Chemical behavior of the Salí River, Province of Tucumán, Argentina

Major ionic composition and other chemical parameters were determined at five sampling stations on the Salí River (Province of Tucumán, Argentina). The heavy human usage of the river causes increased levels of dissolved ions, from the dissolution of halite and gypsum, and from the weathering of basic sediments. Correlations demonstrate that sodium chloride and sulphate, and calcium carbonate are the main contributors to dissolved ions in the river. In the polluted region, south of the Celestino Gelsi dam, the main source of calcium and sulphate is the dissolution of gypsum. Large amounts of halite are also dissolved. Weathering of biotite, K-feldspar and albite are suggested by the data. Conductivity, dissolved oxygen and organic matter all indicate severe contamination by organic matter (mainly from sugar-cane processing) in the lower course. The data also demonstrate a substantial improvement in water quality before the discharge of the river at the Río Hondo dam. Data from the Colorado (a tributary of the Salí River) and Medina rivers are also analyzed and compared.     

Sustainable landscape management in Slovenia: Environmental improvements for the Velenje coal mining community 1991–2000

The Velenje area (almost 200 km² with over 31,000 inhabitants) is based on the Šalek Valley, which became a leading area of industrialisation and urbanisation after the Second World War, with consequent pollution problems. Various industrial plants polluted the river Paka while more serious hazards arose through the coal mine which is a still causing landscape subsidence and the thermal power station in the neighbourhood of Šoštanj which is a major source of sulphur dioxide and nitrogen oxide pollution. In 1987 there was an ecological protest which marked the beginning of a sustainable development strategy for the community. During the past decade programmes have dealt with the degradation of air, soil and water to achieve cleaner air, a transformation in landuse and enhancement the river's formerly weak self-purifying capabilities. This article examines the changes in the valley since the attention of the authorities was drawn to the deterioration of living conditions. Despite the pressures of transition which have seen unemployment rising to over ten percent, significant environmental improvements have been made and the area stands as a model for the rest of the country. This revised version was published online in July 2006 with corrections to the Cover Date.     

Modeling of dioctahedral 2:1 phyllosilicates by means of transferable empirical potentials

 Dioctahedral 2:1 phyllosilicates with different interlayer charge have been studied theoretically by using transferable empirical interatomic potentials. The crystal structures of pyrophyllite, muscovite, margarite, beidellite, montmorillonite, and different smectites and illites have been simulated. The interatomic potentials were able to reproduce the experimental structure of phyllosilicates with high, medium and low interlayer charge. The calculated structures are in agreement with experiment for the main structural features of the crystal lattice. The effect of the cation substitution in the octahedral and tetrahedral sheets on the structural features has been also studied. Good linear relationships have been found, and the calculated effects are consistent with experimental results. Some unknown structural features of the crystal structures of clays are predicted in this work. Received: 8 March 2000 / Accepted: 19 September 2000     

Application of the photoacoustic method for characterization of natural galena (PbS)

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.     

Finding regions of influence on SO2 and SO= 4 daily concentration measurements at four sites in Spain

Contamination by the pollutants SO₂ and SO⁼₄ was analyzed for the 1989–1992 period at four regional stations in Spain under the auspices of the EMEP-BAPMON program. The evolution of the time series of the daily pollution has also been assessed, and high mean concentrations at La Cartuja and Logroño observed, with values of 3.8 and 4.5 g m⁻³ for SO₂, respectively. Maximum annual concentrations were recorded in 1989, when SO₂ reached values of 6.24, 5.39, 5.71, and 9.30 g m⁻³ for the stations of La Cartuja, San Pablo de los Montes, Roquetas, and Logroño, respectively. This work attempts to establish a relationship between the concentrations of the pollutants - both SO₂ gas and SO⁼₄ aerosol - and the zones of emission or persistence of these long-range transported pollutants. In this way, those regions showing a greater impact on the air quality in each season have been determined. To achieve this, the trajectories of the air masses carrying away the pollution to each of the receiving stations were considered and followed by a sectorial analysis. Nonparametric statistical methods were implemented to contrast the chemical homogeneity among the different sectors. The criterion that several homogeneous sectors form a chemically homogeneous region was used. To improve this sectorial analysis, we have proposed a new technique based on the Potential-Source-Contribution Function (PSCF). Starting out from a set of specified regions, considered to be chemically homogeneous domains, it is possible to determine the likelihood that an air mass with particular characteristics (e.g., that a value of the daily concentration higher than the mean recorded at the station has been obtained) will arrive at a given station after having crossed one of the previously defined regions. Using this technique, it is possible to determine the source regions through which the air masses circulate and bring high pollution concentrations to the studied stations. Thanks to the PSCF, these statistical methods offer, through a sectorial analysis, the possibility to pass from a qualitative to a more quantitative view.     

Application of transilient turbulent theory to study interactions between the atmospheric boundary layer and forest canopies

The new Forest-Land-Atmosphere ModEl called FLAME is presented. The first-order, nonlocal turbulence closure called transilient turbulence theory (Stull, 1993) is applied to study the interactions between a forested land-surface and the atmospheric boundary layer (ABL). The transilient scheme is used for unequal vertical grid spacing and includes the effects of drag, wake turbulence, and interference to vertical mixing by plant elements. Radiation transfer within the vegetation and the equations for the energy balance at the leaf surface have been taken from Norman (1979). Among others, the model predicts profiles of air temperature, humidity and wind velocity within the ABL, sensible and latent heat fluxes from the soil and the vegetation, the stomata and aerodynamic resistances, as well as profiles of temperature and water content in the soil. Preliminary studies carried out for a cloud free day and idealized initial conditions are presented. The canopy height is 30 m within a vertical domain of 3 km. The model is able to capture some of the effects usually observed within and above forested areas, including the relative wind speed maximum in the trunk space and the counter gradient-fluxes in the lower part of the plant stand. Of special interest is the determination of the location and magnitude of the turbulent mixing between model layers, which permits one to identify the effects of large eddies transporting momentum and scalar quantities into the canopy. A comparison between model simulations and field measurements will be presented in a future paper.     

Surface NO and NO2 mixing ratios measured between 30° N and 30° S in the Atlantic region

Surface NO and NO₂ mixing ratios were measured aboard the research vessel Polarstern during the mission ANT VII/1 from 24 September to 5 October 1988. The measurements were taken along the meridian at 30° W in the Atlantic region covering latitudes between 30° N and 30° S. The average mixing ratios were about 12 pptv NO/30 pptv NO₂ in the Northern Hemisphere and about 7 pptv NO/22 pptv NO₂ in the Southern. Elevated mixing ratios of 20 pptv NO/70 pptv NO₂ were found at 12° N (probably due to air masses originating from the surface of West Africa) and in the region of the ITCZ between 8° N and 5° N. Because of probable contamination by the ship, the measured mixing ratios mostly represent upper limits.     

The mesometeorological temperature field in a mediterrannean-alpine region

Summary The structure of the surface-air temperature field in meso-alpha and meso-beta scale is studied for the purpose of regionalisation and for the optimum interpolation meso-analysis in Slovenia. The possibilities of subregionalisation, of the split into the horizontal and the vertical part of autocorrelation function and of separation according to the general weather type have been tested. It was found that the influence of weather type could not be introduced without the simultaneous introduction of first-guess fields for each weather type. The relative importance of first-guess field versus the importance of the type of autocorrelation function is estimated by several tests of the optimum interpolation meso analysis.With 6 Figures