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81.
Luca Bracchini Antonio Tognazzi Arduino Massimo Dattilo Franco Decembrini Claudio Rossi Steven Arthur Loiselle 《Aquatic Sciences - Research Across Boundaries》2010,72(4):485-498
In the past two decades, optical properties of chromophoric dissolved organic matter (CDOM) in marine environments have been
extensively studied. Many of these studies report CDOM properties for the offshore environment where this complex mixture
of optically active compounds is strongly diluted. Nevertheless, autochthonous and allochthonous sources have been identified
and sinks related to photodegradation and bacterial activity have been demonstrated. The calculation of the spectral slope
of the CDOM absorption curve has been proven to be useful and is often reported. However, a rigorous uncertainty analysis
of the slope calculation is rarely reported. In this paper, we propose a method to evaluate the uncertainty of CDOM spectral
slope calculated between 270 and 400 nm, using both naturally sampled and artificial solutions. We use these results to study
the ultra-oligotrophic waters of the Mediterranean Sea (central eastern basin), where little is known about CDOM spatial distribution.
We show that dilutions of both artificial and natural samples produce a Gaussian distribution of spectral slopes, indicating
that consistent values may be determined, with a typical uncertainty of ±0.0004 nm−1 when absorption at 300 nm was greater then 0.1 m−1 (0.1 m pathlength). Comparing the distribution of spectral slopes from central eastern basin samples to a Gaussian distribution,
we show differences between measurements that were significantly different. These values allow us to distinguish possible
sources (algal derived CDOM), sinks (e.g. photo-bleaching) at different depths. We propose a subdivision of CDOM compounds
into refractory and semilabile/refractory pools and evaluate the CDOM spectral slope of algal derived CDOM released at or
near deep chlorophyll maximum. 相似文献
82.
Rainfall-induced shallow landslides: a model for the triggering mechanism of some case studies in Northern Italy 总被引:5,自引:1,他引:4
The article relates the main findings of a recent investigation aimed at modeling the triggering of shallow landslides. A
simplified model for assessing the safety factor of potentially unstable slopes, directly related with rainfall trends, was
developed. Based on the geometric characteristics of the slope, the geotechnical properties, and strength parameters of the
soil, the model makes it possible to define a safety factor of a slope as a function of time. The model is based on the limit
equilibrium method and takes into account the seepage of underground water. The safety factor is, in turn, related to the
seasonal rainfall. The model was applied on a local scale to some historical cases which had occurred recently in Northern
Italy. The paper shows how the results of the application of the model on a local scale achieve a good agreement between the
instability condition and the real date of each considered event. 相似文献
83.
Francesco Di Benedetto Daniele Borrini Andrea Caneschi Gabriele Fornaciai Massimo Innocenti Alessandro Lavacchi Carlo Andrea Massa Giordano Montegrossi Werner Oberhauser Luca A. Pardi Maurizio Romanelli 《Physics and Chemistry of Minerals》2011,38(6):483-490
An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu3SnS4, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu3SnS4 crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)2Cu(II)SnS4 and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites. 相似文献
84.
The 1997 Umbria-Marche (Italy) earthquake sequence: analysis of the data recorded by the local and temporary networks 总被引:1,自引:0,他引:1
M. Cattaneo P. Augliera G. De Luca A. Gorini A. Govoni S. Marcucci A. Michelini G. Monachesi D. Spallarossa L. Trojani Xgums 《Journal of Seismology》2000,4(4):401-414
We present some preliminary results obtained from thejoined analysis of the data collected by the permanentand the temporary networks operating in the area ofthe earthquake sequence that followed (andanticipated) the 26 September, Central Italy, mainshocks. In particular, these earthquake data haveallowed us to determine a well constrainedwave-velocity model (both P and S) with stationcorrections which demonstrated to produce robusthypocentral locations. These velocity modelswith station corrections have been used forre-locating the whole September 1997–July 1998subset of data of the permanent network, and theprevious background seismicity, starting from May1996. The focal mechanisms of the largest events werealso obtained from an analysis of the first-motionpolarities.Our results indicate that 1) the seismic activityaligns on a SE-NW trend for a total length of about50 km of extension; 2) the focal depth of theseevents is restricted to the range 0–9 km; 3) mostevents can be related to sub-parallel SW dipping faultplanes; 4) focal mechanisms of the largest shocks(ML > 4) show a coherent behaviour, withnormal fault solution on SSE-NNW striking, SW dippingplanes; 5) the space-time evolution of the activitydisplays a discontinuous mode of energy release, withdifferent episodes of activation and an apparentclustering of aftershocks at the edges of the areaswhich presumably ruptured in the main shocks. 相似文献
85.
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87.
Francesca Garfagnoli Gianluca Martelloni Andrea Ciampalini Luca Innocenti Sandro Moretti 《Earth Science Informatics》2013,6(4):227-240
A new graphical user interface (GUI) for pre-processing reflectance spectra, built using MATLAB and expressly designed for the ASD FieldSpec® spectroradiometer, was developed to solve problems that generally affect experimental ASD data. The GUI is characterised by an easily readable, graphic visualisation of spectra, from which the absorption band depth (ABD) can be obtained for a selected wavelength. The output format of the ASD data is a binary file with an .asd extension. The binary file, that provides a single spectrum, can be processed using a software functionality, by means of a GUI, that allows to select one or more binary files to produce a spectral library in a unique .txt file. The spectral reflectance is re-calibrated with the “convex-hull” methodology to eliminate the convex shape, which is typical of reflectance spectra. Different examples of the use of the new GUI are provided. 相似文献
88.
Garnet and spinel in fertile and depleted mantle: insights from thermodynamic modelling 总被引:1,自引:1,他引:1
Luca Ziberna Stephan Klemme Paolo Nimis 《Contributions to Mineralogy and Petrology》2013,166(2):411-421
We performed thermodynamic calculations based on model and natural peridotitic compositions at pressure and temperature conditions relevant to the Earth’s upper mantle, using well-established free energy minimization techniques. The model is consistent with the available experimental data in Cr-bearing peridotitic systems and can therefore be used to predict phase relations and mineral compositions in a wide range of realistic mantle compositions. The generated phase diagrams for six different bulk compositions, representative of fertile, depleted and ultra-depleted peridotitic mantle, shown that the garnet + spinel stability field is always broad at low temperatures and progressively narrows with increasing temperatures. In lithospheric sections with hot geotherms (ca. 60 mW/m2), garnet coexists with spinel across an interval of 10–15 km, at ca. 50–70 km depths. In colder, cratonic, lithospheric sections (e.g. along a 40 mW/m2 geotherm), the width of the garnet–spinel transition strongly depends on bulk composition: In fertile mantle, spinel can coexist with garnet to about 120 km depth, while in an ultra-depleted harzburgitic mantle, it can be stable to over 180 km depth. The formation of chromian spinel inclusions in diamonds is restricted to pressures between 4.0 and 6.0 GPa. The modes of spinel decrease rapidly to less than 1 vol % when it coexists with garnet; hence, spinel grains can be easily overlooked during the petrographical characterization of small mantle xenoliths. The very Cr-rich nature of many spinels from xenoliths and diamonds from cratonic settings may be simply a consequence of their low modes in high-pressure assemblages; thus, their composition does not necessarily imply an extremely refractory composition of the source rock. The model also shows that large Ca and Cr variations in lherzolitic garnets in equilibrium with spinel can be explained by variations of pressure and temperature along a continental geotherm and do not necessarily imply variations of bulk composition. The slope of the Cr# [i.e. Cr/(Cr + Al)mol] isopleths in garnet in equilibrium with spinel changes significantly at high temperatures, posing serious limitations to the applicability of empirical geobarometric methods calibrated on cratonic mantle xenoliths in hotter, off-craton, lithospheric mantle sections. 相似文献
89.
Luca Fabris Iain Archibald Malcolm Willem Bastiaan Buddendorf Chris Soulsby 《水文研究》2018,32(6):776-791
The importance of riparian tree cover in reducing energy inputs to streams is increasingly recognized in schemes to mitigate climate change effects and protect freshwater ecosystems. Assessing different riparian management strategies requires catchment‐scale understanding of how different planting scenarios would affect the stream energy balance, coupled with a quantitative assessment of spatial patterns of streamflow generation. Here, we use the physically based MIKE SHE model to integrate simulations of catchment‐scale run‐off generation and in‐stream hydraulics with a heat transfer model. This was calibrated to model the spatio‐temporal distribution of hourly stream water temperature during warm low flow periods in a Scottish salmon stream. The model was explored as a “proof of concept” for a tool to investigate the effects of riparian management on high stream water temperatures that could affect juvenile Atlantic salmon. Uncertainty was incorporated into the assessment using the generalized likelihood uncertainty estimation approach. Results showed that by decreasing both the warming (daylight hours) and the cooling (night‐time hours) rates, forest cover leads to a reduction of the temperature range (with a delay of the time to peak by up to 2 hr) and can therefore be effectively used to moderate projected climate change effects. The modelling presented here facilitated the quantification of potential mitigating effects of alternative riparian management strategies and provided a valuable tool that has potential to be utilized as an evidence base for catchment management guidance. 相似文献
90.