Bulk organic δ13C and C/N ratios as palaeosalinity indicators within a Scottish isolation basin

Microfossils in isolation basin sediments are frequently used to reconstruct sea‐level change, but preservation problems and non‐analogue situations can limit their usefulness. Here we investigate the potential of stable carbon isotopes (δ¹³C) and C/N ratios from bulk organic matter, as an alternative proxy of salinity within isolation basin sediments from a basin in northwest Scotland. Within the Holocene sediment δ¹³C and C/N are determined largely by the mean weighted values of the predominant source of the organic material. Analysis of modern materials and comparison with the diatom record shows that the marine parts of the sequence are dominated by high δ¹³C and variable C/N. In the fresh water sequences the organic material is a mixture of both freshwater aquatic and terrestrial plant input that have relatively low δ¹³C and high C/N. The application of δ¹³C and C/N ratios in the studied basin in general follow the environmental change recorded by the diatoms and shows the potential of bulk organic matter in the investigation of salinity change in isolation basins. Copyright © 2005 John Wiley & Sons, Ltd.     

Jets in the Fanaroff–Riley class I radio galaxies PKS B1234−723, MRC 1452−517 and PKS B2148−555

We present radio observations made with the Australia Telescope Compact Array to study the jets and lobes of three Fanaroff–Riley class I (FR I) radio galaxies: PKS B1234−723, 1452−517 and B2148−555. The total intensity and polarization radio images of the FR I jets are used to determine jet brightness and width variations, magnetic field structure and fractional polarization. The equipartition pressure is determined as a function of distance from the galaxies to probe the intergalactic medium.     

Transboundary impacts on regional ground water modeling in Texas

Recent legislation required regional grassroots water resources planning across the entire state of Texas. The Texas Water Development Board (TWDB), the state's primary water resource planning agency, divided the state into 16 planning regions. Each planning group developed plans to manage both ground water and surface water sources and to meet future demands of various combinations of domestic, agricultural, municipal, and industrial water consumers. This presentation describes the challenges in developing a ground water model for the Llano Estacado Regional Water Planning Group (LERWPG), whose region includes 21 counties in the Southern High Plains of Texas. While surface water is supplied to several cities in this region, the vast majority of the regional water use comes from the High Plains aquifer system, often locally referred to as the Ogallala Aquifer. Over 95% of the ground water demand is for irrigated agriculture. The LERWPG had to predict the impact of future TWDB-projected water demands, as provided by the TWDB, on the aquifer for the period 2000 to 2050. If detrimental impacts were noted, alternative management strategies must be proposed. While much effort was spent on evaluating the current status of the ground water reserves, an appropriate numerical model of the aquifer system was necessary to demonstrate future impacts of the predicted withdrawals as well as the effects of the alternative strategies. The modeling effort was completed in the summer of 2000. This presentation concentrates on the political, scientific, and nontechnical issues in this planning process that complicated the modeling effort. Uncertainties in data, most significantly in distribution and intensity of recharge and withdrawals, significantly impacted the calibration and predictive modeling efforts. Four predictive scenarios, including baseline projections, recurrence of the drought of record, precipitation enhancement, and reduced irrigation demand, were simulated to identify counties at risk of low final ground water storage volume or low levels of satisfied demand by 2050.     

Mars: Components of infrared spectra and the composition of the dust cloud

Infrared spectra of Mars are made up of three separate components, each of which may dominate the spectrum under different Martian meteorological and observational conditions. By means of laboratory examples we show that both the shape and spectral contrast of the spectral curves change dramatically, depending on which component is dominant. Each experimental condition has been experienced during either the Mariner 69 or 71 observations. Comparing the preliminary Mariner 71 radiance data with laboratory transmission spectra, we suggest that the clay mineral montmorillonite could be the major component of the Martian dust cloud.     

Iron(III) accumulations in inland saline waterways,Hunter Valley,Australia: Mineralogy,micromorphology and pore-water geochemistry

Discharge of Fe(II)-rich groundwaters into surface-waters results in the accumulation of Fe(III)-minerals in salinized sand-bed waterways of the Hunter Valley, Australia. The objective of this study was to characterise the mineralogy, micromorphology and pore-water geochemistry of these Fe(III) accumulations. Pore-waters had a circumneutral pH (6.2–7.2), were sub-oxic to oxic (Eh 59–453 mV), and had dissolved Fe(II) concentrations up to 81.6 mg L⁻¹. X-ray diffraction (XRD) on natural and acid-ammonium-oxalate (AAO) extracted samples indicated a dominance of 2-line ferrihydrite in most samples, with lesser amounts of goethite, lepidocrocite, quartz, and alumino-silicate clays. The majority of Fe in the samples was bound in the AAO extractable fraction (Fe^Ox) relative to the Na-dithionite extractable fraction (Fe^Di), with generally high Fe^Ox:Fe^Di ratios (0.52–0.92). The presence of nano-crystalline 2-line ferrihydrite (Fe₅HO₃·4H₂O) with lesser amounts of goethite (α-FeOOH) was confirmed by scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED). In addition, it was found that lepidocrocite (γ-FeOOH), which occurred as nanoparticles as little as ∼5 lattice spacings thick perpendicular to the (0 2 0) lattice plane, was also present in the studied Fe(III) deposits. Overall, the results highlight the complex variability in the crystallinity and particle-size of Fe(III)-minerals which form via oxidation of Fe(II)-rich groundwaters in sand-bed streams. This variability may be attributed to: (1) divergent precipitation conditions influencing the Fe(II) oxidation rate and the associated supply and hydrolysis of the Fe(III) ion, (2) the effect of interfering compounds, and (3) the influence of bacteria, especially Leptothrix ochracea.     

An introspective glance into damage assessment: challenges and lessons learned from the Paso Robles (San Simeon) earthquake

This paper underscores the importance of damage assessment and recognizes the direct effect it has on post-disaster response and recovery operations. The paper first explores the literature on this subject, including the history, types, methods, and problems relating to damage assessment. After discussing the employed research methodology, the paper uses the Paso Robles (San Simeon, California) earthquake as a case study to illustrate the challenges and successes with regard to damage assessment. Logistics, politics, information management, coordination, preparedness, and other topics are discussed in this section. The paper concludes with lessons and opportunities for research and its application.     

Characterisation of organic matter and microbial communities in contrasting arsenic-rich Holocene and arsenic-poor Pleistocene aquifers,Red River Delta,Vietnam

High concentrations of geogenic As in the groundwaters of south and SE Asia, which are used as drinking waters, are causing severe health impacts to the exposed human populations. It is widely accepted that As mobilisation from sediments into these shallow reducing groundwaters requires active metal-reducing microbes and electron donors such as organic matter (OM). Although OM in such Holocene aquifers has been characterised, there is a dearth of data on Pleistocene aquifers from the same areas. Reported here are preliminary studies of OM and microbial communities present in two aquifers, one of Pleistocene and one of Holocene age, with contrasting concentrations of As (viz. Pleistocene: low As <10 μg/L; Holocene: high As up to 600 μg/L) from Van Phuc village in the Red River Delta, Vietnam. Results revealed OM inputs from multiple sources, including potential contributions from naturally occurring petroleum seeping into the shallow aquifer sediments from deeper thermally mature source rocks. Although concentrations vary, no noticeable systematic differences in biomarker distribution patterns within the OM were observed between the two sites. Microbial analyses did not show a presence of microbial communities previously associated with As mobilisation. All clone libraries were dominated by α-, β-, and γ-Proteobacteria not known to be able to reduce Fe(III) or sorbed As(V). Furthermore, representatives of the Fe(III)-reducing genus Geobacter could only be detected at very low abundance by PCR, using highly selective 16S rRNA gene primers, supporting the hypothesis that metal reduction is not a dominant in situ process in these sediments. No correlation between As concentration in groundwater and OM composition nor microbial community in the host sediments was found. This suggests that either (i) As is not being significantly mobilised in situ in these sediments, instead As appears to be mobilised elsewhere and transported by groundwater flow to the sites or (ii) sorption/desorption processes, as implicated by geochemical data from the cores, play a critical role in controlling As concentrations at these sites.     

Volatile loss from melt inclusions in pyroclasts of differing sizes

We have investigated the loss of H₂O from olivine-hosted melt inclusions (MIs) by designing an experiment using tephra samples that cooled at different rates owing to their different sizes: ash, lapilli, and bomb samples that were deposited on the same day (10/17/74) of the sub-Plinian eruption of Volcán de Fuego in Guatemala. Ion microprobe, laser ablation-ICPMS, and electron probe analyses show that MIs from ash and lapilli record the highest H₂O contents, up to 4.4 wt%. On the other hand, MIs from bombs indicate up to 30 % lower H₂O contents (loss of ~1 wt% H₂O) and 10 % post-entrapment crystallization of olivine. This evidence is consistent with the longer cooling time available for a bomb-sized clast, up to 10 min for a 3–4-cm radius bomb, assuming conductive cooling and the fastest H diffusivities measured in olivine (D~10^?9 to 10^?10 m²/s). On the other hand, several lines of evidence point to some water loss prior to eruption, during magma ascent and degassing in the conduit. Thus, results point to both slower post-eruptive cooling and slower magma ascent affecting MIs from bombs, leading to H₂O loss over the timescale of minutes to hours. The important implication of this study is that a significant portion of the published data on H₂O concentrations in olivine-hosted MIs may reflect unrecognized H₂O loss via diffusion. This work highlights the importance of reporting clast and MI sizes in order to assess diffusive effects and the potential benefit of using water loss as a chronometer of magma ascent.