In situ neutron diffraction study of deuterated portlandite Ca(OD)2 at high pressure and temperature

The structure of deuterated portlandite, Ca(OD)₂, has been investigated using time-of-flight neutron diffraction at pressures up to ∼4.5 GPa and temperatures up to ∼823 K. Rietveld analysis of the data reveals that with increasing pressure, unit-cell parameter c decreases at a rate about 4.5 times larger than that for a, which is largely due to rapid contraction of the interlayer spacing in this pressure range. Fitting of the determined cell volumes to the third-order Birch–Murnaghan equation of state yields a bulk modulus (K ₀) of 32.2 ± 1.0 GPa and its first derivative (K ₀′) of 4.4 ± 0.6. Moreover, on compression, hydrogen-mediated interatomic interactions within the interlayer become strengthened, as reflected by decreases in interlayer D···O and D···D distances with increasing pressure. Correspondingly, D–D, the distance between the three equivalent sites over which D is disordered, increases, suggesting a pressure-induced hydrogen disorder. This behavior is similar to that reported in brucite at elevated pressure. On heating at ∼2.1 GPa, cell parameter c increases more rapidly than a, as expected. However, because of the pressure effect, the thermal expansion coefficients, particularly along c, are much smaller than those at ambient pressure. With increasing temperature, the three partially occupied D sites become further apart, and the D-mediated interactions, mainly the interlayer D···D repulsion, become weakened.     

Induction of auroral zone electric currents within the Alaska pipeline

The Alaskar pipeline is a highly conducting anomaly extending 800 miles (1300 km) from about 62° to 69° geomagnetic latitude beneath the most active regions of the ionospheric electrojet current. The spectral behavior of the magnetic field from this current was analyzed using data from standard geomagnetic observatories to establish the predictable patterns of temporal and spatial changes for field pulsation periods between 5 min and 4 hr. Such behavior is presented in a series of tables, graphs and formulae. Using 2- and 3-layer models of the conducting earth, the induced electric fields associated with the geomagnetic changes were established. From the direct relationship of the current to the geomagnetic field variation patterns one can infer counterpart temporal and spatial characteristics of the pipeline current. The relationship of the field amplitudes to geomagnetic activity indices,A _p, and the established occurrence of various levels ofA _p over several solar cycles were employed to show that about half of the time the induced currents in the pipe would be under 1 A for the maximum response oscillatory periods near 1 hr. Such currents should be of minimal consequence in corrosion effects for even a section of the pipeline unprotected by sacrificial electrodes. Of greater interest was the result that the extreme surges of current should reach over one-hundred amperes in the pipeline during high activity.     

Performance of the Nuclear Compton Telescope

On 1 June 2005, the prototype Nuclear Compton Telescope (NCT) flew on a high altitude balloon from Fort Sumner, New Mexico. NCT is a balloon-borne soft γ-ray (0.2–10 MeV) telescope for studying astrophysical sources of nuclear line emission and γ-ray polarization. Our program is designed to develop and test technologies and analysis techniques crucial for the Advanced Compton Telescope; however, our detector design and configuration is also well matched to the focal plane requirements for focusing Laue lenses. The NCT prototype utilizes two, 3D imaging germanium detectors (GeDs) in a novel, ultra-compact design optimized for nuclear line emission in the 0.5–2 MeV range. Our prototype flight provides a critical test of the novel detector technologies, analysis techniques, and background rejection procedures developed for high resolution Compton telescopes.     

Wildfire and earth surface processes

Wildfire is a landscape-scale disturbance that changes the rate and magnitude of many earth surface processes. The impacts of fire on earth surface processes can vary substantially from place to place depending on a variety of site-specific conditions, including topography, fire severity, regional climate, vegetation type, and soil type. This variation makes it critical to bring together scientists studying fire and earth surface processes from different perspectives and in different parts of the world. This special issue pulls together studies that present cutting-edge research addressing the geomorphic and hydrologic impacts of wildfire across a range of spatial and temporal scales, including advances in managing some of the negative, short-term effects of wildfire. Contributions to this collection cover the following themes: insights from field measurements, sediment and carbon redistribution, insights from process-based modeling, post-fire debris flows, and post-fire mitigation. The work presented in this special issue will help to advance the capabilities of scientists and land managers to observe, simulate, and anticipate changes to earth surface processes following fire.     

On the origin of the unusual orbit of Comet 2P/Encke

The orbit of Comet 2P/Encke is difficult to understand because it is decoupled from Jupiter—its aphelion distance is only 4.1 AU. We present a series of orbital integrations designed to determine whether the orbit of Comet 2P/Encke can simply be the result of gravitational interactions between Jupiter-family comets and the terrestrial planets. To accomplish this, we integrated the orbits of a large number of objects from the trans-neptunian region, through the realm of the giant planets, and into the inner Solar System. We find that at any one time, our model predicts that there should be roughly 12 objects in Encke-like orbits. However, it takes roughly 200 times longer to evolve onto an orbit like this than the typical cometary physical lifetime. Thus, we suggest that (i) 2P/Encke became dormant soon after it was kicked inward by Jupiter, (ii) it spent a significant amount of time inactive while rattling around the inner Solar System, and (iii) it only became active again as the ν₆ secular resonance drove down its perihelion distance.     

Controls on valley spacing in landscapes subject to rapid base‐level fall

What controls the architecture of drainage networks is a fundamental question in geomorphology. Recent work has elucidated the mechanisms of drainage network development in steadily uplifting landscapes, but the controls on drainage‐network morphology in transient landscapes are relatively unknown. In this paper we exploit natural experiments in drainage network development in incised Plio‐Quaternary alluvial fan surfaces in order to understand and quantify drainage network development in highly transient landscapes, i.e. initially unincised low‐relief surfaces that experience a pulse of rapid base‐level drop followed by relative base‐level stasis. Parallel drainage networks formed on incised alluvial‐fan surfaces tend to have a drainage spacing that is approximately proportional to the magnitude of the base‐level drop. Numerical experiments suggest that this observed relationship between the magnitude of base‐level drop and mean drainage spacing is the result of feedbacks among the depth of valley incision, mass wasting and nonlinear increases in the rate of colluvial sediment transport with slope gradient on steep valley side slopes that lead to increasingly wide valleys in cases of larger base‐level drop. We identify a threshold magnitude of base‐level drop above which side slopes lengthen sufficiently to promote increases in contributing area and fluvial incision rates that lead to branching and encourage drainage networks to transition from systems of first‐order valleys to systems of higher‐order, branching valleys. The headward growth of these branching tributaries prevents the development of adjacent, ephemeral drainages and promotes a higher mean valley spacing relative to cases in which tributaries do not form. Model results offer additional insights into the response of initially unincised landscapes to rapid base‐level drop and provide a preliminary basis for understanding how varying amounts of base‐level change influence valley network morphology. Copyright © 2015 John Wiley & Sons, Ltd.     

Rare earth element geochemistry of Late Devonian reefal carbonates, Canning Basin, Western Australia: confirmation of a seawater REE proxy in ancient limestones

Rare earth element and yttrium (REE+Y) concentrations were determined in 49 Late Devonian reefal carbonates from the Lennard Shelf, Canning Basin, Western Australia. Shale-normalized (SN) REE+Y patterns of the Late Devonian samples display features consistent with the geochemistry of well-oxygenated, shallow seawater. A variety of different ancient limestone components, including microbialites, some skeletal carbonates (stromatoporoids), and cements, record seawater-like REE+Y signatures. Contamination associated with phosphate, Fe-oxides and shale was tested quantitatively, and can be discounted as the source of the REE+Y patterns. Co-occurring carbonate components that presumably precipitated from the same seawater have different relative REE concentrations, but consistent REE+Y patterns. Clean Devonian early marine cements (n = 3) display REE+Y signatures most like that of modern open ocean seawater and the highest Y/Ho ratios (e.g., 59) and greatest light REE (LREE) depletion (average Nd_SN/Yb_SN = 0.413, SD = 0.076). However, synsedimentary cements have the lowest REE concentrations (e.g., 405 ppb). Non-contaminated Devonian microbialite samples containing a mixture of the calcimicrobe Renalcis and micritic thrombolite aggregates in early marine cement (n = 11) have the highest relative REE concentrations of tested carbonates (average total REE = 11.3 ppm). Stromatoporoid skeletons, unlike modern corals, algae and molluscs, also contain well-developed, seawater-like REE patterns. Samples from an estuarine fringing reef have very different REE+Y patterns with LREE enrichment (Nd_SN/Yb_SN > 1), possibly reflecting inclusion of estuarine colloidal material that contained preferentially scavenged LREE from a nearby riverine input source. Hence, Devonian limestones provide a proxy for marine REE geochemistry and allow the differentiation of co-occurring water masses on the ancient Lennard Shelf. Although appropriate partition coefficients for quantification of Devonian seawater REE concentrations from out data are unknown, hypothetical Devonian Canning Basin seawater REE patterns were obtained with coefficients derived from modern natural proxies and experimental values. Resulting Devonian seawater patterns are slightly enriched in LREE compared to most modern seawaters and suggest higher overall REE concentrations, but are very similar to seawaters from regions with high terrigenous inputs. Our results suggest that most limestones should record important aspects of the REE geochemistry of the waters in which they precipitated, provided they are relatively free of terrigenous contamination and major diagenetic alteration from fluids with high, non-seawater-like REE contents. Hence, we expect that many other ancient limestones will serve as seawater REE proxies, and thereby provide information on paleoceanography, paleogeography and geochemical evolution of the oceans.     

Managing human disturbance of wildlife in coastal areas

Human disturbance of wildlife is an under‐recognised and under‐regulated problem. This article discusses traditional approaches to conservation management in protecting wildlife from disturbance in the context of the New Zealand coastal environment and threatened birds. Limitations and challenges are identified and alternative actions proposed. The key problems are deficiencies in regulation of species disturbance, lack of definition of thresholds of harm that contemplate rarity and conservation status, insufficient comprehensive wildlife conservation planning and the need for innovative planning methods that address species mobility, permeable boundaries and environmental dynamism. Regulatory controls including enforcing setbacks/approach distances through either extended species protection or 'mobile habitat' protection are recommended.