Cost Comparisons of Aquifer Heterogeneity Characterization Methods

The characterization of heterogeneity in hydraulic conductivity (K) is a major challenge for subsurface remediation projects. There are a number of field studies that compare the K estimates obtained using various techniques, but to our knowledge, no field‐based studies exists that compare the performance of estimated K heterogeneity fields or the associated characterization costs. In this paper, we compare the costs of characterizing the three‐dimensional K heterogeneity and its uncertainty estimates of a glaciofluvial aquifer‐aquitard sequence at a 15 m × 15 m × 18 m field site situated on the University of Waterloo campus. We compare geostatistical analysis of high resolution permeameter K data obtained from repacked core samples in five boreholes and hydraulic tomography analysis of four pumping tests consisting of up to 41 monitoring points per test. Aside from the comparison of costs, we also assess the performance of each method by predicting several pumping tests. Our analysis reveals that hydraulic tomography is somewhat more costly than the geostatistical analysis of high resolution permeameter K data due to the higher capital costs associated with the method. However, the equipment may be reused at other sites; hence these costs may be recovered over the life of the equipment. More significantly, hydraulic tomography is able to capture the most important features of the aquifer‐aquitard sequence leading to more accurate predictions of independent pumping tests. This suggests that more robust remediation systems may be designed if site characterization is performed with hydraulic tomography.     

Strombolian explosive styles and source conditions: insights from thermal (FLIR) video

Forward Looking Infrared Radiometer (FLIR) cameras offer a unique view of explosive volcanism by providing an image of calibrated temperatures. In this study, 344 eruptive events at Stromboli volcano, Italy, were imaged in 2001–2004 with a FLIR camera operating at up to 30 Hz. The FLIR was effective at revealing both ash plumes and coarse ballistic scoria, and a wide range of eruption styles was recorded. Eruptions at Stromboli can generally be classified into two groups: Type 1 eruptions, which are dominated by coarse ballistic particles, and Type 2 eruptions, which consist of an optically-thick, ash-rich plume, with (Type 2a) or without (Type 2b) large numbers of ballistic particles. Furthermore, Type 2a plumes exhibited gas thrust velocities (>15 m s⁻¹) while Type 2b plumes were limited to buoyant velocities (<15 m s⁻¹) above the crater rim. A given vent would normally maintain a particular gross eruption style (Type 1 vs. 2) for days to weeks, indicating stability of the uppermost conduit on these timescales. Velocities at the crater rim had a range of 3–101 m s⁻¹, with an overall mean value of 24 m s⁻¹. Mean crater rim velocities by eruption style were: Type 1 = 34 m s⁻¹, Type 2a = 31 m s⁻¹, Type 2b = 7 m s⁻¹. Eruption durations had a range of 6–41 s, with a mean of 15 s, similar among eruption styles. The ash in Type 2 eruptions originates from either backfilled material (crater wall slumping or ejecta rollback) or rheological changes in the uppermost magma column. Type 2a and 2b behaviors are shown to be a function of the overpressure of the bursting slug. In general, our imaging data support a broadening of the current paradigm for strombolian behavior, incorporating an uppermost conduit that can be more variable than is commonly considered.     

Organochlorine contaminants in endangered Hawaiian monk seals from four subpopulations in the Northwestern Hawaiian Islands

We analyzed blubber and blood samples for organochlorines (OCs) from 158 Hawaiian monk seals (Monachus schauinslandi) at four of their six primary breeding colonies in the Northwestern Hawaiian Islands. Levels of OCs in blubber were lower in adult females compared to juveniles or adult males, evidently owing to the transfer of these lipophilic compounds to pups by pregnant and lactating females. Concentrations of SigmaPCBs and p,p'-DDE in blubber generally increased with age until seals were sexually mature and then continued to increase with age in males after puberty. Average levels of PCBs and PCB toxic equivalents (TEQs) in blubber were significantly higher in adult male and juvenile seals at Midway Atoll than the same age class of seals at the other colonies. Unlike concentrations of OCs in blubber, circulating levels of OCs in blood did not vary consistently among age classes of seals or among breeding colonies. Though the concentrations of OCs measured in Hawaiian monk seals were generally equal to or lower than those reported for other pinniped species in the North Pacific Ocean, they were high enough in a few seals to potentially affect their health.     

Discriminating between the roles of late Pleistocene palaeodischarge and geological‐topographic inheritance in fluvial longitudinal profile and channel development

This paper investigates the influences of palaeohydrology and geological‐topographic inheritance in shaping the channel of the lower River Suir, southeast Ireland. Results of acoustic surveys of the lower River Suir and Waterford Harbour reveal two scales of pseudo‐cyclic river bedforms. Longitudinal elevation profiles of the geological topography (undulating bedrock and till‐mantled bedrock) bounding the present floodplain swath reveal pseudo‐cyclicity in that terrain too. Spectral and statistical analyses are used to quantify the cyclicity of the long profile and geological‐topographic series. These methods show that the dominant cyclicity of the long profile reflects autocorrelation more than inheritance of cyclicity from the bounding geological topography. The cyclicity of the long profile mainly reflects a hydraulic control on pool‐spacing, although some cyclicity probably has been inherited from the geological‐topography. Channel‐forming palaeodischarge is estimated based on the dominant pool‐spacing revealed by spectral analysis, validated using relationships between meander wavelength, channel cross‐sectional geometry and hydraulically‐informed discharge reconstruction. The palaeodischarge estimates are in close agreement and are two orders of magnitude greater than present flood maxima. Significantly, these palaeodischarge estimates also agree closely with palaeodischarge calculated for the submerged Pleistocene palaeochannel that extends across the near‐shore continental shelf from Waterford Harbour. The pool‐sequence of the lower Suir and the submerged palaeochannel represent a former land‐system that was active during a period of low relative sea level during the last glacial. More broadly, the paper offers insights into the landscape evolution of formerly glaciated regions that experienced very wide discharge variability during and after the transition from glacial to interglacial regimes, in a context of complex relative sea level change. Copyright © 2017 John Wiley & Sons, Ltd.     

The influence of neap–spring tidal variation and wave energy on sediment flux in salt marsh tidal creeks

Sediment flux in marsh tidal creeks is commonly used to gauge sediment supply to marshes. We conducted a field investigation of temporal variability in sediment flux in tidal creeks in the accreting tidal marsh at China Camp State Park adjacent to northern San Francisco Bay. Suspended‐sediment concentration (SSC), velocity and depth were measured near the mouths of two tidal creeks during three 6‐ to 10‐week deployments: two in winter and one in summer. Currents, wave properties and SSC were measured in the adjacent shallows. All deployments spanned the largest spring tides of the season. Results show that tidally averaged suspended‐sediment flux (SSF) in the tidal creeks varied from slightly landward to strongly bayward with increasing tidal energy. SSF was negative (bayward) for tidal cycles with maximum water surface elevation above the marsh plain. Export during the largest spring tides dominated the cumulative SSF for each deployment. During ebb tides following the highest tides, velocities exceeded 1 m s^?1 in the narrow tidal creeks, resulting in negative tidally averaged water flux, and mobilizing sediment from the creek banks or bed. Storm surge also produced negative SSF. Tidally averaged SSF was positive in wavy conditions with moderate tides. Spring tide sediment export at the creek mouth was about twice that at a station 130 m further up the tidal creek. The negative tidally averaged water flux near the creek mouth during spring tides indicates that in the lower marsh some of the water flooding directly across the bay–marsh interface drains through the tidal creeks, and suggests that this interface may be a pathway for sediment supply to the lower marsh as well. Copyright © 2018 John Wiley & Sons, Ltd.     

Comparison of land surface scheme simulations with field observations versus atmospheric model output as forcing

ABSTRACT

The low density of meteorological stations in parts of Canada necessitates using numerical weather prediction (NWP)/assimilation output for hydrological modelling. In this study, comparisons are made of simulated land surface variables when using field observations versus NWP output as forcing for two well-instrumented sites: the mountainous and forested Marmot Creek Basin (MCRB) in the Canadian Rocky Mountains, and a prairie cropland/grassland site (Kenaston). The Canadian Land Surface Scheme 3.6 (CLASS) was used for modelling. The Global Environmental Multiscale (GEM) model with Canadian Precipitation Analysis (CaPA) was also used as forcing. There was good agreement between observed meteorology and GEM/CaPA, though some deficiencies in GEM/CaPA were identified: the effects of sub-grid topography on incoming radiation and wind speed were not accounted for at MCRB, and CaPA did not capture some convective rainfall events at Kenaston. CLASS simulations using both sets of forcing showed difficulties in simulating snow depth, soil moisture and evapotranspiration; certain difficulties were linked to GEM/CaPA deficiencies and/or CLASS. Both sets of forcing tended to overestimate the duration of snow cover at MCRB, but during different years. With GEM/CaPA as forcing, CLASS overestimated the duration of frozen soils. The GEM/CaPA precipitation difficulties at Kenaston degraded soil moisture simulations.

EDITOR A. Castellarin; ASSOCIATE EDITOR E. Volpi     

In situ biomonitoring of caged, juvenile Chinook salmon (Oncorhynchus tshawytscha) in the Lower Duwamish Waterway

Contaminated sediments may have wide-ranging impacts on human and ecological health. A series of in situ caged exposure studies using juvenile Chinook salmon was conducted in the Lower Duwamish Waterway (LDW). Chemical analysis of sediment, water, and fish tissue were completed. Additionally, in 2004, DNA adducts in hepatic and gill tissues were measured. Gills contained significantly higher DNA adducts at stations B2 and B4, prompting further analysis of gills in 2006 and 2007. Fluorescent aromatic compounds (FACs) in bile, and CYP1A1 in hepatic tissue were also measured during 2006 and 2007, respectively. FACs in field-caged fish were comparable or significantly higher than wild-caught fish LDW fish and significantly higher than lab fish after only 8-10 days, demonstrating the equivalency of exposure to that of migrating salmon. Furthermore, selected biomarkers appear to be capable of detecting spikes in contamination between sampling years, emphasizing the need for multiple year data collection.     

Enantioselectivity of polychlorinated biphenyl atropisomers in sediment and biota from the Turtle/Brunswick River estuary, Georgia, USA

To investigate the potential for enantioselective transformation and accumulation, the enantiomer distributions of seven polychlorinated biphenyl (PCB) atropisomers were measured in the sediment and biota from a sub-tropical estuary heavily contaminated with Aroclor 1268, a technical mixture of highly chlorinated PCB congeners. Enantiomer fractions (EFs) of PCBs 91, 95, 136, 149, 174, 176, and 183 in marsh sediment, invertebrate, forage and predatory fish species, and bottlenose dolphins were determined. Non-racemic EFs greater than 0.75 were found in sediments for PCBs 136 and 174, likely the result of microbial dechlorination. Although enantiomer fractions in grass shrimp (Palaemonetes spp.) mirrored those of sediment, fish species had EFs that differed significantly from sediment or grass shrimp. Similarly, bottlenose dolphins were also found to contain non-racemic quantities of PCBs 91, 136, 174, 176, and 183. Non-racemic EFs in these biota were likely a result of both uptake of non-racemic proportions of PCBs from the diet and enantioselective biotransformation.