Behaviour of radiogenic Pb in zircon during ultrahigh-temperature metamorphism: an ion imaging and ion tomography case study from the Kerala Khondalite Belt,southern India

Zircon crystals from a locally charnockitized Paleoproterozoic high-K metagranite from the Kerala Khondalite Belt (KKB) of southern India have been investigated by high-spatial resolution secondary ion mass spectrometry analysis of U–Th–Pb and rare earth elements (REE), together with scanning ion imaging and scanning ion tomography (depth-profiled ion imaging). The spot analyses constrain the magmatic crystallization age of the metagranite to ca. 1,850 Ma, with ultrahigh-temperature (UHT) metamorphism occurring at ca. 570 Ma and superimposed charnockite formation at ca. 520–510 Ma, while the ion imaging reveals a patchy distribution of radiogenic Pb throughout the zircon cores. Middle- to heavy-REE depletion in ca. 570 Ma zircon rims suggests that these grew in equilibrium with garnet and therefore date the UHT metamorphism in the KKB. The maximum apparent ²⁰⁷Pb/²⁰⁶Pb age obtained from the unsupported radiogenic Pb concentrations is also consistent with formation of the Pb patches during this event. The superimposed charnockitization event appears to have caused additional Pb-loss in the cores and recrystallization of the rims. The results of depth-profiling of the scanning ion tomography image stack show that the Pb-rich domains range in size from <5 nm to several 10 nm (diameter if assumed to be spherical). The occurrence of such patchy Pb has previously been documented only from UHT metamorphic zircon, where it likely results from annealing of radiation-damaged zircon. The formation of a discrete, heterogeneously distributed and subsequently immobile Pb phase effectively arrests the normal Pb-loss process seen at lower grades of metamorphism.     

Street-scale storm surge load impact assessment using fine-resolution numerical modelling: a case study from Nemuro,Japan

Natural Hazards - Due to gradual sea level rise and changes in the climate system, coastal vulnerability to storm surge hazards is expected to increase in some areas. Studies regarding the effect...     

Deep-sea hydrocarbon seep gastropod Bathynerita naticoidea responds to cues from the habitat-providing mussel Bathymodiolus childressi

Bathynerita naticoidea (Gastropoda: Neritidae) is a numerically dominant heterotrophic gastropod found at hydrocarbon seep sites on the upper Louisiana slope of the Gulf of Mexico. Snails of this species are commonly associated with beds of the methanotrophic mussel Bathymodiolus childressi (Bivalvia: Mytilidae), and their population structure mirrors that of the mussels they are found among. Previous studies have shown that these snails feed on bacteria and decomposing periostracum on the B. childressi shell. We predicted that B. naticoidea might be attracted to cues specific to its preferred habitat, such as dissolved methane, mucus from conspecific snails, or metabolites produced by B. childressi mussels. To examine this, we used a flow‐through Y‐maze system to investigate the behavior of B. naticoidea exposed to these potential cues. We found that the nerite is not attracted to methane, but is strongly attracted to seawater conditioned with B. childressi. The attractant appears to be specific to this type of mussel, and is not a soluble cue produced by conspecific snails.     

Composition, porosity, and reservoir potential of the Middle Jurassic Kashafrud Formation, northeast Iran

In the Kopet-Dagh Basin of Iran, deep-sea sandstones and shales of the Middle Jurassic Kashafrud Formation are disconformably overlain by hydrocarbon-bearing carbonates of Upper Jurassic and Cretaceous age. To explore the reservoir potential of the sandstones, we studied their burial history using more than 500 thin sections, supplemented by heavy mineral analysis, microprobe analysis, porosity and permeability determination, and vitrinite reflectance.The sandstones are arkosic and lithic arenites, rich in sedimentary and volcanic rock fragments. Quartz overgrowths and pore-filling carbonate cements (calcite, dolomite, siderite and ankerite) occluded most of the porosity during early to deep burial, assisted by early compaction that improved packing and fractured quartz grains. Iron oxides are prominent as alteration products of framework grains, probably reflecting source-area weathering prior to deposition, and locally as pore fills. Minor cements include pore-filling clays, pyrite, authigenic albite and K-feldspar, and barite. Existing porosity is secondary, resulting largely from dissolution of feldspars, micas, and rock fragments, with some fracture porosity. Porosity and permeability of six samples averages 3.2% and 0.0023 mD, respectively, and 150 thin-section point counts averaged 2.7% porosity. Reflectance of vitrinite in eight sandstone samples yielded values of 0.64-0.83%, in the early mature to mature stage of hydrocarbon generation, within the oil window.Kashafrud Formation petrographic trends were compared with trends from first-cycle basins elsewhere in the world. Inferred burial conditions accord with the maturation data, suggesting only a moderate thermal regime during burial. Some fractures, iron oxide cements, and dissolution may reflect Cenozoic tectonism and uplift that created the Kopet-Dagh Mountains. The low porosity and permeability levels of Kashafrud Formation sandstones suggest only a modest reservoir potential. For such tight sandstones, fractures may enhance the reservoir potential.     

Evidence for microbiological manganese oxidation in the river Tamar Estuary, South West England

Water samples from the Tamar Estuary oxidized manganese when supplemented with Mn²⁺ (2 mgl⁻¹). The rates of oxidation were depressed in the presence of various metabolic inhibitors. The effect of Mn²⁺ and temperature on the rate of manganese oxidation suggested that a biological process was largely responsible for converting Mn²⁺ to Mn⁴⁺. Rates of manganese oxidation were much higher in freshwater (3·32 μgl⁻¹ h⁻¹ in water containing 30 mgl⁻¹ of suspended matter) than in saline water (0·7 μgl⁻¹ h⁻¹ in water of salinity 32‰) containing the same amount of particulate matter. The rate of manganese oxidation was proportional to the particulate load (up to 100 mgl⁻¹ particulates).     

Seasonal cycles and long-term trends of plankton in shelf and oceanic habitats of the Norwegian Sea in relation to environmental variables

The plankton abundance data of the Continuous Plankton Recorder (CPR) route from Bergen or Rotterdam to Weather Station Mike (6444^′N, 2E) from 1949 to 1981 were analysed for long-term trends and seasonal production cycles, and were related to environmental data. The data were explored using the canonical correlation analysis and nonparametric techniques like the Nadaraya–Watson regression. While large copepods such as Calanus spp. and Metridia lucens did not show any temporal trends, a sharp decrease in the abundances of smaller copepods and phytoplankton was observed after 1960. The temporal trends were not related to the NAO, but did show a correlation with the wind direction. Seasonal abundance curves showed that production of both phytoplankton and zooplankton taxa started earlier in coastal water compared to Atlantic water. From the 1950s to the 1970s most taxa showed a delay in the start of the seasonal production cycles, indicating a reduction in the length of the productive cycle. This may to some extent explain the reduced abundance of smaller copepods, phytoplankton and other species during the 1960s and 1970s.     

Palynology and petroleum potential of the Kazhdumi Formation (Cretaceous: Albian–Cenomanian) in the South Pars field,northern Persian Gulf

The Kazhdumi Formation of the Bangestan Group is a well-known source rock that has produced abundant oil in most petroleum fields in the Zagros Basin, which stretches from northwest to southwest Iran over hundreds of kilometres. The formation reaches a thickness of 230 m at the type section in northwest Zagros but thins out to 40–50 m in wells studied from the South Pars giant petroleum field, where it comprises mainly grey shales with occasional intercalations of marls and sandstones. South Pars, best known as the Iranian part of the world's largest non-associated gas field, contains small quantities of oil above and below the Kazhdumi Formation.     

Landscape-scale analysis of ecosystem risk and returns: A new tool for ICZM

Management of the coastal zone often focuses on “islands” of high value ecosystems, in terms of economic value or conservation. However, integrated management requires landscape-level analysis of all ecosystem values. The biodiversity portfolio analysis (BPA) method is derived from the logic used in share (equity) portfolio management in terms of balancing within a portfolio the returns with the risks. Optimising the returns from a share portfolio, or a suite of ecosystems in a landscape, is dependent on the relationship between the units in terms of risk and return. Three case studies are then presented to test the applicability of the BPA method at the international (North West Europe), regional (Durham Heritage Coast, UK) and local (part of South Uist, Outer Hebrides, UK) spatial scale. The Biodiversity Portfolio Analysis for NW Europe showed that risk and return were highly correlated in the studied Member States. The ranking of risk and return, with the highest first, was Ireland > UK > France=Netherlands > Belgium. For these Member States the risks to ecosystem service provision were positively correlated with GNI (r=0.97, P<0.01); suggesting that the higher the economic importance of coastal and marine resources in a Member State the more at risk the resources are. The regional and local case studies were more focussed on providing information on which to base Integrated Coastal Zone Management (ICZM) decision making; both case studies used stakeholder participation to determine risks and returns. The conclusions from these two case studies show how the BPA method can be useful in terms of setting ICZM priorities and in addressing local coastal issues. The BPA involves making a number of assumptions, however, it does provide coastal managers with a potential tool to strategically plan due to increased awareness of the interaction between the ecosystems in the portfolio.There is a need for such techniques, which involve stakeholder participation and which create objective outcomes, to support the implementation of ICZM.     

Rapid visualization of plankton abundance and taxonomic composition using the Video Plankton Recorder

Traditional methods for determining spatial distributions of planktonic taxa involve net, pump, and bottle collections followed by the tedious and time-consuming task of plankton sample analysis. Thus, plankton ecologists often require months or even years to process samples from a single study. In this paper, we present a method that allows rapid visualization of the distribution of planktonic taxa while at sea. Rapid characterization of plankton distributions is essential in the dynamic physical environment, where biological and physical patterns can change quickly. Such a “sample-and-observe” capability is necessary for mapping ephemeral features (such as patches, eddies, jets, plumes) and determining appropriate locations to conduct more localized sampling, including in situ observational studies. We describe the techniques used in imaging the plankton, analyzing the video, and visualizing the data. We present an example of at-sea data analysis conducted aboard R.V. Columbus Iselin on Georges Bank in May 1994 and visualizations of the 3-dimensional distribution of selected planktonic taxa in a 2 × 2 km × 90 m volume of seawater. A video of the image processing and visualization is included on the CD-ROM accompanying this volume and is an essential part of this paper.