Analyzing Changes in Urban Form and Commuting Time*

Urban work trips have changed in important ways during the last decades. In Québec City, a medium‐sized Canadian metropolitan area, commuting distances increased for both male and female workers between 1977 and 1996, while durations increased for male workers and decreased for female workers. This article seeks to identify spatial and social factors responsible for these changes. We develop a disaggregate model of trip duration estimated on the basis of large samples derived from travel surveys comparable through time. Using categorical variables to specify change, we are able to separate change effects from level effects attributable to various dimensions of urban form. Our analysis clearly indicates that, once travel mode and key social factors are controlled for, the shift from a monocentric to a dispersed city form is responsible, in the Québec metropolitan area, for increasing commuting time. This is contrary to findings in larger metropolitan areas, where, it has been argued, the suburbanization of jobs maintains stability in commuting duration.     

Influence of a cyclic and dynamic loading history on dynamic properties of dry sand, part II: cyclic axial preloading

Initial fabric of a soil induced by its cyclic strain history is an important parameter among others like void ratio, state of stress and amplitude concerning the further accumulation of deformations under cyclic loading. It is of high importance to determine methods in order to estimate the initial fabric of the grain skeleton or the cyclic loading history of the soil. An attempt is made in this paper to correlate small strain stiffness of non-cohesive soil with its cyclic loading history. For this purpose several cyclic triaxial tests with specimens subjected to cyclic axial loading were performed and changes of small strain soil properties due to this cyclic loading were studied. All these tests showed only moderate changes of small strain stiffnesses independently of the different boundary conditions. Thus, a correlation between fabric or strain history and small strain stiffnesses seems not to be possible.     

Results from 44 months of observations with a superconducting gravimeter at Moxa/Germany

Results for more than 42 months of observations with the superconducting gravimeter CD-034 at the Geodynamic Observatory Moxa are discussed. Moxa observatory is one of the newer stations within the ‘Global Geodynamics Project’ (GGP). A special feature of the gravimeter at Moxa is its dual sensor system; differences in the results obtained from the two sensor recordings are generally well within the standard deviations of the tidal analysis. One significant difference concerns the slightly different drift rates of 31 and 49.5 nm/s² per year for upper and lower sensor; both sensor drifts can be fitted by a linear function. We find that the noise levels are close to the ‘New Low Noise Model’ for the seismic-modes and are also low in the tidal bands. Due to this low noise, Moxa is a station well suited to search for small geodynamic signals. The long-period variation in the gravity residuals correlates well with the polar motion.The difference signal between the two sensor recordings has a peak-to-peak amplitude of about 6 nm/s² and shows systematic variations. Its spectrum is characterised by instrumental noise between 0.2 and 0.4 cph. The noise level of the difference and of the sum of the two residual datasets are clearly lower, respectively, higher than the noise contents of the gravity residuals themselves. This is a strong indication for the existence of broadband signals common to the two residual datasets, leading to the conjecture that the reduction of environmental effects is still not sufficient.Our results once more emphasize the necessity to correct the data for barometric pressure effects when analyzing the data for seismic modes. The reduction visibly increases the signal-to-noise ratio in the low frequencies of the mode band and helps to avoid misinterpreations of peaks. Besides the well known barometric pressure influence we can establish hydrological effects in the data which are probably caused by soil moisture and groundwater table variations as well as by batch-wise water movement within the weathering layer. As the major part of the observatory surroundings is above gravimeter level, an anticorrelation between hydrological and gravity changes is observed. In addition, it can be shown that global hydrological effects reach an order of magnitude that makes it necessary to consider these effects when analyzing long-period signals like polar motion. Vice versa these effects are large enough to be detectable in the gravity data. A first joint analysis of five datasets from the GGP network shows no indications for signals related to the Slichter triplet or core modes.     

Quality Assurance of Hydrocarbon Measurements for the German Tropospheric Research Focus (TFS)

In the German Focus on Tropospheric Research (TFS) independent quality assurance procedures were implemented in order to obtain information on data quality and comparability of the different measurements made in the different field campaigns. This paper describes the results for measurements of hydrocarbons using in-situ gas chromatographictechniques and off line analysis of samples collected in canisters (analysed by two central laboratories CL-1 and CL-2) and samples collected on adsorption tubes. The QA-procedures included comparisons with synthetic standards (prepared by EN 45001 certified laboratories), absolute calibration with a diffusion source, and an instrument/methodology comparison in ambient air. Harmonisation of the ambient measurements was achieved with a complex mixture (NCAR/BERLIOZ) containing 70 commonly observed hydrocarbons at mixing ratios of 0.2 to 10 ppb (mole fraction) in nitrogen, which was calibrated by referencing to hydrocarbon standards of the National Institute for Standards and Technology (NIST).For the certified synthetic standards, the experienced groups agreed to within ± 20% for most compounds. Much larger discrepancies were observed for the new Airmotec HC2010 instruments due to problems with identification, co-elution and blanks/memory effects. The results in ambient air were similar: Reasonable agreement was found for the results from the experienced groups with well characterised in situ instruments andfor the charcoal tubes, whereas larger discrepancies were observed for the results from new groups and instruments. For the latter, only selected compounds met the data quality objectives (DQO). The canister samples analysed by CL-2 were in good agreement with the reference instrument, whereas large deviations were found for a number of compounds in the analysis of the same canisters by CL-1. The results of the comparison provided the final basis for flagging and harmonising the data from all participants prior to their submission to the TFS central data bank.     

Isotopic dating of the emplacement of the ultramafic masses in the Serrania de Ronda,Southern Spain

A Rb-Sr analysis of suites of samples from a small intrusion of cordierite-bearing alkali granite into the peridotite of the Sierra Bermeja (Serrania de Ronda) yields an age of 22± 4 Ma ( = 1.42×10^–11 a^–1): Late Oligocene/Early Miocene. It is believed that the intrusion was derived from contact-anatectic melts produced along the hot ultramafic mass during and/or directly following its tangential, tectonic dislocation from a mantle diapir. Its age can thus be taken as dating the termination of the hot emplacement of the ultramafic masses. K-Ar dates of biotites and Rb-Sr dates of biotite/whole-rock pairs in contact-metamorphic wall rocks along the ultramafics mostly lie between 19.5 and 18.5 Ma. This probably indicates that about 19 Ma ago the contact-zones of the ultramafic masses had cooled down to the blocking temperature of biotite to Rb-Sr and K-Ar.     

Formation, prevention and breaking of sea water in crude oil emulsions ‘chocolate mousses’

During the combatting of oil spills, the handling of the stable sea water in crude oil emulsions called ‘chocolate mousses’, either at sea or on the beach, is often a major problem.

A recent laboratory study of the formation and properties of such emulsions revealed the key roles played by asphaltenes and crystallized wax in their stability.

Viscosity measurements showed that mousses with 70% vol. sea water are thixotropic and may solidify after having been pumped into the hold of a salvage vessel or into a storage tank. During a search for novel chemicals for combatting oil spills we found a type of chemical additive that is effective in preventing the formation of mousses, in greatly improving the pumpability of mousses once formed and in decreasing their water content after recovery or during storage. The additive, designated LA 1834, has been tested successfully in the laboratory, on a semi-technical scale in cooperation with the Netherlands State Waterways Board and in the large-scale clean-up operation after a recent oil spill in Greece. The compound keeps oil from dispersing vertically into the water column, when applied to spilled oil or mousse on a sea water surface and holds promise of environmental acceptability.