Stratigraphy and geochemistry of pillow basalts within the ophiolitic mélange of the Izmir–Ankara–Erzincan suture zone: implications for the geotectonic character of the northern branch of Neotethys

The Izmir-Ankara-Erzincan suture zone of Turkey is a broad zone of ophiolitic mélange containing numerous fragmented blocks ranging in age from Triassic to Cretaceous. Stratigraphic sequences for various mélange units are compared, together with the geochemistry of associated basaltic pillow lavas of Cretaceous age. A review of geochemical data for the pillow lavas demonstrate: (a) a dominant group of alkalic basalts with enriched incompatible elements, variable Zr/Y and Zr/Nb ratios, and (b) a range of tholeiitic basalts with slightly depleted to mildly enriched (normalized) rare earth patterns, (La/Yb)_N 0.4-3.0, and generally low Zr/Y ratios. The alkalic basalts can be chemically matched to Pacific Ocean seamounts, although the close association of red radiolarites and cherts suggests that many basalts represent the margins of such structures, rather than the main seamount edifice. Nd-Sr isotope data are typical for ocean island basalts and represent an admixture of a dominant EM-1 source and a depleted MORB-like source. Enhanced δ¹⁸O compositions are a consequence of submarine alteration and not crustal contamination. Tholeiitic compositions have affinities with both N- and E-type MORB, although most are probably representative of tholeiitic ocean islands. Overall the basalts are mainly representative of structures built on the ocean floor, rather than the oceanic crust itself, being scraped off the subducting crust and preserved in the mélange of the accretionary wedge.     

Spatially-Averaged Temperature Structure Parameter Over a Heterogeneous Surface Measured by an Unmanned Aerial Vehicle

The structure parameter of temperature, \({C_{T}^{2}}\) , in the lower convective boundary layer was measured using the unmanned mini aerial vehicle M²AV. The measurements were carried out on two hot summer days in July 2010 over a heterogeneous land surface around the boundary-layer field site of the Lindenberg Meteorological Observatory—Richard-Aßmann-Observatory of the German Meteorological Service. The spatial series of \({C_{T}^{2}}\) showed considerable variability along the flight path that was caused by both temporal variations and surface heterogeneity. Comparison of the aircraft data with \({C_{T}^{2}}\) values derived from tower-based in situ turbulence measurements showed good agreement with respect to the diurnal variability. The decrease of \({C_{T}^{2}}\) with height as predicted by free-convection scaling could be confirmed for the morning and afternoon flights while the flights around noon suggest a different behaviour.     

Evaluating the Sensitivity of Image Fusion Quality Metrics to Image Degradation in Satellite Imagery

Referring to the high potential of topographic satellite in collecting high resolution panchromatic imagery and high spectral, multi spectral imagery, the purpose of image fusion is to produce a new image data with high spatial and spectral characteristics. It is necessary to evaluate the quality of fused image by some quality metrics before using this product in various applications. Up to now, several metrics have been proposed for image quality assessment; which are also applicable for quality evaluation of fused images. However, it seems more investigations are needed to inspect the potentials of proposed Image Fusion Quality Metrics (IFQMs) to registration accuracy, especially in high resolution satellite imagery. This paper focuses on such studies and, using different image fusion quality metrics, experiments are conducted to evaluate the sensitivity of such metrics to a set of high resolution satellite imagery covering urban areas. The obtained results clearly reveal that these metrics sometimes do not behave robust in the whole area and also their obtained results are inconsistence in different patch areas in comparison with the whole image. These limitations are in minimum situation for an image quality metric such as SAM and are completely tangible for image quality metrics such as ERGAS in case of multi modal and DIV and CC from mono modal category.     

Archaean high-K granitoids produced by remelting of earlier Tonalite–Trondhjemite–Granodiorite (TTG) in the Sangmelima region of the Ntem complex of the Congo craton,southern Cameroon

We present a geochemical and isotopic study that, consistent with observed field relations, suggest Sangmelima late Archaean high-K granite was derived by partial melting of older Archaean TTG. The TTG formations are sodic-trondhjemitic, showing calcic and calc-alkalic trends and are metaluminous to peraluminous. High-K granites in contrast show a potassic calc-alkaline affinity that spans the calcic, calc-alkalic, alkali-calcic and alkalic compositions. The two rock groups (TTG and high-K granites) on the other hand are both ferroan and magnesian. They have a similar degree of fractionation for LREE but a different one for HREE. Nd model ages and Sr/Y ratios define Mesoarchaean and slab-mantle derived magma compositions respectively, with Nb and Ti anomalies indicating a subduction setting for the TTG. Major and trace element in addition to Sr and Nd isotopic compositions support field observations that indicate the derivation of the high-K granitic group from the partial melting of the older TTG equivalent at depth. Geochemical characteristics of the high-K granitic group are therefore inherited features from the TTG protolith and cannot be used for determining their tectonic setting. The heat budget required for TTG partial melting is ascribed to the upwelling of the mantle marked by a doleritic event of identical age as the generated high-K granite melts. The cause of this upwelling is related to linear delamination along mega-shear zones in an intracontinental setting.     

Dependence of radon exhalation on grain size of sedimentary waste

Tailings resulted from sulphuric acid leaching process of uranium from sedimentary rocks contain high concentrations of ²²⁶Ra and its daughters, the most important of which is ²²²Rn. Movement of radon gas out of the tailings is strongly influenced by the physicochemical characteristics of these tailings especially their radium content and the grain size. So, the tailing samples were size fractionated into four sizes (>?250, 250–125, 125–74 and <?74 µm). The natural radioactivity was investigated using hyper-pure germanium detector and solid-state nuclear track detectors (CR-39) for bulk size and after size fractionation. The activity concentrations of different radionuclides in size-fractionated tailing samples have been shown to be strongly dependent on the size of the particles. In the range of >?250 and <?74 µm, the activity concentrations of ²³⁰Th, ²²⁶Ra, ²¹⁴Pb, ²¹⁴Bi, ²¹⁰Pb, ²³²Th and ⁴⁰K increased throughout with decreasing particle size, while that of ²³⁸U, ²³⁴U and ²³⁵U have an opposite effect. The results revealed an inverse relationship between the radon exhalation rate and size fractionation. Also, the results showed a good correlation between radium activity concentration and radon mass exhalation rate.     

Tidal Marsh Restoration Design Affects Feedbacks Between Inundation and Elevation Change

Tidal marsh (re)creation on formerly embanked land is increasingly executed along estuaries and coasts in Europe and the USA, either by restoring complete or by reduced tidal exchange. Ecosystem functioning and services are largely affected by the hydro-geomorphologic development of these areas. For natural marshes, the latter is known to be steered by feedbacks between tidal inundation and sediment accretion, allowing marshes to reach and maintain an equilibrium elevation relative to the mean sea level. However, for marsh restoration sites, these feedbacks may be disturbed depending on the restoration design. This was investigated by comparing the inundation-elevation change feedbacks in a natural versus restoration site with reduced tidal exchange in the Scheldt estuary (Belgium). This study analyzes long-term (9 years) datasets on elevation change and tidal inundation properties to disentangle the different mechanisms behind this elevation-inundation feedback. Moreover, subsequent changes in sediment properties that may affect this feedback were explored. In the restoration area with reduced tidal exchange, we found a different elevation-inundation feedback than on natural marshes, which is a positive feedback on initially high sites (i.e., sediment accretion leads to increasing inundation, hence causing accelerating sediment accretion rates) and a gradual silting up of the whole area. Furthermore, there is evidence for the presence of a relict consolidated sediment layer. Consequently, shallow subsidence is less likely to occur. Although short-term ecological development of the tidal marsh was not impeded, long-term habitat development may be affected by the differences in hydro-geomorphological interactions. An increase of inundation frequency on the initially high sites may cause inhibition of habitat succession or even reversed succession. Over time, the climax state of the restoration area may be different compared to natural marshes. Moreover, sediment-related ecosystem services, such as nutrient and carbon burial, may be positively influenced because of continuing sedimentation, although flood water storage potential will decrease with increasing elevation. Depending on the restoration goals, ecosystem trajectories and delivery of ecosystem services can be controlled by adaptive management of the tidal volume entering the restoration area.     

Effects of mesoscale sea-surface temperature fronts on the marine atmospheric boundary layer

A numerical modelling study is presented focusing on the effects of mesoscale sea-surface temperature (SST) variability on surface fluxes and the marine atmospheric boundary-layer structure. A basic scenario is examined having two regions of SST anomaly with alternating warm/cold or cold/warm water regions. Conditions upstream from the anomaly region have SST values equal to the ambient atmosphere temperature, creating an upstream neutrally stratified boundary layer. Downstream from the anomaly region the SST is also set to the ambient atmosphere value. When the warm anomaly is upstream from the cold anomaly, the downstream boundary layer exhibits a more complex structure because of convective forcing and mixed layer deepening upstream from the cold anomaly. An internal boundary layer forms over the cold anomaly in this case, generating two distinct layers over the downstream region. When the cold anomaly is upstream from the warm anomaly, mixing over the warm anomaly quickly destroys the shallow cold layer, yielding a more uniform downstream boundary-layer vertical structure compared with the warm-to- cold case. Analysis of the momentum budget indicates that turbulent momentum flux divergence dominates the velocity field tendency, with pressure forcing accounting for only about 20% of the changes in momentum. Parameterization of surface fluxes and boundary-layer structure at these scales would be very difficult because of their dependence on subgrid-scale SST spatial order. Simulations of similar flow over smaller scale fronts (<5 km) suggest that small-scale SST variability might be parameterized in mesoscale models by relating the effective heat flux to the strength of the SST variance.     

Preparation of integrative cubes as a novel biological permeable reactive barrier medium for the enhancement of in situ aerobic bioremediation of nitrobenzene-contaminated groundwater

Recent studies have indicated that in situ aerobic bioremediation is one of the most effective methods for remediating groundwater contaminated with nitrobenzene (NB). Aerobic bioremediation is largely dependent on the maintenance of adequate dissolved oxygen (DO) levels in the groundwater. Traditional in situ aeration has various disadvantages, such as high operational costs and nonuniform aeration. In this study, integrative cubes were prepared and utilized as a novel biological permeable reactive barrier (bio-PRB) medium to enhance the aerobic bioremediation of NB-contaminated groundwater. The results revealed an NB removal rate greater than 98.68% after 15–20 days of continuous oxygen release from the bio-PRB medium. DO concentrations reached 8.0 mg/L during treatment, and NB-degrading bacteria were able to tolerate a range of pH conditions. This multifaceted bio-PRB medium can simultaneously adsorb and biodegrade NB, release oxygen, and neutralize the pH with phosphate buffer. The results of this study suggest that this bio-PRB medium represents a highly effective in situ bioremediation method for NB-contaminated groundwater.     

An experimental study on variation of <Emphasis Type="Italic">b</Emphasis> value during deformation of rock samples with different structural models

A preliminary study of b value of rocks with two kinds of structural models has been made on the base of a new acoustic emission recording system. It shows that b value of the sample decreases obviously when the sample with compressive en echelon faults changes into a tensile one after interchange occurs between stress axis σ ₁ and σ ₂. A similar experiment is observed when the sample with tensile en echelon faults changes into that with a bend fault after two segments of the en echelon fault linking up. These facts indicate that the variation of b value may contain the information of the regional dominant structural model. Therefore, b-value analyses could be a new method for studying regional dominant structural models.     

A Parameterization of Dry Thermals and Shallow Cumuli for Mesoscale Numerical Weather Prediction

For numerical weather prediction models and models resolving deep convection, shallow convective ascents are subgrid processes that are not parameterized by classical local turbulent schemes. The mass flux formulation of convective mixing is now largely accepted as an efficient approach for parameterizing the contribution of larger plumes in convective dry and cloudy boundary layers. We propose a new formulation of the EDMF scheme (for Eddy Diffusivity\Mass Flux) based on a single updraft that improves the representation of dry thermals and shallow convective clouds and conserves a correct representation of stratocumulus in mesoscale models. The definition of entrainment and detrainment in the dry part of the updraft is original, and is specified as proportional to the ratio of buoyancy to vertical velocity. In the cloudy part of the updraft, the classical buoyancy sorting approach is chosen. The main closure of the scheme is based on the mass flux near the surface, which is proportional to the sub-cloud layer convective velocity scale w _*. The link with the prognostic grid-scale cloud content and cloud cover and the projection on the non- conservative variables is processed by the cloud scheme. The validation of this new formulation using large-eddy simulations focused on showing the robustness of the scheme to represent three different boundary layer regimes. For dry convective cases, this parameterization enables a correct representation of the countergradient zone where the mass flux part represents the top entrainment (IHOP case). It can also handle the diurnal cycle of boundary-layer cumulus clouds (EUROCS\ARM) and conserve a realistic evolution of stratocumulus (EUROCS\FIRE).