocity and attenuation in partially saturated rocks: poroelastic numerical experiments

We use a poroelastic modelling algorithm to compute numerical experiments on wave propagation in a rock sample with partial saturation using realistic fluid distribution patterns from tomography scans. Frequencies are in the range 10 to 500 kHz. The rock is a homogeneous isotropic sandstone partially filled with gas and water, which are defined by their characteristic values of viscosity, compressibility and density. We assume no mixing and that the two different pore-fills occupy different macroscopic regions. The von Kármán self-similar correlation function is used, employing different fractal parameters to model uniform and patchy fluid distributions, respectively, where effective saturation is varied in steps from full gas to full water saturation. Without resorting to additional matrix–fluid interaction mechanisms, we are able to reproduce the main features of the variation in wave velocity and attenuation with effective saturation and frequency, as those of published laboratory experiments. Furthermore, the behaviour of the attenuation peaks versus water saturation and frequency is similar to that of White's model. The conversion of primary P-wave energy into dissipating slow waves at the heterogeneities is shown to be the main mechanism for attenuating the primary wavefield. Fluid/gas patches are shown to affect attenuation more than equivalent patches in the permeability or solid-grain properties.     

Correcting the distortion of apparent resistivity pseudosection produced by 3D effect of the embankment geometry

Two-dimensional electrical resistivity tomography data acquired on the crest of the embankment are distorted by the 3D effect of the embankment geometry, reservoir water level and abutment. The distortion affects seriously the final solution of the 2D inverse problem. By comparing the apparent resistivity pseudosections from a 3D and 2D electrical resistivity model of the embankment, the distortion degrees of the apparent resistivity pseudosections along the axis on the crest were estimated for the cases of reservoir and which does not contain water. The obtained results indicate that the distortion degree acquired in the case of a reservoir that contains water was much less than that in the case of the reservoir that does not contain water. In the case of reservoir that contains water, the apparent resistivity pseudosections of the P–P and ED–ED arrays had the largest distortion degree and of D–D, W–S and P–D arrays had the smallest distortion degree. In the case of the reservoir that does not contain water, the apparent resistivity pseudosection of P–P array had the smallest distortion among all arrays. Through modeling investigation, a correction process to reduce the distortion of the apparent resistivity pseudosection was proposed. The correction process was tested in the embankment model, and two field works were carried out in the To Lich River in Hanoi and Khuan Cat embankment in Lang Son province, Vietnam. It is possible to bring the distortion of the apparent resistivity pseudosection down to 2.8–13.9%, depending on the type of electrode arrays and the type of reservoirs, containing or does not contain water. The distortion correction of the apparent resistivity pseudosection is strongly recommended before doing the 2D inverse interpretation.     

Geochemistry,zircon U–PB ages and HF isotopes of the Muong Luan granitoid pluton,Northwest Vietnam and its petrogenetic significance

The Indosinian Orogeny plays a significant role in tectonic background and magmatic evolution in Indochina and surrounding regions. Being a part product of the Indosinian magmatism in northwest Vietnam during late Permian–middle Triassic period, Muong Luan granitoid pluton dominantly consists of granodiorite, less diorite and granite. This pluton is located in the Song Ma suture and assigned to the Dien Bien complex. Geochemically, the Muong Luan granitoid rocks are characterized by a wide range of SiO₂ contents (59.9–75.1 wt%) and high K₂O contents. They display typical features of I‐type granites. The presence of hornblende and no muscovite and cordierite in the rocks further supports for I‐type character of granitoids. The emplacement age of the Muong Luan pluton obtained by LA–ICP–MS U–Pb zircon is at 242–235 Ma, corresponding to Indosinian time. Zircon ε_Hf values of –5.6 to –10.4, in combination with moderate Mg values of 34–45 suggested that the Muong Luan granitoid was derived from partial melting of mafic crustal source rocks, which are probably Paleoproterozoic in age as revealed by Hf model ages (T_DM2 = 1624–1923 Ma).     

Synoptic-scale physical mechanisms associated with the Mei-yu front: A numerical case study in 1999

The Mei-yu front system occurring from 23 to 27 June 1999 consists of the Mei-yu front and the dewpoint front, which confine a warm core extending from the eastern flank of the Tibetan Plateau to the west of 145°E. To further understand the synopticscale physical mechanisms associated with the Mei-yu front system, the present study proposes another insight into the physical significance of the x-component relative vorticity (XRV) whose vertical circulation is expected to tilt isentropic surfaces. The XRV equation diagnoses exhibit that the twisting effect of the planetary vorticity (TEPV) is positive along the Mei-yu front and negative in the dewpoint front region, and tilts isentropic surfaces from south to north in the Mei-yu frontal zone. Conversely, the meridional gradient of the atmospheric buoyancy (MGAB) tilts isentropic surfaces in the opposite direction and maintains negative in the regions where the TEPV is positive and vice versa. Thus, the TEPV plays the role of the Mei-yu frontogenesis, whereas the MGAB demonstrates the Meiyu frontolysis factor. Both terms control the evolution of the cross-front circulation. The other terms show much minor contributions in this case study. The present simulations also indicate that the weakening of the upper-level jet evidently induces the weakening of the Mei-yu front and reduces the amplitude of the East Asia cold trough. Furthermore, the impact can also penetrate into the lower troposphere in terms of mesoscale disturbances and precipitation, proving that the upper-level jet imposes a noticeable top-down influence on the Mei-yu front system.     

Layered tektites of southeast Asia: Field studies in central Laos and Vietnam

Abstract— We have recovered 18 kg of layered tektites from 10 tektite-bearing localities in Laos and central Vietnam, including 5 localities around the town of Muong Nong (Laos). Several of these deposits originally contained several hundred kilograms of layered tektite fragments, and one fragmented mass may have been as large as 1000 kg. This is the largest single deposit of tektites yet reported. In this region, layered tektite fragments are found in isolated clusters usually associated with a pebbly laterite horizon that is 0–1 m below the surface. Near Khe Sanh, Vietnam, we estimate the abundance of layered tektite fragments to be ～100 g/m². This is greater than five times the abundance estimated for northeast Thailand (Fiske et al., 1996). In a region that extends from northeast Thailand, through central Laos, and into central Vietnam, we found only layered tektites, which confirmed the existence of a large (>50 000 km²) subfield of the Australasian strewn field with only layered tektites. The east-west extent of the “layered-only” subfield is well constrained, but little field data exist to constrain its north-south extent.     

基于越南遥感时间序列数据的湄公河三角洲土地利用及河岸变化检测研究

通过采用先进的遥感技术,基于光学和雷达时间序列卫星影像（陆地卫星,SPOT和雷达卫星）,本文对金瓯半岛（位于湄公河三角洲南部）土地覆被变化及湄公河河岸侵蚀情况进行了检测研究。鉴于金瓯半岛典型的土地覆被类型为红树林,通过对1973-2008年红树林遥感影像分析发现,近年来红树林林地面积急剧下降,超过一半的红树林已经转变为虾养殖场。与此同时,检测发现湄公河河岸已经被严重侵蚀,且侵蚀趋势正加速恶化。具体而言,田河和口河的左右两岸被认为是遭受严重侵蚀的热点区域。本文以1966-1968年地形图作为基准线数据,与1989-2009年卫星影像数据进行比照分析,此外采用数字海岸线分析系统（DSAS）模型对未来变化趋势进行了预测。     

Flood susceptibility modelling using advanced ensemble machine learning models

Floods are one of nature's most destructive disasters because of the immense damage to land, buildings, and human fatalities.It is difficult to forecast the areas that are vulnerable to flash flooding due to the dynamic and complex nature of the flash floods.Therefore, earlier identification of flash flood susceptible sites can be performed using advanced machine learning models for managing flood disasters.In this study, we applied and assessed two new hybrid ensemble models, namely Dagging and Random Subspace(RS) coupled with Artificial Neural Network(ANN), Random Forest(RF), and Support Vector Machine(SVM) which are the other three state-of-the-art machine learning models for modelling flood susceptibility maps at the Teesta River basin, the northern region of Bangladesh.The application of these models includes twelve flood influencing factors with 413 current and former flooding points, which were transferred in a GIS environment.The information gain ratio, the multicollinearity diagnostics tests were employed to determine the association between the occurrences and flood influential factors.For the validation and the comparison of these models, for the ability to predict the statistical appraisal measures such as Freidman, Wilcoxon signed-rank, and t-paired tests and Receiver Operating Characteristic Curve(ROC) were employed.The value of the Area Under the Curve(AUC) of ROC was above 0.80 for all models.For flood susceptibility modelling, the Dagging model performs superior, followed by RF,the ANN, the SVM, and the RS, then the several benchmark models.The approach and solution-oriented outcomes outlined in this paper will assist state and local authorities as well as policy makers in reducing flood-related threats and will also assist in the implementation of effective mitigation strategies to mitigate future damage.     

越南西北部莱州地区新生代煌斑岩地球化学特征及其成因

越南西北部菜州地区出露的新生代煌斑岩岩脉对理解特提斯造山带东段的深部岩石圈特征和演化具有重要的地质意义.本文报道莱州地区煌斑岩的元素地球化学和Sr-Nd-Pb同位素组成特征,探讨其岩石成因.该地区煌斑岩属于钙碱性,钾质-超钾质煌斑岩特征.地球化学特征对比表明,菜州地区煌斑岩与哀牢山断裂带碱性岩具有相似的地球化学特征,但与海南和越南南部火山岩存在明显差异.分析结果表明,煌斑岩具有高的87Sr/86Sr比值、低143Nd/144Nd比值和高放射性成因Pb同位素组成特征.岩石的微量元素组成特征指示,形成煌斑岩的地幔源区可能经历过流体交代作用或沉积物组分的加入.低208Pb*/206Pb*比值暗示地幔源区富集事件是近期发生的,可能与晚古生代-早中生代印支地块向扬子地块俯冲事件有关.     

Antibiotics in the Hong Kong metropolitan area: Ubiquitous distribution and fate in Victoria Harbour

We investigated the presence and fate of 16 antibiotics belonging to seven groups (β-lactams, fluoroquinolones, macrolides, sulfonamides, tetracyclines, trimethoprim and amphenicols) in effluents of sewage plants and receiving waters in Hong Kong. Cefalexin, amoxicillin, ofloxacin and erythromycin-H₂O were ubiquitous in sea water throughout Victoria Harbour, indicating continuous discharge to the environment. This is one of the few studies reporting the frequent occurrence of cefalexin and amoxicillin in sewage effluents and sea water (170-5070 and 64-1670 ng/L in sewage; 6.1-493 and 0.64-76 ng/L in sea water, respectively). Mass flows from seven sewage plants discharged an estimated total of 14.4 kg/day to the Harbour. Typhoon shelters also appeared to play an important role as sources of antibiotics, as evidenced by elevated concentrations within their boundaries. Mass balance estimations suggested significant quantities of antibiotics are discharged to the Harbour without passage through treatment plants.