Flory-Huggins' formulation,its validity and implications in retrieval of equilibrium temperature of binary and ternary systems at higher pressures,using liquid silicate data and 1 bar liquidus temperature

For a pure phase at equilibrium with a polycomponent melt, two sets of expressions can be derived; one expressing its activity as a function of enthalpy, entropy, heat capacity and temperature, and the other by coupling a Flory-Huggins' polymerisation model with the van Laar heat of mixing term. Interaction parameters for binary and ternary systems have been computed at 1 bar by equating these two expressions. Assuming the interaction parameter to be independent of temperature, equilibrium temperatures at higher pressures can be calculated by an iterative procedure. Such retrieval calculations were carried out in simple eutectic, volatile-free systems like CaAl₂Si₂O₈-CaMgSi₂O₆, Mg₂SiO₄-TiO₂, MgSiO₃-TiO₂, Mg₂SiO₄-CaMgSi₂O₆, NaAlSi₃O₈-SiO₂ and CaAl₂Si₂O₈-CaMgSi₂O₆-Mg₂SiO₄. The close agreement between the theoretically retrieved and the experimentally determined equilibrium temperatures testifies to the validity of the model at higher pressures. The successful application of the model to simple eutectic, binary and ternary systems involving vastly dissimilar phases without imposing added constraints implies that it can be possibly extended to hitherto unknown systems provided the thermodynamic parameters of the phases involved are known.     

Historical Auckland on foot

Abstract:  This paper discusses three walking tour guides prepared for the 12th International Conference of Historical Geographers. It argues that the guides are innovative in terms of format, content and ironic sensibility. It construes them as devices for re-imagining Auckland's urban heritage.     

Fluvial process and the establishment of bottomland trees

The effects of river regulation on bottomland tree communities in western North America have generated substantial concern because of the important habitat and aesthetic values of these communities. Consideration of such effects in water management decisions has been hampered by the apparent variability of responses of bottomland tree communities to flow alteration. When the relation between streamflow and tree establishment is placed in a geomorphic context, however, much of that variability is explained, and prediction of changes in the tree community is improved.The relation between streamflow and establishment of bottomland trees is conditioned by the dominant fluvial process or processes acting along a stream. For successful establishment, cottonwoods, poplars, and willows require bare, moist surfaces protected from disturbance. Channel narrowing, channel meandering, and flood deposition promote different spatial and temporal patterns of establishment. During channel narrowing, the site requirements are met on portions of the bed abandoned by the stream, and establishment is associated with a period of low flow lasting one to several years. During channel meandering, the requirements are met on point bars following moderate or higher peak flows. Following flood deposition, the requirements are met on flood deposits ;high above the channel bed. Flood deposition can occur along most streams, but where a channel is constrained by a narrow valley, this process may be the only mechanism that can produce a bare, moist surface high enough to be safe from future disturbance. Because of differences in local bedrock, tributary influence, or geologic history, two nearby reaches of the same stream may be dominated by different fluvial processes and have different spatial and temporal patterns of trees. We illustrate this phenomenon with examples from forests of plains cottonwood (Populus deltoides ssp. monilifera) along meandering and constrained reaches of the Missouri River in Montana.     

On the Attractive Force of an Elliptical Gaussian Ring

Solar System Research - A numerical-analytical method for analyzing the orbital evolution of a planetary satellite under the influence of a perturbing body moving in an elliptical orbit is...     

Combination Scattering by Anisotropic Langmuir Turbulence with Application to Solar Radar Experiments

We develop a theory for radar signal scattering by anisotropic Langmuir turbulence in the solar corona due to a t+l ⇄ t process. Langmuir turbulence is assumed to be generated within a cone by a narrow type III burst electron beam. Using wave-kinetic theory we obtain expressions for the frequency shift, scattering cross-section of the turbulence, coefficient of absorption (due to scattering) and optical depth. On the basis of those expressions we give some estimates for an echo spectrum. We show that the minimum radar echo frequency shift is determined by the minimal phase velocity of the Langmuir waves, the maximum shift is determined by the electron beam velocity, but in any case it can not exceed −wt/2 (decay) and wt (coalescence), where wt is the frequency of a radar signal. The angular characteristics of the scattered signal differ dramatically for the cases of coalescence and decay. The signal is scattered into a narrow cone high above the specular reflection point (wp ≪ wt), but in the vicinity of wp ∼ wt/2 the red-shifted echo is scattered isotropically, while the blue-shifted echo is scattered into a even narrower cone. We show that absorption (due to scattering) increases with increasing radar frequency. The dependence of the absorption on the local plasma frequency is strongly determined by the Langmuir turbulence spectrum. Our theory shows that the role of the nonlinear scattering process t+l ⇄ t is essential and that such process can be used for radar studies of the spectral energy density of anisotropic Langmuir turbulence.     

Micrometeorological Observations of a Microburst in Southern Finland

On the afternoon of 3 July 2004 in Hyytiälä (Juupajoki, Finland), convective cells produced a strong downburst causing forest damage. The SMEAR II field station, situated near the damage site, enabled a unique micrometeorological analysis of a microburst with differences above and inside the canopy. At the time of the event, a squall line associated with a cold front was crossing Hyytiälä with a reflectivity maximum in the middle of the squall line. A bow echo, rear-inflow notch, and probable mesovortex were observed in radar data. The bow echo moved west-north-west, and its apex travelled just north of Hyytiälä. The turbulence data were analysed at two locations above the forest canopy and at one location at sub-canopy. At 1412 EET (Eastern European Time, UTC+2), the horizontal and vertical wind speed increased and the wind veered, reflecting the arrival of a gust front. At the same time, the carbon dioxide concentration increased due to turbulent mixing, the temperature decreased due to cold air flow from aloft and aerosol particle concentration decreased due to rain scavenging. An increase in the number concentration of ultra-fine particles (< 10 nm) was detected, supporting the new particle formation either from cloud outflow or due to rain. Five minutes after the gust front (1417 EET), strong horizontal and downward vertical wind speed gusts occurred with maxima of 22 and 15 m s^?1, respectively, reflecting the microburst. The turbulence spectra before, during and after the event were consistent with traditional turbulence spectral theory.     

Active deformation in the Vrancea region,Rumania

Recent and historical seismicity as well as reliable fault plane solutions are used to study the active deformation caused by the occurrence of intermediate depth (60–170 km) earthquakes of the Vrancea region, Rumania. In this area, located in the southeastern part of the Carpathian arc, the westward subduction of the Carpathian trench has terminated, leaving continental lithosphere, at present, at the arc. The principalT axis of the intermediate depth events trends N159°E and has a plunge of 74°, which is the same as the dip of the subducted plate. TheP axis has a trend of 314° and a shallow plunge of 15°. The analysis of the moment tensor of six focal mechanisms showed that the dominant mode of deformation of the subducted lithosphere is a down-dip extension at a rate of about 2 cm/yr, based on seismicity data.     

Regional and temporal changes in bivalve diversity off the south coast of Portugal

From 2000 to 2006, a total of 75 bivalve species were identified, varying from 29 (spring 2001) to 54 species (spring 2005) per year. Seasonal tendencies in diversity varied according the year, thus the interpretation of long-term and regional scales is essential before drawing any conclusions in other studies. Richness and diversity consistently decreased with depth and increased with sediment grain size (from low in very coarse sand to high in coarse silt). Diversity decreased progressively from 3 to 16 m depth, thus the harsher shallower environments (due to waves and tidal air exposure) showed greater diversity than the most stable areas. Communities in finer sediments were more diverse than those in coarser sand. Evenness showed patterns opposite to diversity, overall.Diversity and evenness maps (produced with multivariate universal kriging), showed that most geographic areas with greater diversity were farer from river outflows and wastewater treatment plants. Two types of geographic pattern were observed: areas with persistently greater bivalve diversity through time and areas that changed locally from year to year. This spatial analysis can be used to establish priority conservation areas for management purposes, and to analyse the persistency of regional diversity patterns. The area with most habitat heterogeneity (Sotavento) corresponded to greatest diversity.There was a positive relationship between Spisula solida and Chamelea gallina landings and bivalve diversity 2 years and 1 year later, respectively. Possibly, local fisheries, by selectively withdrawing the commercial numerically dominant species from the ecosystem, increased diversity 1 to 2 years later, as the ecological niches of the dominants are quickly filled by several other species thereby creating a more even community. On regional scales, no significant impact was found on long-term bivalve diversity in local fisheries,     

Monthly Variations of Water Masses in the Yellow and East China Seas, November 6, 1998

The monthly water mass variations in the Yellow Sea and the East China Sea are investigated using over 40 years of historical temperature and salinity observations via a cluster analysis that incorporates geographical distance and depth separation in addition to the temperature and salinity. Results delineate monthly variations in the major water masses and provide some insight into formation mechanisms and intermixing. The major water masses include the Kuroshio-East China Sea water (KE), the Yellow Sea surface water (YSS) and bottom cold water (YSB), mixed water (MW), and coastal water (CW). The distribution of the KE water mass reveals the intrusion pattern into the area west of Cheju. A separate mixed water type appears between the KE water mass and the Yellow Sea water masses during winter. The formation mechanism of the YSB appears to be the surface cooling and active mixing in winter. In the East China Sea, during summer, surface water is differentiated from the subsurface water while there is no differentiation during winter. In the Yellow Sea, a three layer system exists in the summer and fall (May–November) while a two layer system exists during the rest of the year. A fresh water mass generated by Yangtze River discharge (YD) is present over the northern East China Sea and the southern Yellow Sea during summer. This revised version was published online in August 2006 with corrections to the Cover Date.