Organic pollutants (PAHs, PCBs) in sediments from the Mar Piccolo in Taranto (Ionian Sea, Southern Italy)

Polychlorinated biphenyls (PCBs) and 17 parent polycyclic aromatic hydrocarbons (PAHs) were determined in surface sediments from nine stations in the Mar Piccolo of Taranto (Ionian Sea, Southern Italy). Total PAH concentrations ranged from 380 to 12,750 microg/kg d.w., while total PCB levels ranged from 2 to 1684 microg/kg d.w.; this values were higher than those found in others marine coastal areas of the Mediterranean Sea. For PAHs, low molecular weight/high molecular weight, phenanthrene/anthracene and fluoranthene/pyrene ratio were used for discriminating between pyrolitic and petroleum origin. Results showed that PAHs were mainly of pyrolitic origin. PCB and PAH levels in sediments were compared with Sediments Quality Guidelines (ERM-ERL, TEL-PEL indexes) for evaluation probable toxic effects on marine organism. Finally, ERM and PEL quotients were used to evaluate the degree to which chemicals exceed guidelines. Results suggest an ecotoxicological risk for benthic organisms mainly in the first inlet, where high concentrations of PCBs were found in sediments influenced by harbour activities.     

Extraordinary blowing snow transport events in East Antarctica

In the convergence slope/coastal areas of Antarctica, a large fraction of snow is continuously eroded and exported by wind to the atmosphere and into the ocean. Snow transport observations from instruments and satellite images were acquired at the wind convergence zone of Terra Nova Bay (East Antarctica) throughout 2006 and 2007. Snow transport features are well-distinguished in satellite images and can extend vertically up to 200 m as first-order quantitatively estimated by driftometer sensor FlowCapt?. Maximum snow transportation occurs in the fall and winter seasons. Snow transportation (drift/blowing) was recorded for ~80% of the time, and 20% of time recorded, the flux is >10^?2 kg m^?2 s^?1 with particle density increasing with height. Cumulative snow transportation is ~4 orders of magnitude higher than snow precipitation at the site. An increase in wind speed and transportation (~30%) was observed in 2007, which is in agreement with a reduction in observed snow accumulation. Extensive presence of ablation surface (blue ice and wind crust) upwind and downwind of the measurement site suggest that the combine processes of blowing snow sublimation and snow transport remove up to 50% of the precipitation in the coastal and slope convergence area. These phenomena represent a major negative effect on the snow accumulation, and they are not sufficiently taken into account in studies of surface mass balance. The observed wind-driven ablation explains the inconsistency between atmospheric model precipitation and measured snow accumulation value.     

Two-component galaxy models: the effect of density profile at large radii on the phase-space consistency

It is well known that the density and anisotropy profile in the inner regions of a stellar system with positive phase-space distribution function (DF) are not fully independent. Here, we study the interplay between density profile and orbital anisotropy at large radii in physically admissible (consistent) stellar systems. The analysis is carried out by using two-component  ( n - γ, γ₁)  spherical self-consistent galaxy models, in which one density distribution follows a generalized γ profile with external logarithmic slope n , and the other a standard  γ₁  profile (with external slope 4). The two density components have different 'core' radii, the orbital anisotropy is controlled with the Osipkov–Merritt recipe, and for simplicity we assume that the mass of the  γ₁  component dominates the total potential everywhere. The necessary and sufficient conditions for phase-space consistency are determined analytically, also in the presence of a dominant massive central black hole, and the analytical phase-space DF of (   n - γ  ,1) models, and of   n - γ  models with a central black hole, is derived for  γ= 0, 1, 2  . It is found that the density slope in the external regions of a stellar system can play an important role in determining the amount of admissible anisotropy: in particular, for fixed density slopes in the central regions, systems with a steeper external density profile can support more radial anisotropy than externally flatter models. This is quantified by an inequality formally identical to the 'cusp slope-central anisotropy' theorem by An & Evans, relating at all radii (and not just at the centre) the density logarithmic slope and the anisotropy indicator in all Osipkov–Merritt systems.     

Recent geological and hydrological activity on Mars: The Tharsis/Elysium corridor

The paradigm of an ancient warm, wet, and dynamically active Mars, which transitioned into a cold, dry, and internally dead planet, has persisted up until recently despite published Viking-based geologic maps that indicate geologic and hydrologic activity extending into the Late Amazonian epoch. This paradigm is shifting to a water-enriched planet, which may still exhibit internal activity, based on a collection of geologic, hydrologic, topographic, chemical, and elemental evidences obtained by the Viking, Mars Global Surveyor (MGS), Mars Odyssey (MO), Mars Exploration Rovers (MER), and Mars Express (MEx) missions. The evidence includes: (1) stratigraphically young rock materials such as pristine lava flows with few, if any, superposed impact craters; (2) tectonic features that cut stratigraphically young materials; (3) features with possible aqueous origin such as structurally controlled channels that dissect stratigraphically young materials and anastomosing-patterned slope streaks on hillslopes; (4) spatially varying elemental abundances for such elements as hydrogen (H) and chlorine (Cl) recorded in rock materials up to 0.33 m depth; and (5) regions of elevated atmospheric methane. This evidence is pronounced in parts of Tharsis, Elysium, and the region that straddles the two volcanic provinces, collectively referred to here as the Tharsis/Elysium corridor. Based in part on field investigations of Solfatara Crater, Italy, recommended as a suitable terrestrial analog, the Tharsis/Elysium corridor should be considered a prime target for Mars Reconnaissance Orbiter (MRO) investigations and future science-driven exploration to investigate whether Mars is internally and hydrologically active at the present time, and whether the persistence of this activity has resulted in biologic activity.     

Correlating Alpine glaciation with Adriatic sea‐level changes through lake and alluvial stratigraphy

We compare lake and alluvial stratigraphy along a frame connecting the southern Alpine foothills and the Adriatic Sea, with the aim of matching the effects of Alpine glaciation and sea‐level changes on sedimentation during the last glacial cycle. The palynostratigraphy of Lake Fimon provided proxies for regional vegetation and climate change and was coupled with sediment petrography, loss on ignition and magnetic susceptibility, disentangling alluvial phases from fluvioglacial activity related to culminations of the southeastern Alpine glaciers. The Fimon area was not reached by alluvial fans during the penultimate glacial maximum, nor by the sea transgression during the last interglacial, but a closed lake soon developed at the Eemian onset due to enhanced rainfall. Sea‐level fall at glacial inception triggered the entrenchment of the drainage network in the plain reaching the outer Fimon Basin. Slow aggradation, but no sign of fluvioglacial activity, lasted to 38.2 ± 1.45 cal. ka BP, when a major forest withdrawal took place, coeval to the spread of alluvial fans. By 27.5 ± 0.5 cal. ka BP the Fimon Basin was dammed by the Brenta outwash system. The main step of of forest recovery commenced at around (15.8) cal. ka BP, when apex trenching of the outwash fans was triggered by the glacier's decay. Copyright © 2011 John Wiley & Sons, Ltd.     

Assessment of the topsoil heavy metals pollution in the Sarno River basin,south Italy

The Sarno River basin area is one of the most polluted in Europe and it is due to the waste products of the tomato industry, the leather tanneries and the pharmaceutical industry. This area also has been densely populated and urbanized since the Middle Bronze Age, as testified by the presence of numerous archeological sites, including the ancient Pompeii town, and environmental degradation that characterizes the area is absolutely unacceptable. This paper represents a detailed study to assess the potentially harmful element content of topsoils. In total, 283 soil samples were collected and analyzed, after an aqua regia extraction, by a combination of inductively coupled plasma atomic emission and inductively coupled plasma mass spectrometry for 53 elements. Univariate and multivariate analyses were carried out to show the single-element geochemical distribution and the distribution of factor scores of the elemental associations resulting from R-mode factor analysis. Maps showing elements and the association factor score distributions have been obtained using GeoDAS and ArcGIS software. The assessment of the soil contamination was also carried out using the contamination factor and degree of contamination. The results obtained indicate that soil pollution has different anthropogenic sources. Specifically, Cr pollution derives from tanneries discharging wastewaters in the main water bodies of the basin while Cu contamination seems to depend on widespread agricultural practices. Tin, Pb, Hg, Zn, Cd, Sb anomalies are found mainly in urban and industrial areas, sometimes close to roads with high traffic levels while there is a substantial coincidence with background values for other elements (Co, Ni, Se, Tl and V).     

The Cimmerian geopuzzle: new data from South Pamir

Based on its Permian‐Triassic stratigraphic and biotic evolution, we correlate the SE Pamir to the Karakoram terrane, and we consider them equivalent, along with the Central Pamir, to the Qiantang Terrane of Tibet, all of Palaeozoic Gondwanan ancestry. We prove the occurrence of a marked Cimmerian unconformity, documented by lowermost Jurassic deposits suturing intensively faulted and folded Permian and Triassic units, which suggests that the South Pamir collided around the T‐J boundary with the Central Pamir along the Rushan‐Pshart suture. Collision of the Karakoram to the South Pamir happened slightly later along the Wakhan‐Tirich Boundary Zone. Progressive time shifting of deformation can be related to the complex setting of the Cimmerian belt, which was subdivided into minor blocks by incipient oceanic basins, providing strong crustal mobility.