Comparative studies on compounds occluded inside asphaltenes hierarchically released by increasing amounts of H2O2/CH3COOH

Being the heaviest fraction of crude oils, asphaltenes are liable to aggregate, and other molecules in the oils can be steadily adsorbed onto, and even occluded inside the macromolecular structures of the asphaltenes. These occluded compounds inside the asphaltenes can survive over geological time in oil reservoirs owing to effective protection by the macromolecular structures of the asphaltenes. The asphaltenes of a crude oil (ZG31) from the central Tarim Basin, NW China, were hierarchically degraded by increasing the amount of H₂O₂/CH₃COOH to release the occluded compounds. Besides the common components, series of even numbered n-alk-1-enes and 3-ethylalkanes were detected among the occluded compounds. Comparison of the biomarker distributions and the compound-specific C isotopic results between the compounds from the maltenes and those from the occluded fraction, the ZG31 reservoir was suggested to have been charged multiple times, with different charges being derived from different strata of source rocks.     

金沙江地震带强震动及其与现今弱震活动关系

包括川滇菱块及马边－大关，宣威－弥勒地区在内的金沙江地震带记载（录）了川滇两省发生的绝大部分中、强以上地震，为我国西南一主要地震区。本文重点研究了该范围内强震的重复性及现今弱震密集区的强震危险性问题。金沙江地震带强震具有很高的原地重复性，７级以上强震原地重复率达６５．４％，平均复发时间１５７年；６级地震原地重复率达４１．８％，平均复发时间为２７．２年。川滇地区现今弱震活动密集区在活动期内本身发生６级以上强震的可能性很小。四川地区大多数情况下强震发生在距密集区４０－５０千米处，云南情况较复杂。但在作今后较长时间危险性分析预测时，现今弱震密集区本身仍有发生６级地震的危险，虽然发生７级以上地震可能性不大。     

华北东部地区上地幔运动与盆地形成关系的模拟研究

在综合分析华北东部深部构造、盆地构造及其动力学特征等资料的基础上,运用离心技术讨论了该区盆地形成机制与上地幔运动的关系。这种离心技术采用物质密度差代替温度差是一种新的实验方法。 实验结果表明,上地幔对流、上地幔隆起(或底辟)以及重力均衡作用产生了华北地壳的单向引张力,从而导致箕状盆地的形成。 作者认为,华北东部地区盆地形成和发展的动力源与上地幔的运动和重力作用密切相关     

Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

重庆10 kV高压输电线路雷击火灾事故分析

针对2007年7月12日重庆华浩冶炼有限公司粉末厂火灾事故,用力学性能分析和剩余磁场测试相结合的方法对该厂火灾发生处的10 kV高压输电线路进行鉴定,并结合雷电天气分析,得出该火灾事故是由雷击10 kV高压输电线路造成。该方法为在没有安装录波器和闪电计数器的情况下,判断输电线路故障是否由于雷击引起提供参考。     

Modeling of spatial distributions of farmland density and its temporal change using geographically weighted regression model

This study used spatial autoregression（SAR） model and geographically weighted regression（GWR） model to model the spatial patterns of farmland density and its temporal change in Gucheng County,Hubei Province,China in 1999 and 2009,and discussed the difference between global and local spatial autocorrelations in terms of spatial heterogeneity and non-stationarity. Results showed that strong spatial positive correlations existed in the spatial distributions of farmland density,its temporal change and the driving factors,and the coefficients of spatial autocorrelations decreased as the spatial lag distance increased. SAR models revealed the global spatial relations between dependent and independent variables,while the GWR model showed the spatially varying fitting degree and local weighting coefficients of driving factors and farmland indices（i.e.,farmland density and temporal change）. The GWR model has smooth process when constructing the farmland spatial model. The coefficients of GWR model can show the accurate influence degrees of different driving factors on the farmland at different geographical locations. The performance indices of GWR model showed that GWR model produced more accurate simulation results than other models at different times,and the improvement precision of GWR model was obvious. The global and local farmland models used in this study showed different characteristics in the spatial distributions of farmland indices at different scales,which may provide the theoretical basis for farmland protection from the influence of different driving factors.     

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中国大陆西部强震前超低频磁场时空变化特征

对2015年至2019年期间中国大陆西部的磁通门磁力仪秒采样观测资料开展了5—100 s频段的地磁垂直强度极化分析,并运用一些数学方法对分析结果进行了处理.结果显示,极化高值在经向和纬向均无明显的形态和幅值变化,且极化高值与地磁外源场扰动无关.在此基础上筛选出18次极化高值异常事件,利用插值方法得到了极化高值异常的空间...     

Exploring the database of a soil environmental survey using a geo-self-organizing map: A pilot study

A model integrating geo-information and self-organizing map (SOM) for exploring the database of soil environmental surveys was established. The dataset of 5 heavy metals (As, Cd, Cr, Hg, and Pb) was built by the regular grid sampling in Hechi, Guangxi Zhuang Autonomous Region in southern China. Auxiliary datasets were collected throughout the study area to help interpret the potential causes of pollution. The main findings are as follows: (1) Soil samples of 5 elements exhibited strong variation and high skewness. High pollution risk existed in the case study area, especially Hg and Cd. (2) As and Pb had a similar topo-logical distribution pattern, meaning they behaved similarly in the soil environment. Cr had behaviours in soil different from those of the other 4 elements. (3) From the U-matrix of SOM networks, 3 levels of SEQ were identified, and 11 high risk areas of soil heavy metal-contaminated were found throughout the study area, which were basically near rivers, factories, and ore zones. (4) The variations of contamination index (CI) followed the trend of construction land (1.353) > forestland (1.267) > cropland (1.175) > grassland (1.056), which suggest that decision makers should focus more on the problem of soil pollution surrounding industrial and mining enterprises and farmland.

     

广西北部湾城市群生态承载力研究

引入区域生态足迹模型评价广西北部湾经济圈生态发展可持续程度,定量分析研究区域土地可持续利用状况.进一步利用灰色关联度和系统聚类分析方法,对北部湾城市群整体和个体在关联度上进行纵向与横向对比分析,划分在结构和功能上相似或互补的单位.分析结果表明,北部湾2011年的人均生态足迹赤字达到0.373hm2,说明人类对自然资源的利用已经超过区域土地的承载能力.建议实行区域合作分工制,明确各自发展方向,合理调整产业结构,调整区域内土地利用结构和功能,提高北部湾区域土地可持续利用能力.