Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.     

江西省永平铜矿西部排土场极限堆载高度确定

国内外对排土场极限堆载高度的理论计算缺乏研究,目前尚无成熟的统一理论计算方法。文章结合永平铜矿西部排土场的工程实例,在进行边坡工程地质条件勘察与排土场岩土物理力学性质试验研究的基础上,采用数值计算方法对排土场进行了分层堆载数值模拟计算。通过对计算结果的分析,得到位移、塑性区与安全系数随堆载高度的变化规律,并确定了该排土场的极限堆载高度。     

Estimating hydraulic conductivity using grain-size analyses, aquifer tests, and numerical modeling in a riverside alluvial system in South Korea

Hydraulic conductivity (K) for an alluvial system in a riverbank filtration area in Changwon City, South Korea, has been studied using grain-size distribution, pumping and slug tests, and numerical modeling. The alluvial system is composed of layers: upper fine sand, medium sand, lower fine sand, and a highly conductive sand/gravel layer at the base. The geometric mean of K for the sand/gravel layer (9.89?×?10^?4 m s^?1), as determined by grain-size analyses, was 3.33 times greater than the geometric mean obtained from pumping tests (2.97?×?10^?4 m s^?1). The geometric mean of K estimates obtained from slug tests (3.08?×?10^?6 m s^?1) was one to two orders of magnitude lower than that from pumping tests and grain-size analyses. K estimates derived from a numerical model were compared to those derived from the grain-size methods, slug tests and pumping tests in order to determine the degree of deviation from the numerical model. It is considered that the K estimates determined by the slug tests resemble the uppermost part of the alluvial deposit, whereas the K estimates obtained by grain-size analyses and pumping tests are similar to those from the numerical model for the sand/gravel layer of the riverside alluvial system.     

GPS CORS系统中NTRIP传输技术的应用研究

NTRIP是一种播发实时差分定位改正信息的IP协议。本文讨论了NTRIP的组成、工作原理,并给出一个应用实例。     

一种基于双重距离的空间聚类方法

传统聚类方法大都是基于空间位置或非空间属性的相似性来进行聚类,分裂了空间要素固有的二重特性,从而导致了许多实际应用中空间聚类结果难以同时满足空间位置毗邻和非空间属性相近。然而,兼顾两者特性的空间聚类方法又存在算法复杂、结果不确定以及不易扩展等问题。为此,本文通过引入直接可达和相连概念,提出了一种基于双重距离的空间聚类方法,并给出了基于双重距离空间聚类的算法,分析了算法的复杂度。通过实验进一步验证了基于双重距离空间聚类算法不仅能发现任意形状的类簇,而且具有很好的抗噪性。     

Genesis of monazite and Y zoning in garnet from the Black Hills, South Dakota

The paragenesis of monazite in metapelitic rocks from the contact aureole of the Harney Peak Granite, Black Hills, South Dakota, was investigated using zoning patterns of monazite and garnet, electron microprobe dating of monazite, bulk-rock compositions, and major phase mineral equilibria. The area is characterized by low-pressure and high-temperature metamorphism with metamorphic zones ranging from garnet to sillimanite zones. Garnet porphyroblasts containing euhedral Y annuli are observed from the garnet to sillimanite zones. Although major phase mineral equilibria predict resorption of garnet at the staurolite isograd and regrowth at the andalusite isograd, textural and mass balance analyses suggest that the formation of the Y annuli is not related to the resorption-and-regrowth of garnet having formed instead during garnet growth in the garnet zone. Monazite grains in Black Hills pelites were divided into two generations on the basis of zoning patterns of Y and U: monazite 1 with low-Y and -U and monazite 2 with high-Y and -U. Monazite 1 occurs in the garnet zone and persists into the sillimanite zone as cores shielded by monazite 2 which starts to form in the andalusite zone. Pelites containing garnet porphyroblasts with Y annuli and monazite 1 with patchy Th zoning are more calcic than those with garnet with no Y annuli and monazite with concentric Th zoning. Monazite 1 is attributed to breakdown of allanite in the garnet zone, additionally giving rise to the Y annuli observed in garnet. Monazite 2 grows in the andalusite zone, probably at the expense of garnet and monazite 1 in the andalusite and sillimanite zones. The ages of the two different generations of monazite are within the precision of chemical dating of electron microprobe. The electron microprobe ages of all monazites from the Black Hills show a single ca. 1713 Ma population, close to the intrusion age of the Harney Peak Granite (1715 Ma). This study demonstrates that Y zoning in garnet and monazite are critical to the interpretation of monazite petrogenesis and therefore monazite ages.     

Modeling of rainfall-triggered shallow landslide

By integrating hydrological modeling with the infinite slope stability analysis, a rainfall-triggered shallow landslide model was developed by Iverson (Water Resour Res 36:1897-1910, 2000). In Iverson’s model, the infiltration capacity is assumed to be equivalent to the saturated hydraulic conductivity for finding pressure heads analytically. However, for general infiltration process, the infiltration capacity should vary with time during the period of rain, and the infiltration rate is significantly related to the variable infiltration capacity. To avoid the unrealistically high pressure heads, Iverson employed the beta-line correction by specifying that the simulated pressure heads cannot exceed those given by the beta line. In this study, the suitability of constant infiltration capacity together with the beta-line correction for hydrological modeling and landslide modeling of hillslope subjected to a rainfall is examined. By amending the boundary condition at ground surface of hillslope in Iverson’s model, the modified Iverson’s model with considering general infiltration process is developed to conduct this examination. The results show that the unrealistically high pressure heads from Iverson’s model occur due to the overestimation of infiltration rate induced from the assumption that the infiltration capacity is identical to the saturated hydraulic conductivity. Considering with the general infiltration process, the modified Iverson’s model gives acceptable results. In addition, even though the beta-line correction is applied, the Iverson’s model still produces greater simulated pressure heads and overestimates soil failure potential as compared with the modified Iverson’s model. Therefore, for assessing rainfall-triggered shallow landslide, the use of constant infiltration capacity together with the beta-line correction needs to be replaced by the consideration of general infiltration process.     

Ammonium regeneration in intertidal sediments of the Yangtze estuary during air-exposure

The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification rate (˜500 nmol N cm⁻³ day⁻¹), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×10⁵ t N year⁻¹ in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to the estuarine ecosystem.