The Oneka intrusive complex: a new structural type of large-scale manifestations of intrusive trap magmatism on the Siberian Platform

The Oneka intrusive complex, recognized on prospecting for hydrocarbons in the western Siberian Platform, in the northern half of the Bakhta megablock (Tunguska syneclise), holds a special position among the known and new large-scale manifestations of intrusive trap magmatism. During the process, original data on the distribution of traps in the 4.2 km thick platform cover were obtained. Diverse in morphology and size, the intrusions are of the same genesis, composition, and character of intrachamber differentiation and form a “framework” igneous complex in the northern half of the Bakhta megablock. This complex occupies an area of about 40,000 km². It is an intricate tectonomagmatic superstructure, with the volume of magmatic material estimated at 50,000 km³. Results of petrochemical and geochemical studies, multispectra and REE ratios, and isotope ratios ⁸⁷Sr/⁸⁶Sr (0.70558–0.70580) suggest that diverse rocks of the Oneka intrusive complex were, most likely, formed from a primary picritoid magma, which underwent deep-level differentiation and was slightly contaminated with rocks of the crust and platform cover. The comprehensive study of the massif and results of numerical modeling show that the formation of such tectonomagmatic structures is closely related to the processes of intraplate magma formation in the craton lithosphere. The large Oneka intrusive complex, like other similar manifestations of Permo-Triassic trap (and alkaline-ultrabasic) magmatism of the Siberian Platform, can be considered projections of hotspots recording the evolution of the Siberian superplume.     

New insights into the crustal structure of the North German Basin from reprocessing of seismic reflection data using the Common Reflection Surface stack

The influence of deep crustal processes on basin formation and evolution and its relation to current morphology is not well understood yet. A key feature to unravel these issues is a detailed seismic image of the crust. A part of the data recorded by the hydrocarbon industry in the late 1970s and 1980s in the North German Basin were released to the public recently. The seismic reflection data were recorded down to 15 s two-way travel time. The mean Common Midpoint fold of about 20 is relatively low compared to contemporary seismic acquisitions. The processing of the 1980s focussed on the sedimentary structures to explore the hydrocarbon potential of this area. We applied the Common Reflection Surface stack technique to the data sets, which is well suited for low-fold data. The reprocessing was focussed on the imaging of the subsedimentary crustal range. The reprocessed images show enhanced reflections, especially in the mid and lower crustal part. Also, the image of the salt structures in the graben area was improved. Furthermore, the reprocessed images indicate an almost flat Moho topography in the area of the Glückstadt Graben and an additional lower crustal structure, which can be correlated with a high-density body found in recent gravity modeling studies.     

Mineralogical and geochemical investigation of clay-rich mine tailings from a closed phosphate mine, Bartow Florida, USA

Clay-rich mine tailings from phosphate mine operations in Florida are a major environmental and economic problem. Options for reclamation and restoration for these tailings are very limited and are fundamentally restricted by poor physical properties such as low mechanical strength, low hydraulic conductivity, and heavy metal content. The major control on these bulk physical properties is the mineralogy of the materials. Eight continuous push borings were obtained to investigate stratigraphy, mineralogy, aspects of geochemistry, and bulk properties of a deposit of clay-rich mine tailings from a phosphate mine near Bartow, Florida that ceased operations in the early 1970s. Stratigraphy is dominated by laminated clay-rich sediment with minor units of silt and sand. An intact kaolinite liner occurs near the impoundment walls and the impoundment floor has approximately 4 m of relief. Moisture content varies from 4.35 to 57.40 wt% and organic content varies from 0.41 to 9.53 wt%. Bulk XRF investigation indicates that the P₂O₅ concentrations vary from approximately 4 to 21 wt%. A very strong correlation (r ² = 0.92) between CaO and P₂O₅ indicates that apatite is a major control on the phosphate. The strong correlation (r ² = 0.77) of Al₂O₃ and TiO₂ suggests that the source materials for this deposit are comparatively uniform. A number of heavy metal elements and trace elements occur. Cr, V, Ni, Cu are interpreted to be in phosphate minerals, largely apatite. Sr and Pb are interpreted to be in both phyllosilicates and phosphate minerals. Two populations of apatite were observed in the clay-sized fraction, one that was Fe and Si- bearing and another that was only Si-bearing. Fe-bearing apatite had Fe₂O₃ contents that varied from 0.38 to 5.32 wt% and SiO₂ contents that varied from 0.90 to 3.32 wt%. The other apatite population had a wider range of SiO₂ contents that varied from 0.77 to 8.80 wt%. TEM imaging shows that apatite grains are dominantly single crystals with lesser amounts of aggregates. Wavellite commonly occurs as individual or clusters of lath-like crystals and the chemical composition differs from the pure aluminium phosphate end member with average concentrations of components being that of CaO (1.57 wt%), Fe₂O₃ (1.98 wt%), SiO₂ (5.94 wt%). In the clay-sized phosphate minerals investigated no fluorine was found above detection limit (approximately 0.15 wt%), nor was any uranium, radium, heavy metal, or REE element detected. The phyllosilicate mineralogy of the deposit is dominated by smectite (montmorillonite with lesser amounts of nontronite), palygorskite, illite and kaolinite. No systematic variation in the relative proportions of phyllosilicates was observed in the clay deposit. Energy dispersive spectroscopy EDS analysis indicates that chemical compositions of phyllosilicates are somewhat typical but overall are enriched with respect to Fe compared to theoretical end members. The relative enrichment of Fe is interpreted to be a primary sedimentary feature. Ca content in smectite minerals is high and may inhibit stabilization using lime or similar methods. The high percentages of montmorillonite and palygorskite explain the high bulk water contents observed. This investigation provides fundamentally new details regarding clay tailing deposits from closed phosphate mines in central Florida which can be used in restoration and reclamation efforts.     

Development of sedimentary basins: differential stretching,phase transitions,shear heating and tectonic pressure

Classical models of lithosphere thinning predict deep synrift basins covered by wider and thinner post‐rift deposits. However, synextensional uplift and/or erosion of the crust are widely documented in nature (e.g. the Base Cretaceous unconformity of the NE Atlantic), and generally the post‐rift deposits dominate basins fills. Accordingly, several basin models focus on this discrepancy between observations and the classical approach. These models either involve differential thinning, where the mantle thins more than the crust thereby increasing average temperature of the lithosphere, or focus on the effect of metamorphic reactions, showing that such reactions decrease the density of lithospheric rocks. Both approaches result in less synrift subsidence and increased post‐rift subsidence. The synextensional uplift in these two approaches happens only for special cases, that is for a case of initially thin crust, specific mineral assemblage of the lithospheric mantle or extensive differential thinning of the lithosphere. Here, we analyse the effects of shear heating and tectonic underpressure on the evolution of sedimentary basins. In simple 1D models, we test the implications of various mechanisms in regard to uplift, subsidence, density variations and thermal history. Our numerical experiments show that tectonic underpressure during lithospheric thinning combined with pressure‐dependent density is a widely applicable mechanism for synextensional uplift. Mineral phase transitions in the subcrustal lithosphere amplify the effect of underpressure and may result in more than 1 km of synextensional erosion. Additional heat from shear heating, especially combined with mineral phase transitions and differential thinning of the lithosphere, greatly decreases the amount of synrift deposits.     

Evidence for the zircon origin of cadmium anomalies in bottom sediments from the littoral zone of the northern part of Lake Ladoga

The minor-element composition of bottom sediments from the littoral zone of the northern part of Lake Ladoga was studied. Close relationships between the anomalous Cd concentrations in lake sediments and Quaternary glacial formations on the territory of Karelia were shown. A negative correlation of Cd with other heavy metals and a positive correlation with Zr were observed. Most likely, Cd is an impurity in zircons from sandy and sandy loam sedimentary formations on the northern coastal area of Lake Ladoga.     

Fluxes of iron and manganese across the sediment–water interface under various redox conditions

Fluxes of dissolved forms of iron and manganese across the sediment–water interface were studied in situ in the Gulf of Finland and the Vistula Lagoon (Baltic Sea), and in the Golubaya Bay (Black Sea) from 2001 to 2005. Fluxes were measured using chamber incubations, and sediment cores were collected and sliced to assess the porewater and solid phase metal distribution at different depths. Measured and calculated benthic fluxes of manganese and iron were directed out of sediment for all sites and were found to vary between 70–4450 and 5–1000 µmole m^− 2 day^− 1 for manganese and iron, respectively. The behavior of the studied metals at various redox conditions in the near-bottom water and in the sediment was the main focus in this study. Our results show the importance of bottom water redox conditions for iron fluxes. We measured no fluxes at oxic conditions, intermediate fluxes at anoxic conditions (up to 200 μmole m^− 2 day^− 1) and high fluxes at suboxic conditions (up to 1000 μmole m^− 2 day^− 1). Total dissolved iron fluxes were generally dominated by iron(II). Contribution of iron(III) to the total iron flux did not exceed 20%. Obtained fluxes of manganese at all studied regions showed a linear correlation (r² = 0.97) to its concentration in the porewater of the top sediment layer (0–5 mm) and did not depend on dissolved oxygen concentrations of bottom water. Organically complexed iron and manganese were in most cases not involved in the benthic exchange processes.     

WSO-UV—ultraviolet mission for the next decade

The World Space Observatory UltraViolet (WSO–UV) is an international space mission devoted to UV spectroscopy and imaging. The observatory includes a 170 cm aperture telescope capable of high-resolution and long slit low-resolution spectroscopy, and deep UV and optical imaging. The observatory is designed for observations in the ultraviolet domain where most of astrophysical processes can be efficiently studied with unprecedented capability.     

On the composition and differentiation of Ceres

The dwarf planet Ceres has a density of 2040-2250 kg m⁻³, and a dark non-icy surface with signs of hydrated minerals. As opposed to a differentiated internal structure with a nonporous rocky core and a water mantle, there are arguments for undifferentiated porous interior structure. Ceres’ mass and dimensions are uncertain and do not exclude undifferentiated interior even if hydrostatic equilibrium is attained. The rocky surface may be inconsistent with a large-scale water-rock differentiation. A differentiated structure with a thick water mantle below a rocky crust is gravitationally unstable and an overturn would have led to abundant surface salt deposits, which are not observed. A formation of hydrated surface minerals caused by internal heating implies a major density increase through devolatilization of the interior. A later accumulation of hydrated materials is inconsistent with anhydrous surfaces of many asteroids and with a low rate of the cosmic dust deposition in the inner Solar System. Ceres’ internal pressures (<140-200 MPa) are insufficient to significantly reduce porosity of chondritic materials and there is no need for abundant water phases to be present to account for the bulk density. Having the porosity of ordinary chondrites (∼10%), Ceres can consist of rocks with the grain density of pervasively hydrated CI carbonaceous chondrites. However, additional low-density phases (e.g., water ice) require to be present in the body with the grain density of CM chondrites. The likely low-density mineralogy of the interior implies Ceres’ accretion from pervasively aqueously altered carbonaceous planetesimals depleted in short-lived radionuclide ²⁶Al. Abundant water ice may not have accreted. Limited heat sources after accretion may not have caused major mineral dehydration leading to formation of water mantle. These inferences can be tested with the Dawn spacecraft in 2015.     

Carbonization and geochemical characteristics of graphite-bearing rocks in the northern Khanka terrane,primorie, Russian Far East

Regional carbonization was examined in Riphean metamorphic complexes in the northern part of the Khanka terrane. The results obtained by various techniques of physicochemical analysis indicate that all petrographic rock varieties of this complex bear elevated concentrations (from 10⁻⁴ to 10⁻⁶ wt %) of Au and PGE. XRF data were used to describe a wide spectrum of trace elements: Ti, V, Ni, Cr, Pt, Pd, Re, Rh, Os, Ir, Cu, Hg, Au, Ag, Ta, Nb, Sr, Rb, Zr, La, W, Sn, Pb, and Zn. The Rb/Sr-Ba diagram shows the fields of anatectic granite-gneisses, biotite granites, lamprophyres, graphitized crystalline schists, black shales, skarns, and quartz-graphite metasomatic rocks. The C isotopic composition in graphite from the metaigneous rocks (lamprophyres and crystalline schists of the amphibolite facies) corresponds to δ¹³C from −8.5 to −8.7‰, which suggests that the carbon could be of endogenic provenance. The carbon isotopic composition of the greenschist-facies black shales corresponds to δ¹³C from −19.9 to −26.6‰, as is typical of organogenic carbon. The concentrations of precious metals in the rocks are, on average, one order of magnitude lower than in the graphitized crystalline schists. The origin of the precious-metal ore mineralization was likely genetically related to the regional carbonization process.