Simulating the effects of geologic heterogeneity and transient boundary conditions on streambed temperatures — Implications for temperature-based water flux calculations

Analytical solutions to the one-dimensional heat transport equation for steady-state conditions can provide simple means to quantify groundwater surface water exchange. The errors in exchange flux calculations that are introduced when the underlying assumptions of homogeneous sediments and constant temperature boundary conditions are violated were systematically evaluated in a simulation study. Temperatures in heterogeneous sediments were simulated using a numerical model. Heterogeneity in the sediments was represented by discrete, binary geologic units. High contrasts between the hydraulic conductivities (K) of the geologic units were found to lead to large errors, while the influence of the structural arrangement of the units was smaller. The effects of transient temperature boundary conditions were investigated using an analytical equation. Errors introduced by transient boundary conditions were small for Darcy-velocities > 0.1 m d^− 1 in the period near maximum and minimum annual surface water temperatures. For smaller fluxes, however, errors can be large. Assuming steady-state conditions and vertical flow in homogeneous sediments is acceptable at certain times of the year and for medium to high exchange fluxes, but pronounced geologic heterogeneity can lead to large errors.     

Trace Elements in Sediments and Mussels – Spatial Distribution,Chemical Partitioning,and Risk Assessment

Sediment samples were collected from 30 different locations in Abu Qir Bay (Mediterranean Sea), East Alexandria, Egypt and analyzed for trace elements. The highest concentrations of most of the elements were observed in the nearshore stations in the vicinity of the major anthropogenic activities as industrial settlements, wastewater discharges, and agricultural drainage. In addition, mussel samples of Mactra corallina and Tapes decussata were collected corresponding to the sediment samples. Concentrations of As, Cd, Cr, Mn, and Zn in the mussel tissues were higher than concentrations in sediments, thus indicating their relatively high bioavailability. Sequential extraction procedure was performed on selected sediment samples. Significant correlations were observed between the concentrations of Cu, Mn, Pb, and Zn in the exchangeable fraction of the sediments and the corresponding tissues of M. corallina. The output of the risk assessment applied on the sediments revealed that adverse ecological effects to benthic species could occur and that a higher level of risk is expected from the exposure to Cd, Cr, Hg, and Zn. No adverse carcinogenic or non‐carcinogenic human health effects are expected from the consumption of the two mussel species from Abu Qir Bay.     

Zur derivativspektroskopischen Bestimmung der Ligninsulfonsäure in Gegenwart von Huminsäuren

A Specord M 40 device with the Date Handling 1 computer cassette was used for the derivative-spectroscopie determination of lignosulphonic acid. Because of the higher sensitivity and the better evaluable peaks, the 2nd derivation of the five possible derivations was used. The analysis method described in detail was tested with test substances on a surface water which was polluted with waste-products from the pulp industry. With the stated device parameters, the lignosulphonic acid up to 2 mg/l can be determined in the presence of humic acids and chlorolignosulphonic acids. In weakly polluted waters, as groundwaters and shore filtrates. still lignosulphonic acid concentrations of 0.1 mg/l can be detected after an adequate enrichment.     

Localizing and quantifying groundwater-surface water interactions at different scales: A tracer approach at the River Moselle,Germany

Groundwater-surface water interactions (GSI) connect rivers and streams with riparian areas and the adjacent aquifer. Although these interactions exert a substantial control of quantity and quality of both groundwater and surface water, knowledge on GSI along rivers at the regional scale, particularly for inland waterways, is still limited. We investigated GSI along the river Moselle, an important federal inland waterway in Germany, by using radon and tritium to identify gaining (water flux from the aquifer to the surface water) and losing (water flux from the surface water to the aquifer) stream conditions, respectively. Gaining stream conditions were identified by continuously measuring radon along the river during boat surveys with a high spatial resolution (every 2 km) during intermediate (October 2020) and near low flow conditions (August/September 2021). The tritium concentrations in surface water and groundwater and the resulting tritium inventories were used to characterize losing stream conditions Monthly tritium inventories from 2017 to 2022 revealed a mean loss for the whole period of 20.3 % and a mean gain of 21.8%. Both were probably triggered by a combination of losing stream conditions and flood-induced mass transfer of water from the aquifer back into the river as well as discharge fluctuations. At the investigated site Lehmen there were direct indications of an influence of surface water due to elevated tritium concentrations in the groundwater (up to 13.3 Bq L⁻¹). Using radon mass balance modelling, good agreements of simulated versus measured radon data with respect to two groundwater end-member scenarios were obtained during intermediate flow (Spearman's ρ: 0.97 and 0.99; MAE: 10.1 and 3.4 Bq L⁻¹) and near low flow (Spearman's ρ: 0.97 and 0.99; MAE: 11 and 6.5 Bq L⁻¹). Considerable groundwater inflow was limited to the meander of Detzem, where cumulated groundwater inflow of about 19 m³ s⁻¹ (9.5% of total discharge) and 4.2 m³ s⁻¹ (3.8% of total discharge) was simulated during intermediate and near low flow, respectively. However, the groundwater inflow was relatively low compared to alpine streams, for example. The study will help to better identify and quantify GSI at the regional scale and provide methodological guidance for future studies focusing on inland waterways.     

The significance of scarp retreat for cenozoic landform evolution on the Colorado Plateau,U.S.A.

Since the beginning of the Cenozoic period several hundreds of metres of the sedimentary cover have been removed from the Colorado Plateau. Palaeoclimatic considerations show that the Colorado Plateau has been dominated by dry climates throughout the Cenozoic with the possible exception of the early Palaeocene. Today in the still prevailing arid climate, which strongly accentuates differences in rock resistance, the relief shows a structurally controlled cuesta scarp topography in the slightly deformed strata of alternating resistance. In examining whether the denudational efficiency of scarp retreat was sufficient to account for the wide erosional gaps in the sedimentary cover, rates of scarp retreat were determined by using the information of dated volcanic material and by applying a new method, which calculates the amount of retreat from the width of beheaded valleys of known age. Rates of retreat range from 0·5 to 6·7 km my^?1. The results show that the rates of retreat are controlled by the thickness and resistance of the caprocks. A model of Cenozoic scarp retreat demonstrates that the rates of recession calculated for the scarps in Upper Cretaceous rocks were sufficient to bring them into their present positions from the centre of the Monument Uplift on the central Colorado Plateau. The late Eocene positions of the cliffs in the Early Tertiary formations give an indication of their maximal extent. After the Upper Cretaceous sediments had been removed from the uplifts, erosion cut through successively older rocks, and activated scarps in stratigraphically lower positions. Scarp retreat can operate simultaneously and independently at different levels, which enabled this erosional mechanism to remove great proportions of the sedimentary cover of the Colorado Plateau during the Cenozoic.     

Diatomeenstratigraphische Untersuchungen zur Trophieänderung und Industrieschlammakkumulation im Traunsee/Österreich

Three cores from Traunsee were investigated and compared with respect to diatom stratigraphy concerning dating of incursions into and rate of accumulation of industrial tailings in the profundal zone.

     

Effects of the pharmaceuticals gemfibrozil and diclofenac on the marine mussel (Mytilus spp.) and their comparison with standardized toxicity tests

Human pharmaceuticals, like the lipid lowering agent gemfibrozil and the non-steroidal anti-inflammatory drug diclofenac are causing environmental concern. In this study, the marine mussel (Mytilus spp.) was exposed by injection to environmentally relevant and elevated (1 μg/L and 1000 μg/L) concentrations of both compounds and biomarker expression was observed. Gemfibrozil exposure induced biomarkers of stress (glutathione S-transferase and metallothionein) at both concentrations 24 h and 96 h after exposure, respectively. Biomarkers of damage (lipid peroxidation (LPO) and DNA damage) were significantly affected, as well as the biomarker for reproduction, alkali-labile phosphate assay, indicating the potential oxidative stress and endocrine disrupting effect of gemfibrozil. Diclofenac significantly induced LPO after 96 h indicating tissue damage. Additionally standard toxicity tests using the marine species Vibrio fischeri, Skeletonema costatum and Tisbe battagliai showed differences in sensitivity to both drugs in the mg/L range. Results indicate a suite of tests should be used to give accurate information for regulation.     

The distribution of acetaldehyde in the lower troposphere during TROPOZ II

A series of 72 measurements of the acetaldehyde (CH₃CHO) mixing ratio were made in the lower troposphere during TROPOZ II. These measurements are the first ever made of the background level of this trace gas in the free troposphere. The data show a vertical decrease of the CH₃CHO mixing ratio with increasing altitude and indicate higher CH₃CHO concentrations in the Northern Hemisphere — in general agreement with a model-derived average CH₃CHO distribution. Deviations of the observed CH₃CHO mixing ratios from the modelled mean distribution are correlated with similar deviations in the corresponding HCHO mixing ratios.     

Formation of carbonate concretions in surface sediments of two mud mounds,offshore Costa Rica: a stable isotope study

The surface sediments of two mud mounds (“Mound 11” and “Mound 12”) offshore southwest Costa Rica contain abundant authigenic carbonate concretions dominated by high-Mg calcite (14–20 mol-% MgCO₃). Pore fluid geochemical profiles (sulfate, sulfide, methane, alkalinity, Ca and Mg) indicate recent carbonate precipitation within the zone of anaerobic oxidation of methane (AOM) at variable depths. The current location of the authigenic carbonate concretions is, however, not related to the present location of the AOM zone, suggesting mineral precipitation under past geochemical conditions as well as changes in the flow rates of upward migrating fluids. Stable oxygen and carbon isotope analysis of authigenic carbonate concretions yielded δ¹⁸O_carbonate values ranging between 34.0 and 37.7 ‰ Vienna standard mean ocean water (VSMOW) and δ¹³C_carbonate values from ?52.2 to ?14.2 ‰ Vienna Pee Dee belemnite (VPDB). Assuming that no temperature changes occurred during mineral formation, the authigenic carbonate concretions have been formed at in situ temperature of 4–5 °C. The δ¹⁸O_carbonate values suggest mineral formation from seawater-derived pore fluid (δ¹⁸O_porefluid = 0 ‰ VSMOW) for Mound 12 carbonate concretions but also the presence of an emanating diagenetic fluid (δ¹⁸O_porefluid ≈5 ‰) in Mound 11. A positive correlation between δ¹³C_carbonate and δ¹⁸O_carbonate is observed, indicating the admixing of two different sources of dissolved carbon and oxygen in the sediments of the two mounds. The carbon of these sources are (1) marine bicarbonate (δ¹³C_porefluid ≈0 ‰) and (2) bicarbonate which formed during the AOM (δ¹³C_porefluid ≈?70 ‰). Furthermore, the δ¹⁸O_porefluid composition, with values up to +4.7 ‰ Vienna standard mean ocean water (VSMOW), is interpreted to be affected by the presence of emanating, freshened and boron-enriched fluids. Earlier, it has been shown that the origin of ¹⁸O-enriched fluids are deep diagenetic processes as it was indicated by the presence of methane with thermogenic signature (δ¹³C_CH4 = ?38 ‰). A combination of present geochemical data with geophysical observations indicates that Mounds 11 and 12 represent a single fluid system interconnected by deep-seated fault(s).