郯庐断裂带形成演化的年代学研究

通过对郯庐断裂带东侧张八岭蓝片岩带内白云母4 0 Ar - 3 9Ar年龄、断裂带内片麻状花岗岩中钾长石4 0 Ar- 3 9Ar年龄以及断裂带内断层泥K -Ar、ESR年龄的测定 ,并结合有关的地质和古地磁资料 ,厘定了郯庐断裂带形成和演化的过程 :(1)三叠纪 (2 44～ 2 0 9Ma)由于华北与扬子地块碰撞 ,郯庐断裂带形成为其主要左行平移时期 ;(2 )侏罗纪 (189～ 16 4Ma)时郯庐断裂东侧下扬子地块可能经历了逆时针转动 ;(3)白垩纪 (10 3～ 94Ma)开始郯庐断裂带伴随走滑平移而发生正断活动 ;(4)晚白垩—第三纪右旋平移阶段。郯庐断裂的形成与大别 -苏鲁变质带有关。     

Eclogite relics in the Variscan orogenic belt of Bulgaria (SE Europe)

Eclogitic rocks were sampled from two zones in the basement of the Sredna Gora terrane (central western Bulgaria): (1) partially retrogressed eclogites and amphibolites embedded in sillimanite-bearing garnet-micaschists with kyanite relics and migmatites and (2) banded amphibolites associated with muscovite-bearing metagranites within two-mica paragneisses. Rutile relics and oligoclase + green hornblende + epidote ± biotite pseudomorphs after garnet suggest an eclogite facies event. A tholeiitic, transitional affinity was determined for the protoliths, suggesting a continental rift environment, consistent with several eclogite-bearing complexes in the eastern segments of the Variscan belt that arose from the Cambro-Ordovician Gondwana break-up. Decreasing pressure after the eclogite overprint was demonstrated by (a) diopside-albite symplectite, and (b) plagioclase + red–brown to green amphibole kelyphite. The early static re-equilibration, dated to 398 ± 5.2 Ma by ⁴⁰Ar–³⁹Ar technique, was followed by an amphibolite facies foliation, which was pervasive in amphibolites, gneisses and micaschists, and poorly developed in eclogites. The lithospheric PT paths corresponding to higher and lower metamorphic gradients reflect the juxtaposition of crustal and lithospheric mantle units, respectively. In the build-up of the basement of the Balkan orogen, the physical properties of the lithological complexes might have influenced the collisional pattern of involved microplates.     

Caledonian high-pressure metamorphism in the Strona-Ceneri Zone (Southern Alps of southern Switzerland and northern Italy)

The Strona-Ceneri Zone comprises a succession of polymetamorphic, pre-Alpidic basement rocks including ortho- and paragneisses, metasedimentary schists, amphibolites, and eclogites. The rock pile represents a Late Proterozoic or Palaeozoic subduction accretion complex that was intruded by Ordovician granitoids. Eclogites, which occur as lenses within the ortho-paragneiss succession and as xenoliths within the granitoids record a subduction related high-pressure event (D1) with peak metamorphic conditions of 710 ± 30 °C at 21.0 ± 2.5 kbar. After isothermal uplift, the eclogites experienced a Barrowtype (D2) tectonometamorphic overprint under amphibolite facies conditions (570-630 °C, 7-9 kbar). U-Pb dating on zircon of the eclogites gives a metamorphic age of 457 ± 5 Ma, and syn-eclogite facies rutile gives a ²⁰⁶Pb/²³⁸U age of 443 ± 19 Ma classifying the subduction as a Caledonian event. These data show that the main tectonometamorphic evolution of the Strona-Ceneri Zone most probably took place in a convergent margin scenario, in which accretion, eclogitization of MOR-basalt, polyphase (D1 and D2) deformation, anatexis and magmatism all occurred during the Ordovician. Caledonian high-pressure metamorphism, subsequent magmatism and Barrow-type metamorphism are believed to be related to subduction and collision within the northern margin of Gondwana. Editorial handling: Edwin Gnos     

Reduction of surface subsidence risk by fly ash exploitation as filling material in deep mining areas

The possibility of filling empty underground spaces, which exist owing to the extraction of mineral raw materials, with fly ash and cement fly ash mixes has been studied for the purpose of reducing the impact of deep mining on the surface. The method of physical modelling was used to study the behaviour of fly ash mixes deposited in extracted mine spaces. The models were constructed for two different geometries of underground extracted mine spaces: into cavities of the type of large slits created in the course of mining in steeply lode deposits without subsequently filling the empty space and in vertical shafts of rectangular or circular cross-section with horizontal side headings that have partly caved in due to mine shocks or other seismic events.     

Enhanced bioremoval of refractory compounds from dyeing wastewater using optimized sequential anaerobic/aerobic process

The upflow anaerobic sludge blanket process followed by the biological aerated filter process was employed to improve the removal of color and recalcitrant compounds from real dyeing wastewater. The highest removal efficiency for color was observed in the anaerobic process, at 8-h hydraulic retention time, seeded with the sludge granule. In the subsequent aerobic process packed with the microbe-immobilized polyethylene glycol media, the removal efficiency for chemical oxygen demand increased significantly to 75 %, regardless of the empty bed contact time. The average influent non-biodegradable soluble chemical oxygen demand was 517 mg/L, and the average concentration in effluent from the anaerobic reactor was 363 mg/L, suggesting the removal of some recalcitrant matters together with the degradable ones. The average non-biodegradable soluble chemical oxygen demand in effluent from the aerobic reactor was 87, 93, and 118 mg/L, with the removal efficiency of 76, 74, and 67 %, at 24-, 12-, and 8-h empty bed contact time, respectively. The combined anaerobic sludge blanket and aerobic cell-entrapped process was effective to remove the refractory compounds from real dyeing wastewater as well as in reducing organic loading to meet the effluent discharge limits. This integrated process is considered an effective and economical treatment technology for dyeing wastewater.     

The Timescales of Magma Mixing in the Plumbing System of Bezymianny Volcano (Kamchatka): Insights from Diffusion Chronometry

Intrusion of magma of contrasting composition into a magma chamber often triggers eruptions of arc volcanoes. Application of the diffusion chronometry method allowed us to determine the time when fresh magma was supplied to the shallow chamber of Bezymianny volcano in the case of six eruptions in 2006–2012 and to compare them to the recorded seismic activity of this volcano. Two types of eruptions of Bezymianny volcano were distinguished, with a contrasting orthopyroxene rim being formed in the respective magmas (a) up to 3 years and (b) up to 2 months before the beginning of an eruption. It was shown that these differences are caused by two different paths of magma supply to the shallow chamber of Bezymianny volcano.     

Geochemistry of Brines from Salt Ore Deposits in Western Tarim Basin

In the geological evolution of the Tarim Basin, many transgressions and relictions happened. So there have been plentiful sources of salt. Moreover, because of uttermost drought, a lot of salt has been deposited. It is possible to find potash salt in this area. In our fieldwork, we have found salt and brine in western Tarim Basin. Based on a geological survey and the characteristics of sedimentary facies and paleogeography, this paper deals with the geochemical parameters and discusses the possibility of formation of potash salt in terms of the chemical analyses of samples collected from western Tarim Basin. Results of brine analysis lead to some conclusions: most of these salt brines have eluviated from very thick halite beds, mainly chloridetype salt and this kind of halite does not reach the stage of potash deposition in all aspects; WKSL (Wukeshalu) occupies a noticeable place, and we should attach importance to this district because there have been some indicators of the occurrence of potash deposits as viewed from the contents of Br and K. Finally, low Br contents are recognized in the Tarim Basin as a result of salt aggradation, and this point of view has been proved by the results of this experiment and the data available. It cannot depend upon the index of Br to judge the evolution stage of halite. We must look for other facies of potash except marine facies.     

Discovery of Ordovician–Silurian metamorphic monazite in garnet metapelites of the Alpine External Aiguilles Rouges Massif

The pre-Mesozoic, mainly Variscan metamorphic basement of the Col de Bérard area (Aiguilles Rouges Massif, External domain) consists of paragneisses and micaschists together with various orthogneisses and metabasites. Monazite in metapelites was analysed by the electron microprobe (EMPA-CHIME) age dating method. The monazites in garnet micaschists are dominantly of Variscan age (330–300 Ma). Garnet in these rocks displays well developed growth zonations in Fe–Mg–Ca–Mn and crystallized at maximal temperatures of 670°C/7 kbar to the west and 600°C/7–8 kbar to the east. In consequence the monazite is interpreted to date a slightly pressure-dominated Variscan amphibolite-facies evolution. In mylonitic garnet gneisses, large metamorphic monazite grains of Ordovician–Silurian (~440 Ma) age but also small monazite grains of Variscan (~300 Ma) age were discovered. Garnets in the mylonitic garnet gneisses display high-temperature homogenized Mg-rich profiles in their cores and crystallized near to ~800°C/6 kbar. The Ordovician–Silurian-age monazites can be assigned to a pre-Variscan high-temperature event recorded by the homogenised garnets. These monazite age data confirm Ordovician–Silurian and Devonian–Carboniferous metamorphic cycles which were already reported from other Alpine domains and further regions in the internal Variscides.     

pp′-DDT adsorption to suspended particulate matter in sea water

A procedure was devised to study pp′-DDT [2,2-bis($\text{p-}\text{chlorophenyl}$)-1,1,1-trichloroethane] adsorption and desorption to suspended particulates in aqueous solutions. DDT adsorption to a marine sediment, sediment fractions, clay and humic acid suspended in sea water was investigated and the humic fraction was found to have a greater adsorbing capacity than the clay or sediment. Removal of the humic fraction from sediment reduced the adsorption capacity to less than 60 per cent of the original sediment sample. It was concluded that suspended humic particulates may be important agents for transporting chlorinated hydrocarbons through the water column and for concentrating them in sediments and in detritus-feeding organisms.     

Zoning of diamonds from the Mir kimberlite pipe: Results of Fourier-transformed infrared spectroscopy

Plates prepared of diamonds from the Mir kimberlite pipe were examined with FTIR spectroscopy. It is shown that B1 defects were formed by annealing during crystal growth, whereas B2 centers arose after growth cessation. The development of B2 centers in a natural diamond is the secondary process with respect to the aggregation of the nitrogen admixture. The kinetics of this process is related to the breakdown of an oversaturated solid solution. The results obtained make it possible to estimate the temperature and duration of natural diamond growth.