Finite-element modelling of pull-apart basin formation

We present the results of a finite-element modelling study of pull-apart basin formation related to left-stepping left lateral strike-slip faults. The modelling quantifies the relationship between fault geometry (i.e., fault overlap and separation) and pull-apart basin formation. Two depocentres (subbasins) separated by a broad zone of relative uplift in between may develop if the strike-slip domain is characterized by fault underlap. For overlapping faults migration of the subbasins is predicted by the models. Deep subbasins in a large area of subsidence which spans the entire inner fault zone may form if fault overlap is about three times the fault separation.

The models suggest that a topographic asymmetry within the fault zone may arise due to a different displacement ratio of the strike-slip faults. The modelling results show that this asymmetry in topography becomes more pronounced towards the more active fault. Thus, basin deepening occurs progressively towards the fault characterized by the largest amount of lateral displacement. Moreover, the results indicate that the smaller the fault separation (less than basin length) the less pronounced the topographic asymmetry.

The models provide quantitative estimates for the effects of changes in elastic material properties, the magnitude of the compressive far-field stress and the coefficient of friction of the faults on the resulting topography.

Comparison of the modelling results with field observations from the Cerro Blanco-El Barranquete (CBB) subbasin located in the Internal Zone of the Betic Cordillera, southeastern Spain support an interpretation in which the interplay of major faults has formed the CBB subbasin.     

Influence of forest and shrub canopies on precipitation partitioning and isotopic signatures

Over a 4‐month summer period, we monitored how forest (Pinus sylvestris ) and heather moorland (Calluna spp. and Erica spp.) vegetation canopies altered the volume and isotopic composition of net precipitation (NP) in a southern boreal landscape in northern Scotland. During that summer period, interception losses were relatively high and higher under forests compared to moorland (46% of gross rainfall [GR] compared with 35%, respectively). Throughfall (TF) volumes exhibited marked spatial variability in forests, depending upon local canopy density, but were more evenly distributed under heather moorland. In the forest stands, stemflow was a relatively small canopy flow path accounting for only 0.9–1.6% of NP and only substantial in larger events. Overall, the isotopic composition of NP was not markedly affected by canopy interactions; temporal variation of stable water isotopes in TF closely corresponded to that of GR with differences of TF‐GR being ?0.52‰ for δ²H and ?0.14‰ for δ¹⁸O for forests and 0.29‰ for δ²H and ?0.04‰ for δ¹⁸O for heather moorland. These differences were close to, or within, analytical precision of isotope determination, though the greater differences under forest were statistically significant. Evidence for evaporative fractionation was generally restricted to low rainfall volumes in low intensity events, though at times, subtle effects of liquid–vapour moisture exchange and/or selective transmission though canopies were evident. Fractionation and other effects were more evident in stemflow but only marked in smaller events. The study confirmed earlier work that increased forest cover in the Scottish Highlands will likely cause an increase in interception and green water fluxes at the expenses of blue water fluxes to streams. However, the low‐energy, humid environment means that isotopic changes during such interactions will only have a minor overall effect on the isotopic composition of NP.     

Experimentally determined partitioning of Rb between richterites and aqueous (Na, K)-chloride solutions

The distribution of Rb-Na and Rb-K between richterite and a 2-molal aqueous (Na, K, Rb)-chloride solution has been investigated with hydrothermal experiments at 800^∘C and 200 MPa. Experiments were performed as syntheses in which amphiboles grew in the presence of an excess fluid containing the exchangeable cations Na⁺-Rb⁺ or Na⁺-K⁺-Rb⁺. The obtained amphiboles were large enough (up to 20 m in width) for reliable EMP analysis. They were chemically homogeneous and HRTEM investigations showed that they were structurally well ordered. The Rb, Na, K, Ca and Mg concentrations in coexisting fluids were measured by ICP-AES. According to the possible incorporation of Na, K and Rb on the A-site, solid solutions in the ternary Na(NaCa) Mg₅[Si₈O₂₂/(OH)₂] (richterite)-K(NaCa)Mg₅[Si₈O₂₂/(OH)₂] (K-richterite)-Rb(NaCa)Mg₅[Si₈O₂₂/(OH)₂] (Rb-richterite) were expected. However, Rb-rich richterites always had significant amounts of A-site vacancy concentrations (X _□ ^amph=□ ^A /(Rb^A+K^A +Na^A+□^A) of up to 0.42 in the K-free (Na,Rb)-richterites and of up to 0.67 in the (Na, K, Rb)-richterites which corresponds to the same content of tremolite+cummingtonite-component. Amphiboles containing practically only Rb besides vacancies and no Na and/or K on the A-site were also synthesized, however. The Rb-Na and Rb-K exchange coefficients between fluid and richterites are similar. Rubidium always fractionated strongly into the fluid phase. For low Rb-concentrations in richterite (X _Rb ^amph<0.1) a linear correlation between X _Rb ^fluid and X _Rb ^amph exists. In this concentration range, the derived exchange coefficients K _D(Rb−K) ^amph−fluid and K _D(Rb−Na) ^amph−fluid were 0.08 ± 0.04 and 0.04 ± 0.02, respectively. These low exchange coefficients show that significant amounts of Rb in amphiboles require a Rb-rich fluid phase. The results indicate that K-Rb fractionation between alkali amphiboles and fluids is significantly different from K-Rb fractionation between alkali feldspar/ phlogopite and fluid, with K_Ds of about 0.5 and 1.2, respectively. Formation of richterites will drastically alter the K/Rb-ratios of fluids or melts. These results may have important implications for the genetical interpretation of various geological settings, e.g., MARID-type rocks. Received: 6 October 1997 / Accepted: 7 July 1998     

Molecular stable carbon isotope compositions of alkylphenanthrenes in coals and marine shales related to source and maturity

Phenanthrene (PHE) and methylphenanthrenes (MPs) extracted from coaly shale and coal samples containing terrestrial organic matter are compared with the same compounds from marine shales in terms of yields and δ¹³C values at marginally to fully mature stages of thermal evolution. The shales derived from four boreholes in the Hils Half-Graben area, northwestern Germany, were shown to be representative of a greater number of samples from the same sites. The δ¹³C values of extractable PHE and MPs are less negative in the terrestrial (−24.3 to −26.0‰) than in the marine (−28.8 to −30.5‰) samples. Since these values are unrelated to mean vitrinite reflectance (R_r) values in the range of 0.5–0.9%, it appears that the stable carbon isotope composition of PHE and MPs is controlled by organic matter type rather than maturity.     

Differential responses of hillslope and channel elements to rainfall events in a semi-arid area

The degree of hydrological connectivity of hillslope elements in a semi-arid climate was studied at the season and event timescales. Field data were obtained in Rambla Honda, a Medalus project field site situated in SE Spain, on micaschist bedrock and with 300 mm annual rainfall. The season timescale was assessed using correlation analysis between soil moisture and topographic indices. The event timescale was studied by a quasi-continuous monitoring of rainfall, soil moisture, runoff and piezometric levels. Results show that widespread transfers of water along the hillslope are unusual because potential conditions for producing overland flow or throughflow are spatially discontinuous and extremely short-lived. During extreme events, runoff coefficients may be locally high (ca. 40% on slope lengths of 10 m), but decrease dramatically at the hillslope scale (<10% on slope lengths of 50 m). Two mechanisms of overland flow generation have been identified: infiltration excess, and local subsurface saturation from upper layers. The former occurs during the initial stages of the event while the latter, which is quantitatively more important, takes place later and requires a certain time structure of rainfall intensities that allow saturation of the topsoil and the subsequent production of runoff. Hillslopes and alluvial fans function as runoff sources and sinks respectively. Permanent aquifers are lacking in Rambla Honda. Variable proportions of hillslope areas may contribute to flash floods in the main channel, but their contribution to the formation of saturated layers within the sediment fill is very limited.     

Anisotropic reflection coefficients for a weak-contrast interface

In this article the interaction of plane waves with a weak-contrast interface between two weakly anisotropic half-spaces is investigated. The anisotropy dealt with is of a general type. The stress–displacement vectors of the plane waves are calculated by perturbation theory. By assuming that the jump in elastic parameters and density across the interface is small, one can derive a simple expression for the R _qPqP coefficient. In cases in which the wave motion is restricted to a symmetry plane of an anisotropic medium, simple expressions for the R _qSVqSV and R _SHSH coefficients are also derived.     

Thermodynamic modelling of diffusion-controlled garnet growth

Numerical thermodynamic modelling of mineral composition and modes for specified pressure-temperature paths reveals the strong influence of fractional garnet crystallisation, as well as water fractionation, on garnet growth histories in high pressure rocks. Disequilibrium element incorporation in garnet due to the development of chemical inhomogeneities around porphyroblasts leads to pronounced episodic growth and may even cause growth interruptions. Discontinuous growth, together with pressure- and temperature-dependent changes in garnet chemistry, cause zonation patterns that are indicative of different degrees of disequilibrium element incorporation. Chemical inhomogeneities in the matrix surrounding garnet porphyroblasts strongly affect garnet growth and lead to compositional discontinuities and steep compositional gradients in the garnet zonation pattern. Further, intergranular diffusion-controlled calcium incorporation can lead to a characteristic rise in grossular and spessartine contents at lower metamorphic conditions. The observation that garnet zonation patterns diagnostic of large and small fractionation effects coexist within the same sample suggests that garnet growth is often controlled by small-scale variations in the bulk rock chemistry. Therefore, the spatial distribution of garnet grains and their zonation patterns, together with numerical growth models of garnet zonation patterns, yield information about the processes limiting garnet growth. These processes include intercrystalline element transport and dissolution of pre-existing grains. Discontinuities in garnet growth induced by limited element supply can mask traces of the thermobarometric history of the rock. Therefore, thermodynamic modelling that considers fractional disequilibrium crystallisation is required to interpret compositional garnet zonation in terms of a quantitative pressure and temperature path of the host rock.