Reflection coefficients for weak anisotropic media

The interaction of plane elastic waves with a plane boundary between two anisotropic elastic half-spaces is investigated. The anisotropy dealt with in this study is of a general type. Explicit expressions for energy-related reflection and transmission coefficients are derived. They represent an approximation which is valid for a small deviation of the elastic parameters from isotropy.
Classical perturbation theory is applied on a 6times6 non-symmetric real eigenvalue problem to calculate first-order corrections for the polarization and stress of the plane waves. The explicit solution of the isotropic problem is used as a reference case. Degenerate perturbation theory is used to consider the splitting of the isotropic S -wave into two anisotropic qS-waves. The boundary conditions for two half-spaces in welded contact lead to a 6times6 system of linear equations. A correction to the isotropic solution is calculated by linearization. The resultant coefficients are functions of horizontal slowness, Lamé parameters and densities of the reference media, and of the perturbation of the elasticity tensors from isotropy.     

The Val Gabbro Plutonic Suite: A Sub-volcanic Intrusion Emplaced at the End of Flood Basalt Volcanism on the Kerguelen Archipelago

The age, petrology, major and trace element geochemistry, andSr–Nd–Hf–Pb isotopic geochemistry of basicand felsic rocks from the Val gabbro plutonic suite on the KerguelenArchipelago, Southern Indian Ocean, are used to constrain thetemporal and compositional relationships between sub-volcanicintrusions and flood basalt volcanism during the formation ofa major oceanic island. The 4 km² Val gabbro plutonic suitewas emplaced at 24·25 ± 0·15 Ma (U–Pbzircon) into 25 Ma volcanic rocks of the Southeast Province,locally producing a large zone of overlying basaltic breccia.Cumulate basic–ultrabasic rocks are the dominant lithologyin the intrusion, with horizontally layered peridotites at thebase of the exposed part of the intrusion, overlain by verticallylayered, coarse-grained plagioclase-bearing peridotites, melagabbrosand equigranular gabbros. The intrusion was formed by repeatedinjections of relatively crystal-rich and crystal-poor magmasinto an open-system magma reservoir. Strong geochemical andisotopic similarities between the fine-grained marginal microgabbrosand cross-cutting felsic rocks and the hosting mildly alkalicbasalts and trachytes of the Southeast Province indicate thatthey were derived from similar alkalic basaltic parental magmas,which were dominated by the enriched component of the Kerguelenmantle plume source. At 25 Ma, the change from tholeiitic–transitionalto mildly alkalic basalts marks the terminal stage of floodbasalt volcanism on the Kerguelen Archipelago. This compositionalchange was associated with deeper melting within the Kerguelenplume source, lower extents of melting, a decrease in magmasupply, and the emplacement of high-level intrusions such asthe Val gabbro plutonic suite. KEY WORDS: Kerguelen Archipelago; Val gabbro plutonic suite; oceanic island; gabbros; sub-volcanic intrusion; alkalinity; Sr–Nd–Hf–Pb isotopes     

Spectroscopic characterization of fulvic acids extracted from the rock exudate Shilajit

The present work describes the extraction of fulvic acids (FA) from Shilajit and its spectroscopic and mass spectrometric characterization. The spectral features obtained from FT-IR and ¹HNMR were similar to those reported for humic substances from other sources. The molecular elemental composition analysis by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) in electrospray negative ion mode resulted in extraordinary high average O/C ratios (0.55) which might be caused by a significant contribution of carbohydrates in Shilajit. A very high average H/C ratio of 1.27 also points to dominant aliphatic or alicyclic structures and relatively low aromaticity. The average molecular formula of the nitrogen free elemental compositions measured by FT-ICR mass spectrometry is C_18.2H_23.0O_10.0.     

Are major canadian city-regions monocentric,polycentric, or dispersed?

Relatively little research has explored spatial structure in modern major Canadian regions. Three common models are monocentricity, polycentricity, and dispersion, but these are not always mutually exclusive in the complex spatial structures of contemporary city-regions. Shifts between these models are discussed in the context of three explanations of economic growth and restructuring: accessibility, municipal competition, and globalization. All three explanations suggest a trend away from monocentricity. While this appears clearly in US cities, disagreement surrounds whether Canadian cities are following the same path. This study uses cross-sectional data from InfoGroup in 2011 to estimate the relative strengths of monocentricity, polycentricity, and dispersion for characterizing eight major regions. Results indicate that elements of each model are evident in all eight study regions, but each tends to dominate in different contexts. When focusing on Montreal, Toronto, and Vancouver, results imply that all three forces which guide spatial structure play a role and that job centers appear to play a particularly important structural role in larger regions.     

Earth observation-based multi-scale impact assessment of internally displaced person (IDP) camps on wood resources in Zalingei,Darfur

This study describes the development of a semi-automatic object-based image analysis approach for the detection and quantification of deforestation in Zalingei, Darfur, in consequence of the increasing concentration of refugees or internally displaced persons (IDPs) in the region. The classification workflow is based on a multi-scale approach, ranging from the analysis of high resolution SPOT-4 to very high resolution IKONOS and QuickBird satellite imagery between 2003 and 2008. The overall accuracy rates for the classification of the SPOT 4 data ranged from 92% up to 95%, while those for the QuickBird and IKONOS classification have shown values of 88 and 87%, respectively. The resulting trends in woody vegetation cover were compared with the development of the local population and the variability of precipitation. The results show that the strong increase in human population in the Zalingei IDP camps can be associated with considerable decrease in woody vegetation in the camp vicinity.     

Experimental insight into spalling behavior of concrete tunnel linings under fire loading

New experimental insight into the spalling behavior of concrete in fire conditions is presented in this paper. Spalling was recorded by a high-speed camera. The slow-motion sequences allow us to determine the size, shape, and velocity of the spalled-off pieces. With this information at hand, the released energy associated with every spalling event is computed and compared to the energies associated with pore-pressure and thermal-stress spalling. This comparison provides new insight into the impact of the various thermal, mechanical, and hydral processes controlling concrete spalling.