The western Durkan Complex (Makran Accretionary Prism,SE Iran): A Late Cretaceous tectonically disrupted seamounts chain and its role in controlling deformation style

The Durkan Complex is a key tectonic element of the Makran accretionary prism (SE Iran) and it has been interpreted as representing a continental margin succession. We present here a multidisciplinary study of the western Durkan Complex, which is based on new geological, stratigraphic, biostratigraphic data, as well as geochemical data of the volcanic and meta-volcanic rocks forming this complex. Our data show that this complex consists of distinct tectonic slices showing both non-metamorphic and very low-grade metamorphic deformed successions. Stratigraphic and biostratigraphic data allow us to recognize three types of successions. Type-I is composed by a Coniacian – early Campanian pelagic succession with intercalation of pillow lavas and minor volcaniclastic rocks. Type-II succession includes a volcanic sequence passing to a volcano-sedimentary sequence with Cenomanian pelagic limestones, followed by a hemipelagic sequence. This succession is characterized by abundant mass-transport deposits. Type-III succession includes volcanic and volcano-sedimentary sequences, which are stratigraphically covered by a Cenomanian platform succession. The latter is locally followed by a hemipelagic sequence. The volcanic rocks in the different successions show alkaline geochemical affinity, suggesting an origin from an oceanic within-plate setting. Our new results indicate that the western Durkan Complex represents fragments of seamounts tectonically incorporated in the Makran accretionary wedge during the latest Late Cretaceous–Paleocene. We propose that incorporation of seamounts in the frontal prism caused a shortening of the whole convergent margin and possibly contributed to controlling the deformation style in the Makran Accretionary Wedge during Late Cretaceous–Paleocene times.     

Comparison of statistical methods and multi-time validation for the determination of the shallow landslide rainfall thresholds

Shallow landslides are unforeseeable phenomena often resulting in critical conditions in terms of people’s safety and damage. The main purpose of this paper is the comparison of different statistical methods used to determine the rainfall thresholds for the shallow landslide occurrence. Rainfall data over a 46-year period were collected for one rain gauge located in a test area of northwest Italy (Riviera Spezzina; RS). In the RS, intense rainfalls often induce shallow landslides causing damage and sometimes casualties. The rainfall events occurred in the 1967–2006 period were classified as events inducing shallow landslides (SLEs_1967–2006) and events that did not trigger shallow landslides (NSLEs_1967–2006). Thresholds for various percentiles of SLEs_1967–2006 were computed by identifying the lower limit above which shallow landslides occurred. Another set of thresholds, corresponding to different probabilities of occurrence, was determined using SLEs_1967–2006 and NSLEs_1967–2006. The least-squares linear fit (LSF) and the quantile regression (QR) techniques were employed in the former approach, while the logistic regression (LR) was applied in the latter. The thresholds were validated with the same data used for their definition and with the data recorded in the 2008–2014 period. Contingency tables were created and contingencies and skill scores were computed. The 10% probability threshold obtained using the LR method is characterized by the best values of at least two skill scores for both periods considered; therefore, it may be considered the “best” threshold for the RS. The results of this work can help the choice of the best statistical method to determine the shallow landslide rainfall thresholds.     

LARAM School 2018: the doctoral school on “LAndslide Risk Assessment and Mitigation”

The international school for PhD students and young doctors on “LAndslide Risk Assessment and Mitigation” (LARAM) is presented and, specifically, information is provided about the next edition of the doctoral school that will held in Italy, at the University of Salerno, on September 3–14, 2018. The LARAM School is managed by the Geotechnical Engineering Group (GEG) of the University of Salerno, which recently became an Associate member of the International Consortium on Landslides (ICL). The 2018 edition of the LARAM School is organised as an ICL/IPL activity.     

Geometry and kinematics of the Roisan-Cignana Shear Zone,and the orogenic evolution of the Dent Blanche Tectonic System (Western Alps)

The Dent Blanche Tectonic System (DBTS) is a composite thrust sheet derived from the previously thinned passive Adriatic continental margin. A kilometric high-strain zone, the Roisan-Cignana Shear Zone (RCSZ) defines the major tectonic boundary within the DBTS and separates it into two subunits, the Dent Blanche s.s. nappe to the northwest and the Mont Mary nappe to the southeast. Within this shear zone, tectonic slices of Mesozoic and pre-Alpine meta-sediments became amalgamated with continental basement rocks of the Adriatic margin. The occurrence of high pressure assemblages along the contact between these tectonic slices indicates that the amalgamation occurred prior to or during the subduction process, at an early stage of the Alpine orogenic cycle. Detailed mapping, petrographic and structural analysis show that the Roisan-Cignana Shear Zone results from several superimposed Alpine structural and metamorphic stages. Subduction of the continental fragments is recorded by blueschist-facies deformation, whereas the Alpine collision is reflected by a greenschist facies overprint associated with the development of large-scale open folds. The post-nappe evolution comprises the development of low-angle brittle faults, followed by large-scale folding (Vanzone phase) and finally brittle extensional faults. The RCSZ shows that fragments of continental crust had been torn off the passive continental margin prior to continental collision, thus recording the entire history of the orogenic cycle. The role of preceding Permo-Triassic lithospheric thinning, Jurassic rifting, and ablative subduction processes in controlling the removal of crustal fragments from the reactivated passive continental margin is discussed. Results of this study constrain the temporal sequence of the tectono-metamorphic processes involved in the assembly of the DBTS, but they also show limits on the interpretation. In particular it remains difficult to judge to what extent pre-collisional rifting at the Adriatic continental margin preconditioned the efficiency of convergent processes, i.e. accretion, subduction, and orogenic exhumation.     

Theoretical study of the local charge compensation and spectroscopic properties of B-type carbonate defects in apatite

The structure and spectroscopic properties of selected models of B-type carbonate defects in apatite locally compensated by fluoride or hydroxyl ions are investigated using first-principles quantum mechanical calculations. Theoretical infrared absorption spectra and ¹³C, and ¹⁹F nuclear magnetic resonance chemical shifts are determined. Among the investigated models, only the clumped (CO₃ ^2?, F^?) defect, with the carbonate group close to the sloping face of the tetrahedral site and the F^? ion at the remaining apex, corresponds to previous experimental observations performed on carbonate-fluorapatite samples. Although the substitution of hydroxyl by fluoride ions is commonly observed in minerals, the clumped (CO₃ ^2?, OH^?) defects are unlikely to occur in apatite, considering both their theoretical spectroscopic properties and relative stability. Anionic F^? for OH^? exchange between channel and B sites displays a preference of ~20 kJ/mol for the local charge compensation by fluoride ions at the B-site, pointing to a significantly different behavior of F^? and OH^? ions in the charge compensation mechanism. This difference is ascribed to the poor H-bond acceptor character of available oxygen atoms surrounding the apex of the tetrahedral site. The explicit calculation of the infrared absorption spectra of the defect models is also used to interpret the significant difference observed in the linewidth of the ν₂ and ν₃ CO₃ infrared powder absorption bands of carbonated apatite samples. It is shown that for a concentration of 4.4 wt% of CO₂, long-range electrostatic effects already significantly contribute to the broadening of the ν₃ CO₃ bands in apatite.     

A Bayesian vulnerability assessment tool for drinking water mains under extreme events

Drinking water security is a life safety issue as an adequate supply of safe water is essential for economic, social and sanitary reasons. Damage to any element of a water system, as well as corruption of resource quality, may have significant effects on the population it serves and on all other dependent resources and activities. As well as an analysis of the reliability of water distribution systems in ordinary conditions, it is also crucial to assess system vulnerability in the event of natural disasters and of malicious or accidental anthropogenic acts. The present work summarizes the initial results of research activities that are underway with the intention of developing a vulnerability assessment methodology for drinking water infrastructures subject to hazardous events. The main aim of the work was therefore to provide decision makers with an effective operational tool which could support them mainly to increase risk awareness and preparedness and, possibly, to ease emergency management. The proposed tool is based on Bayesian Belief Networks (BBN), a probabilistic methodology which has demonstrated outstanding potential to integrate a range of sources of knowledge, a great flexibility and the ability to handle in a mathematically sound way uncertainty due to data scarcity and/or limited knowledge of the system to be managed. The tool was implemented to analyze the vulnerability of two of the most important water supply systems in the Apulia region (southern Italy) which have been damaged in the past by natural hazards. As well as being useful for testing and improving the predictive capabilities of the methodology and for possibly modifying its structure and features, the case studies have also helped to underline its strengths and weaknesses. Particularly, the experiences carried out demonstrated how the use of BBN was consistent with the lack of data reliability, quality and accessibility which are typical of complex infrastructures, such as the water distribution networks. The potential applications and future developments of the proposed tool have been also discussed accordingly.     

Optical observations of bright elliptical galaxies in the Virgo cluster: stellar population and distance analysis

The analysis of deep imaging data of bright elliptical galaxies is capable of providing fundamental information on the stellar content and the distance of the target, via the Surface Brightness Fluctuation method (SBF hereafter). Here, I present the study of the properties of two ellipticals in the Virgo cluster, NGC 4621 and NGC 4374, based on deep BVR imaging data obtained with the FORS2 camera at the VLT.     

High-order expansion of the solution of preliminary orbit determination problem

A method for high-order treatment of uncertainties in preliminary orbit determination is presented. The observations consist in three couples of topocentric right ascensions and declinations at three observation epochs. The goal of preliminary orbit determination is to compute a trajectory that fits with the observations in two-body dynamics. The uncertainties of the observations are usually mapped to the phase space only when additional observations are available and a least squares fitting problem is set up. A method based on Taylor differential algebra for the analytical treatment of observation uncertainties is implemented. Taylor differential algebra allows for the efficient computation of the arbitrary order Taylor expansion of a sufficiently continuous multivariate function. This enables the mapping of the uncertainties from the observation space to the phase space as high-order multivariate Taylor polynomials. These maps can then be propagated forward in time to predict the observable set at successive epochs. This method can be suitably used to recover newly discovered objects when a scarce number of measurements is available. Simulated topocentric observations of asteroids on realistic orbits are used to assess the performances of the method.     

Environmental suitability of ceramic raw materials: a geochemical approach to volatile emissions and leaching potentials

Growing environmental concern is promoting the necessity of additional ceramic tests. The use of unknown materials with potential contamination conditions requires further studies to demonstrate that the piece encapsulates the pollutant and that during its firing it does not produce the emission of harmful volatile elements. The objective of this work was to perform both tests in a ceramic paste made with slip-casting wastes and electro-plating residues. The leaching methods for determining the encapsulation of potential harmful elements were performed following the TCLP, EP-Tox norm. Having precise chemical analysis of both crude and fired brick, the problem of emissions losses during the firing can be solved by the gain/loss techniques used in geological studies. In particular, the Isocon method that permits a quick visualization of the lost elements is useful. Once the volatile elements were determined, their amount was calculated considering a constant element and the chemical concentrations normalized by the loss of ignition, or using the crude/fired brick ratio densities. The leaching tests indicate that the ceramic brick does not produce harmful leachates according to Argentinean specifications. The leachates of B and Ca are high. Ca does not seem to be a problem while the B content is beyond the permitted limits. During the firing, volatilized elements are Ag, Br, Cl, F, Hg, S, Se, and H₂O. The loss of Ag, Br, and Se are negligible. For F and Cl the potential emission rate is very low (100 mg/kg) while in the case of S, the 2,600 mg/kg rate is high. However, extrapolated emission rates at the chimney assuming an air-to-brick ratio of 2.5 N m³/kg, are approximately 1,040 mg/N m³ for S and 40 mg/N m³ for F and Cl, falling inside environmentally acceptable values. The geochemical procedures proved to be useful tools to assess the element mobilization during firing of ceramic wares and in the analyzed case, the results indicate that the paste is environmentally acceptable.     

Experimental and theoretical study of the vibrational properties of diaspore (α-AlOOH)

Vibrational properties of diaspore, α-AlOOH, have been re-investigated using room-temperature single-crystal Raman spectroscopy and low-temperature powder infrared (IR) transmission spectroscopy. First-principles harmonic calculations based on density functional theory provide a convincing assignment of the major Raman peaks and infrared absorption bands. The large width of the Raman band related to OH stretching modes is ascribed to mode–mode anharmonic coupling due to medium-strength H-bonding. Additional broadening in the powder IR spectrum arises from depolarization effects in powder particles. The temperature dependence of the IR spectrum provides a further insight into the anharmonic properties of diaspore. Based on their frequency and temperature behavior, narrow absorption features at ~2,000 cm⁻¹ and anti-resonance at ~2,966 cm⁻¹ in the IR spectrum are interpreted as overtones of fundamental bending bands.