Non-linear station motions in epoch and multi-year reference frames

In the conventions of the International Earth Rotation and Reference Systems Service (e.g. IERS Conventions 2010), it is recommended that the instantaneous station position, which is fixed to the Earth’s crust, is described by a regularized station position and conventional correction models. Current realizations of the International Terrestrial Reference Frame use a station position at a reference epoch and a constant velocity to describe the motion of the regularized station position in time. An advantage of this parameterization is the possibility to provide station coordinates of high accuracy over a long time span. Various publications have shown that residual non-linear station motions can reach a magnitude of a few centimeters due to not considered loading effects. Consistently estimated parameters like the Earth Orientation Parameters (EOP) may be affected if these non-linear station motions are neglected. In this paper, we investigate a new approach, which is based on a frequent (e.g. weekly) estimation of station positions and EOP from a combination of epoch normal equations of the space geodetic techniques Global Positioning System (GPS), Satellite Laser Ranging (SLR) and Very Long Baseline Interferometry (VLBI). The resulting time series of epoch reference frames are studied in detail and are compared with the conventional secular approach. It is shown that both approaches have specific advantages and disadvantages, which are discussed in the paper. A major advantage of the frequently estimated epoch reference frames is that the non-linear station motions are implicitly taken into account, which is a major limiting factor for the accuracy of the secular frames. Various test computations and comparisons between the epoch and secular approach are performed. The authors found that the consistently estimated EOP are systematically affected by the two different combination approaches. The differences between the epoch and secular frames reach magnitudes of $23.6~\upmu \hbox {as}$ (0.73 mm) and $39.8~\upmu \hbox {as}$ (1.23 mm) for the x-pole and y-pole, respectively, in case of the combined solutions. For the SLR-only solutions, significant differences with amplitudes of $77.3~\upmu \hbox {as}$ (2.39 mm) can be found.     

Towards a Higher Comparability of Geothermometric Data obtained by Raman Spectroscopy of Carbonaceous Material. Part I: Evaluation of Biasing Factors

Raman spectroscopy of carbonaceous material (RSCM) is frequently used to determine metamorphic peak temperatures from the structural order of carbonaceous material enclosed in metasediments. This method provides a quick, robust and relatively cheap geothermometer. However, the comparability of the RSCM parameter is low as there are at least three major sources of biasing factors. These sources are the spectral curve‐fitting procedure, the sample characteristics itself and the experimental design including the used Raman system. To assess the impacts of the biasing factors on RSCM, a series of experiments was performed. The experiments showed that curve‐fitting is strongly influenced by individual operator‐bias and the degrees of freedom in the model, implying the need for a standardised curve‐fitting procedure. Due to the diversity of components (optics, light detection device, gratings, etc.) and their combinations within the Raman systems, different Raman instruments generally give differing results. Consequently, to estimate comparable metamorphic temperatures from RSCM data, every Raman instrument needs its own calibration. This demands a reference material series that covers the entire temperature calibration range. Although sample heterogeneity will still induce some variation, a reference material series combined with standardised curve‐fitting procedures will significantly increase the overall comparability of RSCM data from different laboratories.     

Asbestos and other fibrous minerals contained in the serpentinites of the Gimigliano-Mount Reventino Unit (Calabria,S-Italy)

Serpentinites are metamorphic rocks with good technological properties and valuable ornamental characteristics, which have been exploited since ancient times. Actually, their use is limited and monitored in several countries worldwide because they can contain fibrous asbestos minerals that may be carcinogenic. Furthermore, certain types of fibrous minerals can be confused with asbestos, and must therefore be carefully investigated. We have investigated the possible presence of the asbestos and non-asbestos fibrous phases contained in serpentinitic rocks in a meta-ophiolitic sequence from the Gimigliano-Mount Reventino Unit (Southern Italy), which had not been previously assessed. The detection and quantification of asbestos and the correct distinction of the fibrous non-asbestos minerals are very important not only from a scientific point of view, but also from a legislative one. This is especially the case for the administrative agencies that have to take decisions with regards to the implementation of public and occupational health protection measures (e.g., in road yards and quarry excavations). As a consequence of this, serpentinitic rock samples have been characterized in detail through X-ray powder diffraction, scanning and transmission electron microscopy combined with energy-dispersive spectrometry, analytical electron microscopy (SEM–EDS and TEM–AEM), differential scanning calorimetry, thermogravimetry and micro-Raman spectroscopy. Two kinds of asbestos and four kinds of non-asbestos fibrous silicates have been detected in the examined samples. In order of decreasing abundance these are polygonal serpentine, chrysotile, fibrous antigorite, tremolite, gedrite and magnesiohornblende. The size, morphology, crystallinity and chemical composition of the fibres were also discussed, in the light of the possible role these properties could play in the carcinogenic effect on human health.     

Earthquake imprints on a lacustrine deltaic system: The Kürk Delta along the East Anatolian Fault (Turkey)

Deltas contain sedimentary records that are not only indicative of water‐level changes, but also particularly sensitive to earthquake shaking typically resulting in soft‐sediment‐deformation structures. The Kürk lacustrine delta lies at the south‐western extremity of Lake Hazar in eastern Turkey and is adjacent to the seismogenic East Anatolian Fault, which has generated earthquakes of magnitude 7. This study re‐evaluates water‐level changes and earthquake shaking that have affected the Kürk Delta, combining geophysical data (seismic‐reflection profiles and side‐scan sonar), remote sensing images, historical data, onland outcrops and offshore coring. The history of water‐level changes provides a temporal framework for the depositional record. In addition to the common soft‐sediment deformation documented previously, onland outcrops reveal a record of deformation (fracturing, tilt and clastic dykes) linked to large earthquake‐induced liquefactions and lateral spreading. The recurrent liquefaction structures can be used to obtain a palaeoseismological record. Five event horizons were identified that could be linked to historical earthquakes occurring in the last 1000 years along the East Anatolian Fault. Sedimentary cores sampling the most recent subaqueous sedimentation revealed the occurrence of another type of earthquake indicator. Based on radionuclide dating (¹³⁷Cs and ²¹⁰Pb), two major sedimentary events were attributed to the ad 1874 to 1875 East Anatolian Fault earthquake sequence. Their sedimentological characteristics were determined by X‐ray imagery, X‐ray diffraction, loss‐on‐ignition, grain‐size distribution and geophysical measurements. The events are interpreted to be hyperpycnal deposits linked to post‐seismic sediment reworking of earthquake‐triggered landslides.     

Shallow groundwater temperature in the Turin area (NW Italy): vertical distribution and anthropogenic effects

This study investigated the thermal regime of shallow groundwater in the Turin area (NW Italy), where the large energy demand has motivated a new interest for renewable sources, such as the use of ground-source heat pumps for domestic heating and cooling. The vertical variability of the groundwater temperature between the ground surface and 10–20 m was detected: deeper temperatures were higher than shallow temperatures in spring, while a decrease with depth occurred in autumn. These variations are connected with the heating and cooling cycles of the ground surface due to the seasonal temperature oscillation. Variations below the seasonal oscillation are likely to be connected with the presence of advective heat transport due to the groundwater flow, according to the hydraulic features of a shallow aquifer. Temperature values mostly ranged between 12 and 14 °C in rural areas, while the values were between 14 and 16 °C below the Turin city. This groundwater warming is attributed to a widespread urban heat island phenomenon linked to warmer land surface temperatures in Turin city. Sparse warm outliers are connected with point heat sources and site-specific conditions of land and subsurface use, which may cause the aquifer temperature to rise. A relatively stable temperature below the seasonal fluctuation zone combined with high productivity and legislated limits for deeper groundwater use represent favourable conditions for a large-scale diffusion of groundwater heat pumps within the shallow aquifer. Moreover, this heat surplus should be regarded as a resource for future geothermal installations.