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101.
Anthony C. Withers Marc M. Hirschmann 《Contributions to Mineralogy and Petrology》2008,156(5):595-605
Olivine crystals were grown in the presence of a hydrous silicate fluid during multi-anvil experiments at 8 GPa and 1,000–1,600°C.
Experiments were conducted both in a simple system (FeO–MgO–SiO2–H2O) and in a more complex system containing additional elements (CaO–Na2O–Al2O3–Cr2O3–TiO2–FeO–MgO–SiO2–H2O). Silica activity was buffered by the presence of either pyroxene (high a
SiO2) or ferropericlase (low a
SiO2), and was buffered by the presence of Ni + NiO or Fe + FeO, or constrained by the presence of Fe2O3. Raman spectroscopy was used to identify pyroxene polymorphs in the run products. Clinoenstatite was present in the 1,000°C
experiment, and enstatite in experiments at 1,400–1,520°C. The H2O content of olivine was measured using secondary ion mass spectroscopy, and infrared spectroscopy was used to investigate
the nature of hydrous defects. The H2O storage capacity of olivine decreases with increasing temperature at 8 GPa. In contrast to previous experimental results
at ≤2 GPa, no significant effect of varying oxygen fugacity is evident, but H2O storage capacity is enhanced under conditions of low silica activity. No significant growth of low wavenumber (<3,400 cm−1) peaks, generally associated with high at low pressure, was observed in the FTIR spectra of olivine from the high experiments. Our experiments show that previous high pressure H2O storage capacity measurements for olivine synthesized under more oxidizing conditions than the Earth’s mantle are not likely
to be compromised by the of the experiments. However, the considerable effect of temperature on H2O storage capacity in olivine must be taken into account to avoid overestimation of the bulk upper mantle H2O storage capacity. 相似文献
102.
We present the software program THERIA_G, which allows for numerical simulation of garnet growth in a given volume of rock
along any pressure–temperature–time (P–T–t) path. THERIA_G assumes thermodynamic equilibrium between the garnet rim and the rock matrix during growth and accounts for
component fractionation associated with garnet formation as well as for intracrystalline diffusion within garnet. In addition,
THERIA_G keeps track of changes in the equilibrium phase relations, which occur during garnet growth along the specified P–T–t trajectory. This is accomplished by the combination of two major modules: a Gibbs free energy minimization routine is used
to calculate equilibrium phase relations including the volume and composition of successive garnet growth increments as P and T and the effective bulk rock composition change. With the second module intragranular multi-component diffusion is modelled
for spherical garnet geometry. THERIA_G allows to simulate the formation of an entire garnet population, the nucleation and
growth history of which is specified via the garnet crystal size frequency distribution. Garnet growth simulations with THERIA_G
produce compositional profiles for the garnet porphyroblasts of each size class of a population and full information on equilibrium
phase assemblages for any point along the specified P–T–t trajectory. The results of garnet growth simulation can be used to infer the P–T–t path of metamorphism from the chemical zoning of garnet porphyroblasts. With a hypothetical example of garnet growth in a
pelitic rock we demonstrate that it is essential for the interpretation of the chemical zoning of garnet to account for the
combined effects of the thermodynamic conditions of garnet growth, the nucleation history and intracrystalline diffusion.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
相似文献
F. GaidiesEmail: |
103.
Mauro Lo Cascio Yan Liang Nobumichi Shimizu Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102
The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing
pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum
capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free,
olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across
the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations
in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and
is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange
between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt
interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is
especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt
partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive
boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume
diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements
in residual minerals reequilibrate with their surrounding melt.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
104.
105.
David M. Hirsch 《Contributions to Mineralogy and Petrology》2008,155(4):401-415
Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors
governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts
were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using
high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological
methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural
analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast
to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast
size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast
size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization
annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust
pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these
calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism
bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures
for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens,
respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet
crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations
of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal
size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily
to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important
in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites. 相似文献
106.
A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles. 相似文献
107.
By using continuous helium flow during the crushing of calcite speleothem samples, we are able to recover liberated inclusion waters without isotopic fractionation. A paleotemperature record for the Jacklah Jill Cave locality, Vancouver Island, BC, was obtained from a 30-cm tall stalagmite that grew 10.3-6.3 Ka ago, using δ18O values of the crushed calcite and of the inclusion water as inferred from its δD. It is found that the locality experienced mean annual temperature variations up to 11 °C over a 4-Ka period in the early Holocene. At the beginning of the period, local temperature quickly increased from a minimum of ∼1 °C to around 10 °C, but this early climate optimum, about 3 °C warmer than today, only lasted for ∼1200 years. About 8.6 Ka ago, temperature had declined to ∼7 °C, approximately the same as the modern cave temperature. Since then, the study area has experienced only minor temperature fluctuations, but there was a brief fall to ∼4 °C at around 7 Ka ago, which might be caused by a short lived expansion of local alpine glaciers. The long-term T-dependence of δD was 1.47‰/°C, identical to the value in modern precipitation. 相似文献
108.
Three planktonic foraminiferal species Globigerina bulloides, Neogloboquadrina pachyderma (d), and Globorotalia inflata collected from core-tops spanning 35° to 65°N in the North Atlantic were used for U/Ca and Mg/Ca and foraminiferal shell weight analyses. Except for U/Ca in G. bulloides calcified under warm conditions (>∼13 °C), U/Ca ratios in all three studied species increase with decreasing latitude and show strong positive correlations with Mg/Ca ratios. A dissolution effect on planktonic U/Ca is suggested by decreased shell weight and U/Ca and Mg/Ca ratios for shells from very deep water depth (>4.4 km) along the latitudinal transect. G. bulloides from down core samples in the North Atlantic show low U/Ca ratios during the last glacial and high ratios during the Holocene, similar to the Mg/Ca evolution trend. In general, our data indicate that the U incorporation into planktonic foraminiferal carbonates is strongly influenced by calcification temperature, although U/Ca in G. bulloides may be affected by seawater carbonate ion concentration under warm conditions and/or other factors. 相似文献
109.
Quantitative sinkhole hazard assessments in karst areas allow calculation of the potential sinkhole risk and the performance
of cost-benefit analyses. These estimations are of practical interest for planning, engineering, and insurance purposes. The
sinkhole hazard assessments should include two components: the probability of occurrence of sinkholes (sinkholes/km2 year) and the severity of the sinkholes, which mainly refers to the subsidence mechanisms (progressive passive bending or
catastrophic collapse) and the size of the sinkholes at the time of formation; a critical engineering design parameter. This
requires the compilation of an exhaustive database on recent sinkholes, including information on the: (1) location, (2) chronology
(precise date or age range), (3) size, and (4) subsidence mechanisms and rate. This work presents a hazard assessment from
an alluvial evaporite karst area (0.81 km2) located in the periphery of the city of Zaragoza (Ebro River valley, NE Spain). Five sinkholes and four locations with features
attributable to karstic subsidence where identified in an initial investigation phase providing a preliminary probability
of occurrence of 0.14 sinkholes/km2 year (11.34% in annual probability). A trenching program conducted in a subsequent investigation phase allowed us to rule
out the four probable sinkholes, reducing the probability of occurrence to 0.079 sinkholes/km2 year (6.4% in annual probability). The information on the severity indicates that collapse sinkholes 10–15 m in diameter
may occur in the area. A detailed study of the deposits and deformational structures exposed by trenching in one of the sinkholes
allowed us to infer a modern collapse sinkhole approximately 12 m in diameter and with a vertical throw of 8 m. This collapse
structure is superimposed on a subsidence sinkhole around 80 m across that records at least 1.7 m of synsedimentary subsidence.
Trenching, in combination with dating techniques, is proposed as a useful methodology to elucidate the origin of depressions
with uncertain diagnosis and to gather practical information with predictive utility about particular sinkholes in alluvial
karst settings: precise location, subsidence mechanisms and magnitude, and timing and rate of the subsidence episodes. 相似文献
110.
Gregory P. Marchildon Suren Kulshreshtha Elaine Wheaton Dave Sauchyn 《Natural Hazards》2008,45(3):391-411
Agriculture in the southern Great Plains of Canada has been particularly vulnerable to prolonged episodes of drought. Using
climate data and a precipitation minus potential evapotranspiration index, the extent of the region’s exposure to drought
is examined. Between 1914 and 1917, the Dry Belt was particularly vulnerable to drought, whereas after 1928, a much larger
region known as the Palliser Triangle covering most of southern Alberta and Saskatchewan was much more exposed to drought.
These droughts provoked major institutional adaptation, in particular the establishment of the Special Areas Board by the
Government of Alberta, and the creation of the Prairie Farm Rehabilitation Administration by the Government of Canada. Both
organizations have proved to be relatively permanent public adaptations to the natural hazard of drought in the region. Moreover,
these earlier experiences with prolonged drought as well as institution-building may be of value in helping the residents
of the Palliser Triangle adapt to predicted climate changes in the future as well as anticipate some of the barriers to effective
institutional adaptation. 相似文献