Chemical dispersant effectiveness testing: influence of droplet coalescence

Thermodynamic and kinetic investigations were performed to determine the influence of coalescence of chemically dispersed crude oil droplets in saline waters. For the range of pH (4-10) and salinity (10 per thousand, 30 per thousand, 50 per thousand ) values studied, zeta-potential values ranged from -3 to -10 mV. As the interaction potential values calculated using Derjaguin-Landau-Verway-Overbeek (DLVO) theory were negative, the electrostatic barrier did not produce significant resistance to droplet coalescence. Coalescence kinetics of premixed crude oil and chemical dispersant were determined within a range of mean shear rates (Gm = 5, 10, 15, 20 s(-1)) and salinity (10 per thousand, 30 per thousand ) values. Coalescence reaction rates were modeled using Smoluchowski reaction kinetics. Measured collision efficiency values (alpha = 0.25) suggest insignificant resistance to coalescence in shear systems. Experimentally determined dispersant efficiencies (alpha = 0.35) were 10-50% lower than that predicted using a non-interacting droplet model (alpha = 0.0). Unlike other protocols in which the crude oil and dispersant are not premixed, salinity effects were not significant in this protocol. This approach allowed the effects of dispersant-oil contact efficiency eta(contact) to be separated from those of water column transport efficiency (eta(transport)) and coalescence efficiency (eta(coalescence)).     

Characterizing aquatic sediment-oil aggregates using in situ instruments

The effects of emulsified crude oil and salinity (15, 30 per thousand ) on the steady state aggregate volume distributions and fractal dimensions were determined for a range of mean velocity gradients, (G(m) =5-50 s(-1)). Aggregation was performed in a 40-L cylindrical tank with a 4-blade paddle mixer. Three-dimensional fractal dimensions (D3) and volume distributions were determined using a procedure integrating data from an electrozone and an in situ light scattering instrument. Two-dimensional fractal dimensions (D2) and derived volume distributions were determined using a recently developed submersible flow cytometer equipped with a digital camera and image analysis software. For latex beads or emulsified crude oil systems, the above listed instruments yielded consistent size distributions and fractal dimensions (D2=1.92 +/- 0.16, D3=2.94 +/- 0.12). Mean volume aggregate diameters determined using the FlowCAM were consistently larger that those determined using the LISST-100 or Coulter Multisizer due to aggregate orientations during measurements. With increasing G(m) values, all colloidal aggregates showed increasing D3 values due to reduced aggregate length. Because of the compactness of all the aggregates (D3 >2), D2 values remained constant at 2. Neither salinity nor sediment type significantly affected D2 values calculated for sediment-crude oil aggregates. However, clay-oil aggregates showed higher D3 values than clay aggregates. This suggests that colloidal oil and mixing shear are the more dominant factors influencing aggregate morphology in nearshore waters. Overall, the data suggests that the analysis methods provide consistent size distribution results. However, because of the shear and salinity of coastal waters, resulting aggregates are too compact to estimate their D3 values using image analysis alone.     

Biomarkers for endocrine disruptors in three species of Mediterranean large pelagic fish

The hypothesis that Mediterranean top predator species, such as large pelagic fish, are potentially at risk due to endocrine disrupting chemicals (EDCs), is investigated. The potential estrogenic effects of PHAHs in three fish species of commercial interest, the top predators bluefin tuna (Thunnus thynnus thynnus), swordfish (Xiphias gladius), and Mediterranean spearfish (Tetrapturus belone), were investigated using vitellogenin (Vtg), zona radiata proteins (Zrp) and mixed function oxidases (EROD, BPMO) as diagnostic tools. High induction of Vtg and Zrp was detected by western blot and ELISA techniques in adult males of X. gladius and T. thynnus thynnus, suggesting that these species are at high toxicological risk in the Mediterranean sea. Comparison of BPMO and EROD activities in the three species indicated, both in male and female, much higher MFO activity in bluefin tuna. This data suggests high exposure of this species to lipophilic xenobiotic contaminants in the Mediterranean environment.     

Comparison of local grid refinement methods for MODFLOW

Many ground water modeling efforts use a finite-difference method to solve the ground water flow equation, and many of these models require a relatively fine-grid discretization to accurately represent the selected process in limited areas of interest. Use of a fine grid over the entire domain can be computationally prohibitive; using a variably spaced grid can lead to cells with a large aspect ratio and refinement in areas where detail is not needed. One solution is to use local-grid refinement (LGR) whereby the grid is only refined in the area of interest. This work reviews some LGR methods and identifies advantages and drawbacks in test cases using MODFLOW-2000. The first test case is two dimensional and heterogeneous; the second is three dimensional and includes interaction with a meandering river. Results include simulations using a uniform fine grid, a variably spaced grid, a traditional method of LGR without feedback, and a new shared node method with feedback. Discrepancies from the solution obtained with the uniform fine grid are investigated. For the models tested, the traditional one-way coupled approaches produced discrepancies in head up to 6.8% and discrepancies in cell-to-cell fluxes up to 7.1%, while the new method has head and cell-to-cell flux discrepancies of 0.089% and 0.14%, respectively. Additional results highlight the accuracy, flexibility, and CPU time trade-off of these methods and demonstrate how the new method can be successfully implemented to model surface water-ground water interactions.     

A universal nutrient application strategy for the bioremediation of oil-polluted beaches

Biostimulation by nutrient application is a viable technology for restoring oil-contaminated beaches. Maximizing the nutrient residence time is key for achieving a rapid cost-effective cleanup. We considered the nutrient injection strategy through a perforated pipe at the high tide line and we simulated numerically beach hydraulics, which allowed us to estimate the optimal injection flow rate of nutrient solution. Our results indicate that the optimal application is one that starts following the falling high tide and lasts for half tidal cycle. The saturated wet-front of the nutrient solution on the beach surface would move seaward with the same speed of the falling tide keeping a constant distance with the tide line. The numerical results were generalized to beaches of wide ranges of hydraulic and tidal properties using a novel dimensionless formulation for water flow and solute transport in porous media. Nomographs were presented to provide the flow rate based on four parameters: The beach slope and hydraulic conductivity, and tidal amplitude and period.     

Arsenic and trace metal contents in sediment profiles from the Admiralty Bay, King George Island, Antarctica

Admiralty Bay (Antarctica) hosts three scientific stations (Ferraz, Arctowski and Macchu Picchu), which require the use of fossil fuel as an energy source. Fossil fuels are also considered the main source of pollution in the area, representing important inputs of major pollutants (organic compounds) and trace metals and metalloids of environmental interest. Accordingly, this work presents the results of As, Cd, Cr, Cu, Ni, Pb and Zn in sediment profiles from Admiralty Bay. The sediment results from Ferraz station were slightly higher than the other sampling sites. The highest contents were observed for Cu and Zn (from 44 to 89 mg kg⁻¹). Otherwise, by using enrichment factors and geochronology analysis, the most relevant enrichment was observed for As in the samples collected close to the Ferraz station, indicating that increasing As content may be associated with the activities associated with this site.     

大气污染渠道及大气净化途径

１大气污染渠道大气污染是指一些能对地球动植物群落及人类社会的生存环境造成负面影响的气、固、液态质点及水蒸汽等在空气中的超限度聚集。主要的大气污染源是汽车及其它类型的交通工具，此外还有工农业生产排放物及人类生活垃圾等。１．１汽车排放物１９９７年全世界共生产汽车３７８０万辆，汽车拥有量超过５亿辆，烧掉大量宝贵的石油产品，造成不容忽视的环境污染。近２０年来，独联体的汽车拥有量翻了一番，１９９７年超过３１２０万辆。德国于１９９６年即已达到４９６辆／千人，美国为５５０辆／千人。如此数量庞大的汽车群不时在威…