Relieffolgende Ablagerungen Vulkanischer Lockermassen

Zusammenfassung Als Beispiel primär in nicht horizontaler Stellung abgelagerter Schichten wird die Tuffeindeckung eines Gebirgsreliefs in Columbien beschrieben.     

Theoretical analysis of thermomagnetic properties, low-temperature hysteresis and domain structure of titanomagnetites

Magnetic hysteresis of coarse-grained titanomagnetites at room temperature is characterised by low coercive force, low relative remanence, and a high ratio of coercivity of remanence to coercive force. These properties are generally interpreted in terms of multidomain structure. At low temperatures, however, ulvöspinel-rich compositions exhibit hysteresis properties similar to those of single-domain assemblages, and on this basis Radhakrishnamurty and Deutsch have proposed an alternative interpretation of the domain structure of titanomagnetites having x 0.3 in terms of a mixture of single-domain and superparamagnetic particles. Low apparent Curie temperatures are attributed to the effects of thermal agitation above the blocking temperature.

We have examined theoretically the effects of thermal agitation on the low- and high-field thermomagnetic curves and find that observed Curie temperatures in general represent an intrinsic property of the magnetic mineral present, rather than reflecting thermal agitation. The high coercive force and relative remanence at low temperatures for titanomagnetites having x > 0.5 can be explained on the basis of the interaction of domain walls with crystal defects when the large increases in magnetocrystalline anisotropy and magnetostriction with decreasing temperature are taken into account. We discuss the evidence for the existence of domain walls in coarse-grained ulvöspinel-rich titanomagnetites and conclude that multidomain structure is well established.

It is also shown that fine titanomagnetite grains may have more than one blocking temperature. In any temperature interval for which superparamagnetic grains are present they will disproportionately influence susceptibility and low-field hysteresis.     

Electric field gradient calculation in forsterite,Mg2SiO4

The electric field gradient (EFG) in Mg₂SiO₄ is calculated on the basis of the extended point ion model, including the local term of the overlap contribution. The agreement with experimental data deduced from the quadrupole coupling constants and principal axes at the Mg sites is quite good. The results of the present calculation exhibit a small overlap contribution to the EFG at M1 and a clearly bigger one at M2, whereas the lattice contribution to the EFG at M1 and M2 is reversed. The distinct overlap effects are assumed to be due to the particular Mg₂SiO₄ crystal structure and the different point symmetry at M1 and M2. The oxygen polarizability and charge used to calculate the EFG tensor were found to be smaller than the theoretical polarizability and formal charge, respectively. The sign of the Mg quadrupole coupling constants at M1 and M2, which has not been determined experimentally, results from the EFG calculation as positive.     

J.H. Hagedoorn – inventing the Hapa: A review of a geophysicist's 'other' work and how it inspired others

This paper describes J.G. Hagedoorn's work on 'ultimate sailing'– the combination of a manned kite and a water kite called a Hapa, constituting a minimal sailing system – and the way others have taken up his challenge to sail while suspended from a kite. Hagedoorn's goal has not been entirely achieved, but 'near' and partial solutions have been reached. Kite-Hapa-sailing continues to pose a 'Holy Grail' type challenge to many kite-sailors.     

Determing the effects of El Niño-Southern Oscillation events on coastal water quality

The importance of the El Niño-Southern Oscillation (ENSO) on regional-scale climate variability is well recognized although the associated effects on local weather patterns are poorly understood. Little work has addressed the ancillary impacts of climate variability at the community level, which require analysis at a local scale. In coastal communities water quality and public health effects are of particular interest. Here we describe the historical influence of ENSO events on coastal water quality in Tampa Bay, Florida (USA) as a test case. Using approximate randomized statistics, we show significant ENSO influences on water quality particularly during winter months, with significantly greater fecal pollution levels during strong El Niño winters and significantly lower levels during strong La Niña winters as compared to neutral conditions. Similar significant patterns were also noted for El Niño and La Niña fall periods. The success of the analysis demonstrates the feasibility of assessing local effects associated with large-scale climate variability. It also highlights the possibility of using ENSO forecasts to predict periods of poor coastal water quality in urban region which local agencies may use to make appropriate prepations.     

Autonomous underwater vehicle-based concurrent detection and classification of buried targets using higher order spectral analysis

This paper presents a processing concept for autonomous underwater vehicle (AUV)-based concurrent detection and classification (CDAC) of mine-like objects. In the detection phase, the AUV seeks objects of interest using a simple energy detector combined with a peak tracking mechanism. Upon detection, the processing mechanism changes to a higher order spectral (HOS) classification process. The system is demonstrated through theory, simulation and at-sea experiments to have promise in reducing the false alarm rate of mine detections. The HOS classification mechanism is also shown to have some benefit over classical spectral estimation in all cases. Components of the system concept were also demonstrated live onboard the AUV during the Generic Oceanographic Array Technology Sonar (GOATS 2002) experiment off the coast of Italy, while others are demonstrated using a comprehensive AUV sonar simulation framework.     

In situ hydrocarbon concentrations from pressurized cores in surface sediments, Northern Gulf of Mexico

Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct–Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C₁ through C₅) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg^− 1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH₄. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH₄ concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.     

Analytical intercomparison results from the 1990 Intergovernmental Oceanographic Commission open-ocean baseline survey for trace metals: Atlantic Ocean

“Dissolved” (< 0.4 μm filtered) and “total dissolvable” (unfiltered) trace element samples were collected using “clean” sampling techniques from four vertical profiles in the eastern Atlantic Ocean on the first IOC Trace Metals Baseline expedition. The analytical results obtained by 9 participating laboratories for Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb, and Se on samples from station 4 in the northeast Atlantic have been evaluated with respect to accuracy and precision (intercomparability). The data variability among the reporting laboratories was expressed as 2 × SD for a given element and depth, and was comparable to the 95% confidence interval reported for the NASS seawater reference standards (representing analytical variability only). The discrepancies between reporting laboratories appear to be due to inaccuracies in standardization (analytical calibration), blank correction, and/or extraction efficiency corrections.Several of the sampling bottles used at this station were not adequately pre-cleaned (anomalous Pb results). The sample filtration process did not appear to have been a source of contamination for either dissolved or particulate trace elements. The trace metal profiles agree in general with previously reported profiles from the Atlantic Ocean. We conclude that the sampling and analytical methods we have employed for this effort, while still in need of improvement, are sufficient for obtaining accurate concentration data on most trace metals in the major water masses of the oceans, and to enable some evaluation of the biogeochemical cycling of the metals.