基于中尺度大气模式WRF(Weather Research and Forecasting Model),首先对2007年3次船舶辐射通量观测进行模拟,以检验WRF对长波和短波辐射通量的模拟能力,结果表明使用中国近海海洋环境数值预报系统环流模式POM(Princeton Ocean Model)模拟的高时空分辨率的海洋表层温度能够显著改进短波辐射通量的模拟,而对长波辐射通量模拟的改进不明显。然后,将业务化运行的中国近海海洋环境数值预报系统后报的逐时海洋表面温度(SST)作为WRF底边界条件,对2008年15号强台风"蔷薇"(Jangmi)过程进行了数值后报试验。结果表明,与使用NCEP/NCAR的SST试验后报的台风中心位置偏差相比,使用高时空分辨率的SST能够较为显著地改善"蔷薇"的路径模拟,台风中心位置模拟偏差减少11%,尤其在台风减弱阶段,台风中心位置模拟偏差减少37%。台风强度在台风发展的不同阶段对下垫面SST的变化敏感性不同。台风路径附近的海表面温度下降会导致海洋向大气输送的热量减少从而减弱台风强度。 相似文献
Dissolution experiments of a tholeiite basalt glass carried out at different pH and T (up to 300°C) using a rotatingdisc apparatus show that, depending on pH and T, dissolution can be controlled by one of the following steps: (1) surface reaction; (2) transport of reactants in solution; and (3) mixed reaction. The activation energies of these different processes were found to be 60, 9 and 15–50 kJ mol−1, respectively. Taking account of these results, it appears likely that surface reactions are not rate limiting for the hydrolysis of most crystalline silicate minerals in hydrothermal and metamorphic processes, and that caution should be exercised when predicting rate of reactions at high temperatures solely on the basis of activation energies measured at low temperatures.
Comparison of experimental and theoretical potentiometric titrations of the basalt glass and its constituent oxides indicates that the adsorption of H+ and OH− ions at the basalt surface is metal cation specific and that the net adsorption can be predicted from the sole knowledge of the acidity constants of the network-forming constituent oxides. We found that in the acidic pH region dissolution is promoted by the adsorption of H+ on al and Fe surface sites while in the basic region, dissolution is promoted by the adsorption of OH− on Si sites. The combination of the two distinct types of surface sites, Al and Fe on the one hand, and Si on the other hand, results in a dissolution rate minimum at a pH-value between the pHzpc of the two groups of oxide components. Linear regressions with a slope n=3.8 are observed both in acid and alkaline solutions in logarithmic plots of the rate of dissolution vs. the surface charge. The value of n, which represents the number of protonation or hydroxylation steps prior to metal detachment, has been found equal to the mean valence of the network-forming metals.
Combining concepts of surface coordination chemistry with transition state theory afforded characterisation of the activated complexes involved in basalt dissolution processes. From the values obtained for the thermodynamic properties of activation for basalt dissolution it is assumed that the activated complexes formed during the H2O-promoted dissolution of the basalt glass are more tightly bonded than those formed during H+- or OH−-promoted dissolution. 相似文献