Characterisation of brown coal humic acids and modified humic acids using pyrolysis gcms and other techniques

It has been proposed that Victorian brown coal can be considered as a two-component structure — a lignocellulosic “host”, containing various amounts of weakly bound or entrapped “guest” material together with very small amounts of inorganic and/or mineral matter. The latter predominantly consists of wax esters and/or terpenoid material. In this paper we describe attempts to gain structural information regarding the more complex, “host” component of the coal. Our initial model compound has been humic acid that can be readily obtained from the coal by alkaline extraction. It has been found that “pure” humic acid, free from material associated with the “guest” components of the coal, can be obtained by a highly selective, low-yielding alkaline extraction. This humic acid has been studied by nmr spectroscopy and pyrolysis gas chromatography-mass spectroscopy (py-gc/ms). The products arising from py-gc/ms have been compared with those obtained from similar pyrolysis of whole coals. Alkylation of humic acids using alkyl halides in the presence of base has been successfully carried out and reactivity of the resulting materials compared with those of the parent coal and humic acid.     

Leucoxene fish as a micro-kinematic indicator

Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis.     

Neogene volcanism and Holocene earthquakes in the Tanlu fault zone, eastern China

In this paper, we study the relationship between Neogene volcanism and Holocene earthquakes in the Tanlu fault, eastern China. We find that fault segments through which Neogene and Quaternary magma have extruded do not show Holocene slip because they are covered by unfaulted basalts. In contrast, fault branches that are away from the Quaternary volcanic centers display Quaternary faulting and are responsible for earthquakes as recorded both historically and geomorphologically. Therefore, magma intrusion appears to modify fault activity in two different ways: (1) within the faults, the cooling magma serves as a cohesion or barrier, welding the faults so that they become stronger in resisting slip; (2) beneath the faults, the upwelling magma promotes slip of faults above the magma body, and hence generation of earthquakes. Physically, the first case results from contraction of the cooling magma, which causes a relative increase in fault-normal stress so that the fault failure resistance is enhanced. The second case results from the upward dynamic force and the heat brought in by the magma body, both of which cause the effective fault-normal stress to decrease so that the fault failure resistance is reduced. That could explain why earthquakes occur on faults bypassing the volcanic centers as typified in the Yishu fault zone and in the regions where heat flows are relatively high as shown in the Bohai Bay area.     

A traverse through the western Kunlun (Xinjiang,China): tentative geodynamic implications for the Paleozoic and Mesozoic

The northern part of the western Kunlun (southern margin of the Tarim basin) represents a Sinian rifted margin. To the south of this margin, the Sinian to Paleozoic Proto-Tethys Ocean formed. South-directed subduction of this ocean, beneath the continental southern Kunlun block during the Paleozoic, resulted in the collision between the northern and southern Kunlun blocks during the Devonian. The northern part of the Paleo-Tethys Ocean, located to the south of the southern Kunlun, was subducted to the north beneath the southern Kunlun during the Late Paleozoic to Early Mesozoic. This caused the formation of a subduction-accretion complex, including a sizeable accretionary wedge to the south of the southern Kunlun. A microcontinent (or oceanic plateau?), which we refer to as “Uygur terrane,” collided with the subduction complex during the Late Triassic. Both elements together represent the Kara-Kunlun. Final closure of the Paleo-Tethys Ocean took place during the Early Jurassic when the next southerly located continental block collided with the Kara-Kunlun area. From at least the Late Paleozoic to the Early Jurassic, the Tarim basin must be considered a back-arc region. The Kengxiwar lineament, which “connects” the Karakorum fault in the west and the Ruogiang-Xingxingxia/Altyn-Tagh fault zone in the east, shows signs of a polyphase strike-slip fault along which dextral and sinistral shearing occurred.     

The age and thermal history of Cerro Rico de Potosi, Bolivia

 Cerro Rico de Potosi, Bolivia, is the world’s largest silver deposit and has been mined since the sixteenth century for silver, and for tin and zinc during the twentieth century, together with by-product copper and lead. The deposit consists primarily of veins that cut an altered igneous body that we interpret to be a dacitic volcanic dome and its underlying tuff ring and explosion breccia. The deposit is compositionally and thermally zoned, having a core of cassiterite, wolframite, bismuthinite, and arsenopyrite surrounded by a peripheral, lower-temperature mineral assemblage consisting principally of sphalerite, galena, lead sulfosalt, and silver minerals. The low-temperature assemblage also was superimposed on the high-temperature assemblage in response to cooling of the main hydrothermal system. Both the dacite dome and the ore fluids were derived from a larger magmatic/hydrothermal source at depth. The dome was repeatedly fractured by recurrent movement on the fault system that guided its initial emplacement. The dome was extruded at 13.8±0.2 Ma (2σ), based on U-Th-Pb dating of zircon. Mineralization and alteration occurred within about 0.3 my of dome emplacement, as indicated by a ⁴⁰Ar/³⁹Ar date of 13.76±0.10 Ma (1σ) for sericite from the pervasive quartz-sericite-pyrite alteration associated with the main-stage, high-temperature, mineralization. The last thermal event able to reset zircon fission tracks occurred no later than 12.5±1.1 Ma (1σ), as indicated by fission-tract dating. Minor sericite, and magmatic-steam alunite veins, were episodically formed around 11 Ma and between 8.3 and 5.7 Ma; the younger episodes occurring at the time of extensional fracturing at Cerro Rico and widespread volcanism in the adjacent Los Frailes volcanic field. None of these younger events appear to be significant thermal/mineralizing events; the exceptionally flat thermal release pattern of ³⁹Ar from sericite and the results of the fission-tract dating of zircon show that none of the younger events was hot enough, and lasted long enough, to cause significant loss of Ar or annealing of zircon fission tracks. U-Th-Pb dating of zircon cores indicates a Precambrian progenitor for some zircons, and REE analyses of dated samples of hydrothermally altered dacite show the presence of a prominent positive Eu anomaly, which constrains interpretations of the origin and evolution of the magmatic/hydrothermal system. Received: 14 October 1995/Accepted: 29 January 1996     

An evaluation of models of apatite compositional variability using apatite from the Middle Banded series of the Stillwater Complex,Montana

 Apatite is a relatively common accessory mineral in the olivine-bearing zones (OB-III and OB-IV) of the Middle Banded series of the Stillwater complex, occurring interstitial to cumulus grains, as monomineralic inclusions in cumulus grains, and in polymineralic clusters which may or may not be included in the cumulus grains. Eighty-nine of 185 samples examined were found to contain some apatite. The F-Cl-OH content of the apatite show distinct stratigraphic variations. XClAp (mole fraction Cl in apatite) of interstitial apatite increases upsection in both OB-III and OB-IV with average values ranging from 0.15 to 0.85 in OB-III and from 0.03 to 0.60 in OB-IV. XFAp varies inversely with XClApwith average values ranging from 0.00 to 0.70, while XOHAp remains relatively constant near 0.40 or decreases slightly with height. These variations are remarkable given that no appreciable stratigraphic variations in either the major or trace element compositions of any of the cumulus minerals are found in the 800 m of section that comprise OB-III and OB-IV. Within-sample variation of XClAp for samples containing Cl-rich apatite is substantially larger (up to 0.65 XClAp) than for samples with more F-rich apatite (XClAp varies by approximately 0.15). Although interstitial apatite is found throughout OB-III and OB-IV, apatite occurring as monomineralic inclusion in cumulus grains or in polymineralic clusters is almost exclusively found in samples with Cl-rich apatite. The data are best explained by a model involving the degassing of a Cl-rich volatile phase from the crystallizing interstitial liquid. The up-section migration of this fluid resulted in the crystallization of F-rich apatite in the lower portion and progressive Cl-enrichment in the apatite with height. The presence of hornblende-bearing dikes, veins and pegmatoids at the level of maximum Cl-enrichment is consistent with a fluid migration model. Received: 5 October 1995 / Accepted: 19 March 1996     

Trace element and isotope geochemistry of depleted peridotites from an N-MORB type ophiolite (Internal Liguride,N. Italy)

 Mantle peridotites of the Internal Liguride (IL) units (Northern Apennines) constitute a rare example of the depleted lithosphere of the Jurassic Ligurian Tethys. Detailed chemical (ICP-MS and SIMS techniques) and isotopic investigations on very fresh samples have been performed with the major aim to constrain the timing and mechanism of their evolution and to furnish new data for the geodynamic interpretation. The data are also useful to discuss some general geochemical aspects of oceanic-type mantle. The studied samples consist of clinopyroxene-poor spinel lherzolites, showing incipient re-equilibration in the plagioclase-facies stability field. The spinel-facies assemblage records high (asthenospheric) equilibration temperatures (1150–1250° C). Whole rocks, and constituent clinopyroxenes, show a decoupling between severe depletion in highly incompatible elements [light rare earth elements (LREE), Sr, Zr, Na, Ti] and less pronounced depletion in moderate incompatible elements (Ca, Al, Sc, V). Bulk rocks also display a relatively strong M(middle)REE/H(heavy)REE fractionation. These compositional features indicate low-degree (<10%) fractional melting, which presumably started in the garnet stability field, as the most suitable depletion mechanism. In this respect, the IL ultramafics show strong similarity to abyssal peridotites. The Sr and Nd isotopic compositions, determined on carefully handpicked clinopyroxene separates, indicate an extremely depleted signature (⁸⁷Sr/⁸⁶Sr=0.702203–0.702285; ¹⁴³Nd/¹⁴⁴Nd=0.513619–0.513775). The Sm/Nd model ages suggest that the IL peridotites melted most likely during Permian times. They could record, therefore, the early upwelling and melting of mid ocean ridge basalt (MORB) type asthenosphere, in response to the onset of extensional mechanisms which led to the opening of the Western Tethys. They subsequently cooled and experienced a composite subsolidus evolution testified by multiple episodes of gabbroic intrusions and HT-LP retrograde metamorphic re-equilibration, prior to their emplacement on the sea floor. The trace element chemistry of IL peridotites also provides useful information about the composition of oceanic-type mantle. The most important feature concerns the occurrence of Sr and Zr negative anomalies (relative to “adjacent” REE) in both clinopyroxenes and bulk rocks. We suggest that such anomalies reflect changes in the relative magnitude of Sr, Zr and REE partition coefficients, depending on the specific melting conditions. Received: 15 February 1995/Accepted: 4 August 1995     

Use of landslides for paleoseismic analysis

In many environments, landslides preserved in the geologic record can be analyzed to determine the likelihood of seismic triggering. If evidence indicates that a seismic origin is likely for a landslide or group of landslides, and if the landslides can be dated, then a paleo-earthquake can be inferred, and some of its characteristics can be estimated. Such paleoseismic landslide studies thus can help reconstruct the seismic history of a site or region. In regions that contain multiple seismic sources and in regions where surface faulting is absent, paleoseismic ground-failure studies are valuable tools in hazard and risk studies that are more concerned with shaking hazards than with interpretation of the movement histories of individual faults. Paleoseismic landslide analysis involves three steps: (1) identifying a feature as a landslide, (2) dating the landslide, and (3) showing that the landslide was triggered by earthquake shaking. This paper addresses each of these steps and discusses methods for interpreting the results of such studies by reviewing the current state of knowledge of paleoseismic landslide analysis.     

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.