Uptake of the NO <Subscript>3</Subscript> Radical on Aqueous Surfaces

Using a single drop experiment, the uptake of NO₃ radicals on aqueous solutions of the dye Alizarin Red S and NaCl was measured at 293 K. Uptake coefficients in the range (1.7–3.1) ⋅ 10^{− 3} were measured on Alizarin Red S solutions. The uptake coefficients measured on NaCl solutions were in the range of (1.1–2.0) ⋅ 10⁻³ depending on the salt concentration. Both experiments lead to a consistent result for the mass accommodation coefficient of α_NO3 = (4.2_{− 1.7}^+2.2)⋅ 10⁻³. The product H(D_l k_Cl−^II)^0.5 for the NO₃ radical was determined to be (1.9 ± 0.2) M atm^{− 1} cm s^−0.5 M^−0.5 s^−0.5 by fitting the uptake data for the NaCl solutions to the so-called resistance model. The yield of the chemical NO₃ radical source was characterized using UV-VIS and FT-IR spectroscopy. The amount of gas-phase NO₃ radicals measured at elevated humidities was less than expected. Instead, a rise of the gas-phase HNO₃ concentration was found indicating a conversion of gas-phase NO₃ radicals to gas-phase HNO₃ on the moist reactor walls.     

Local foehn effects in the upper Isar Valley, part 1: Observations

Summary An unusually strong nocturnal downvalley wind can be regularly observed in the upper Isar Valley close to Mittenwald (Bavarian Alps) when a high-pressure system is located over Central Europe or when ambient southerly winds are present. Due to the structure of the local topography, this downvalley wind has foehn-like properties in the sense that the breakthrough of the flow into the valley is characterized by a strong increase in temperature and a decrease in relative humidity. Therefore the author called this flow Minifoehn. In fact, wind speeds are low in comparison to deep foehn, but gusts may reach values up to 20ms^–1, even under the influence of high pressure systems with weak atmospheric pressure gradients. To investigate the Minifoehn, surface stations have been installed for collecting temperature, humidity, wind and pressure data. Measurements have shown that the Minifoehn represents the upper part of one of the drainage currents which flows over a mountain ridge into the valley at Mittenwald. Nocturnally cooled air drains from a plateau south of Mittenwald through different valleys which merge again near Mittenwald. It seems that the forcing of the nocturnal currents is dominated by the temperature difference between this plateau and the free atmosphere above Mittenwald at the same level. Strong temperature differences are found during clear winter nights and in case of subsidence inversions. Moreover, the appearance of the Minifoehn in autumn and winter is so frequent that we even may find a climatic effect: the upper Isar Valley is usually free of fog during these seasons and nocturnal temperatures are often considerably higher than in other Bavarian Alpine valleys at comparable altitude.     

The earth system model of intermediate complexity CLIMBER-3α. Part I: description and performance for present-day conditions

We herein present the CLIMBER-3α Earth System Model of Intermediate Complexity (EMIC), which has evolved from the CLIMBER-2 EMIC. The main difference with respect to CLIMBER-2 is its oceanic component, which has been replaced by a state-of-the-art ocean model, which includes an ocean general circulation model (GCM), a biogeochemistry module, and a state-of-the-art sea-ice model. Thus, CLIMBER-3α includes modules describing the atmosphere, land-surface scheme, terrestrial vegetation, ocean, sea ice, and ocean biogeochemistry. Owing to its relatively simple atmospheric component, it is approximately two orders of magnitude faster than coupled GCMs, allowing the performance of a much larger number of integrations and sensitivity studies as well as longer ones. At the same time its oceanic component confers on it a larger degree of realism compared to those EMICs which include simpler oceanic components. The coupling does not include heat or freshwater flux corrections. The comparison against the climatologies shows that CLIMBER-3α satisfactorily describes the large-scale characteristics of the atmosphere, ocean and sea ice on seasonal timescales. As a result of the tracer advection scheme employed, the ocean component satisfactorily simulates the large-scale oceanic circulation with very little numerical and explicit vertical diffusion. The model is thus suited for the study of the large-scale climate and large-scale ocean dynamics. We herein describe its performance for present-day boundary conditions. In a companion paper (Part II), the sensitivity of the model to variations in the external forcing, as well as the role of certain model parameterisations and internal parameters, will be analysed.     

Effects of cluster galaxies on arc statistics

We present the results of a set of numerical simulations evaluating the effect of cluster galaxies on arc statistics.
We perform a first set of gravitational lensing simulations using three independent projections for each of nine different galaxy clusters obtained from N -body simulations. The simulated clusters consist of dark matter only. We add a population of galaxies to each cluster, mimicking the observed luminosity function and the spatial galaxy distribution, and repeat the lensing simulations including the effects of cluster galaxies, which themselves act as individual lenses. Each galaxy is represented by a spherical Navarro, Frenk & White density profile.
We consider the statistical distributions of the properties of the gravitational arcs produced by our clusters with and without galaxies. We find that the cluster galaxies do not introduce perturbations strong enough to significantly change the number of arcs and the distributions of lengths, widths, curvature radii and length-to-width ratios of long arcs. We find some changes to the distribution of short-arc properties in the presence of cluster galaxies. The differences appear in the distribution of curvature radii for arc lengths smaller than 12 arcsec, while the distributions of lengths, widths and length-to-width ratios are significantly changed only for arcs shorter than 4 arcsec.     

First detection of glacial meltwater signature in tree‐ring δ18O: Reconstructing past major glacier runoff events at Lago Verde (Miage Glacier,Italy)

With the aim of evaluating the influence of glacial meltwater signature on tree‐ring stable isotopes, we analysed δ¹⁸O and δ¹³C in the tree rings of Larix decidua Mill. specimens growing in the area of an ice‐contact lake (Lago Verde, at Miage Glacier, European Alps). Additionally, we analysed δ¹⁸O in the glacial meltwater of the lake and of the glacier stream and compared it with the δ¹⁸O of precipitation predicted by a spatial model. We found that tree‐ring cellulose of trees fed by glacial meltwaters (LVW site) is significantly more depleted in δ¹⁸O than at a control site LVM (?0.91‰) fed only by precipitation, thus reflecting the measured higher depletion of glacial meltwaters with respect to local precipitation. δ¹³C values did not show significant differences in mean values between the two sites but an anomalous correlation with summer temperature was found at the LVW site, probably due to the different responses of trees stomatal conductance. Over the 30‐year period of analysis, four years at LVW (1992, 1995, 2003 and 2009) were markedly depleted in δ¹⁸O. These years are those when the highest summer temperatures were recorded in the area (the ones during which glacier ablation usually increases and more depleted meltwaters fill the lake), with the exception of 1995 during which high water levels occurred following the year with the second highest summer temperature (1994). Overall, our analysis demonstrates that tree‐ring δ¹⁸O, driven by the glacial meltwater signature in the lake, can be used for detecting past major glacier runoff events. The proposed approach could also be used for quantifying past glacier runoff and for defining past distribution areas of glacial meltwaters in glacier forefields, thus contributing to past environmental reconstructions and to hazard assessment.     

Process‐based hydrological modelling: The potential of a bottom‐up approach for runoff predictions in ungauged catchments

Conceptual rainfall–runoff models are a valuable tool for predictions in ungauged catchments. However, most of them rely on calibration to determine parameter values. Improving the representation of runoff processes in models is an attractive alternative to calibration. Such an approach requires a straightforward, a priori parameter allocation procedure applicable on a wide range of spatial scales. However, such a procedure has not been developed yet. In this paper, we introduce a process‐based runoff generation module (RGM‐PRO) as a spin‐off of the traditional runoff generation module of the PREVAH hydrological modelling system. RGM‐PRO is able to exploit information from maps of runoff types, which are developed on the basis of field investigations and expert knowledge. It is grid based, and within each grid cell, the process heterogeneity is considered to avoid information loss due to grid resolution. The new module is event based, and initial conditions are assimilated and downscaled from continuous simulations of PREVAH, which are also available for real‐time applications. Four parameter allocation strategies were developed, on the basis of the results of sprinkling experiments on 60‐m² hillslope plots at several grassland locations in Switzerland, and were tested on five catchments on the Swiss Plateau and Prealps. For the same catchments, simulation results obtained with the best parameter allocation strategy were compared with those obtained with different configurations of the traditional runoff generation module of PREVAH, which was also applied as an event‐based module here. These configurations include a version that avoids calibration, one that transfers calibrated parameters, and one that uses regionalised parameter values. RGM‐PRO simulated heavy events in a more realistic way than the uncalibrated traditional runoff generation module of PREVAH, and, in some instances, it even exceeded the performance of the calibrated traditional one. The use of information on the spatial distribution of runoff types additionally proved to be valuable as a regionalisation technique and showed advantages over the other regionalisation approaches, also in terms of robustness and transferability.     

Structural styles,hydrocarbon prospects,and potential in the Salt Range and Potwar Plateau,north Pakistan

The Salt Range/Potwar Plateau (SRPP) is part of the Himalayan foreland and an important petroleum province in north Pakistan. The hydrocarbons are commonly produced from stacked Cambrian to Eocene clastic and carbonate reservoirs which have an average thickness of 1 km. These strata are overlain by at least 5 km of Miocene and younger continental molasse sedimentation in the deepest part of the foreland basin. Surface and subsurface (seismic interpretations and borehole data) geology combined with the timing and the patterns of sedimentation has allowed to interpret the deformation as thin skinned, with a detachment in weak Eocambrian evaporates and the development of ramp-and-flat structures, since about 8 Ma. We have reviewed the structural interpretations with new borehole logs, field geology, and reserve estimates in this paper to precisely define oil-field structures with a view on future exploration. As a result of this work, 12 oil fields are classified as three detachment folds, four fault-propagation folds, four pop-ups, and one triangle zone structure. The latter two are identified as better prospects with the last one as the best with estimated reserves of 51 million barrels of oil (MMBO). Hence, the triangle zones along with other ramp-and-flat structures from the North Potwar Deformed Zone (NPDZ) are recognized to provide potential future prospects. Finally, a 40-km-long structural cross section from NPDZ is used to discuss complex deformation of the triangle zone and duplex structures as future potential prospects. About 55 km of shortening across the NPDZ during Plio-Pleistocene time is calculated, which has important bearing on the geometry of prospects, reserve calculations, and the future exploration.     

The COST733 circulation type classification software: an example for surface ozone concentrations in Central Europe

In the framework of the COST733 Action ??Harmonisation and Applications of Weather Types Classifications for European Regions?? a new circulation type classification software (hereafter, referred to as cost733class software) is developed. The cost733class software contains a variety of (European) classification methods and is flexible towards choice of domain of interest, input variables, time step, number of circulation types, sequencing and (weighted) target variables. This work introduces the capabilities of the cost733class software in which the resulting circulation types (CTs) from various circulation type classifications (CTCs) are applied on observed summer surface ozone concentrations in Central Europe. Firstly, the main characteristics of the CTCs in terms of circulation pattern frequencies are addressed using the baseline COST733 catalogue (cat 2.0), at present the latest product of the new cost733class software. In a second step, the probabilistic Brier skill score is used to quantify the explanatory power of all classifications in terms of the maximum 8 hourly mean ozone concentrations exceeding the 120-??g/m³ threshold; this was based on ozone concentrations from 130 Central European measurement stations. Averaged evaluation results over all stations indicate generally higher performance of CTCs with a higher number of types. Within the subset of methodologies with a similar number of types, the results suggest that the use of CTCs based on optimisation algorithms are performing slightly better than those which are based on other algorithms (predefined thresholds, principal component analysis and leader algorithms). The results are further elaborated by exploring additional capabilities of the cost733class software. Sensitivity experiments are performed using different domain sizes, input variables, seasonally based classifications and multiple-day sequencing. As an illustration, CTCs which are also conditioned towards temperature with various weights are derived and tested similarly. All results exploit a physical interpretation by adapting the environment-to-circulation approach, providing more detailed information on specific synoptic conditions prevailing on days with high surface ozone concentrations. This research does not intend to bring forward a favourite classification methodology or construct a statistical ozone forecasting tool but should be seen as an introduction to the possibilities of the cost733class software. It this respect, the results presented here can provide a basic user support for the cost733class software and the development of a more user- or application-specific CTC approach.     

An exploratory study on the use of enzyme activities as sediment tracers: biochemical fingerprints?

Little information exists on the potential of soil enzyme activities,which are sensitive to soil properties and management,for the characterization of sediment sources at the catchment scale.The objective of this study is to explore and evaluate enzyme activity as tracer for sediment fingerprinting in the Hiv catchment(55 km~2),Iran.Therefore,four enzymes were measured from 42 different sampling sites,covering three sediment source areas(rangeland/surface erosion,orchard/surface erosion,and streambank erosion),as well as from 12 sediment samples from reservoir check dams (sediment sinks).The results indicate that,based upon backward mode discriminant analysis,βglucosidase and dehydrogenase,allowed more than 95%of the samples to be correctly assigned to their source areas.These enzymes were selected as input data for a mixing-model to determine the relative contribution of the sampled sediment sources.The mean contributions from rangeland, orchard and streambank sources in the study area were estimated as 11.3%,15.1%and 73.7%, respectively.Using geochemical tracers,the mean contribution from rangeland,orchard and streambank sources was estimated as 14.1%,9.5%and 74.8%,respectively.Combined biochemical and geochemical tracers,similar values were obtained(18.7%,10.7%and 70.7%,respectively).Our results indicate that soil enzyme activity allows for a good characterization of sediment sources,and can provide a complementary tool to currently existing sediment fingerprinting approaches.However, the method should be also tested in other regions.     

Phosphate oxygen isotopes: Insights into sedimentary phosphorus cycling from the Benguela upwelling system

Marine sediments are the main sink in the oceanic phosphorus (P) cycle. The activity of benthic microorganisms is decisive for regeneration, reflux, or burial of inorganic phosphate (P_i), which has a strong impact on marine productivity. Recent formation of phosphorites on the continental shelf and a succession of different sedimentary environments make the Benguela upwelling system a prime region for studying the role of microbes in P biogeochemistry. The oxygen isotope signature of pore water phosphate (δ¹⁸O_P) carries characteristic information of microbial P cycling: Intracellular turnover of phosphorylated biomolecules results in isotopic equilibrium with ambient water, while enzymatic regeneration of P_i from organic matter produces distinct offsets from equilibrium. The balance of these two processes is the major control for δ¹⁸O_P.Our study assesses the importance of microbial P cycling relative to regeneration of P_i from organic matter from a transect across the Namibian continental shelf and slope by combining pore water chemistry (sulfate, sulfide, ferrous iron, P_i), steady-state turnover rate modeling, and oxygen isotope geochemistry of P_i.We found δ¹⁸O_P values in a range from 12.8‰ to 26.6‰, both in equilibrium as well as pronounced disequilibrium with water. Our data show a trend towards regeneration signatures (disequilibrium) under low mineralization activity and low P_i concentrations, and microbial turnover signatures (equilibrium) under high mineralization activity and high P_i concentrations. These findings are opposite to observations from water column studies where regeneration signatures were found to coincide with high mineralization activity and high P_i concentrations. It appears that preferential P_i regeneration in marine sediments does not necessarily coincide with a disequilibrium δ¹⁸O_P signature. We propose that microbial P_i uptake strategies, which are controlled by P_i availability, are decisive for the alteration of the isotope signature. This hypothesis is supported by the observation of efficient microbial P_i turnover (equilibrium signatures) in the phosphogenic sediments of the Benguela upwelling system.