Mineralogical control of rare earth elements in acid sulfate soils

Major, trace and rare earth element concentrations were measured in porewater, surface water and sediments at an acid sulfate soil site. The concentrations of La and Ce in porewater are up to 1-3 ppm. There is a strong correlation between REE concentration and acidity, except that the maximum concentrations were consistently found below the horizon of maximum acidity, associated with an increase in pH (to ca. 4) and change in mineralogy from jarosite-dominated to goethite-dominated mottles. Jarosite replacement by goethite is as expected with the rise in pH, which in turn is due to the occurrence of a fossil shell bed just below. The rare earth element patterns in the porewaters are enriched in the MREE with respect to Post-Archaean Australian Shale (PAAS). Measurements and calculations show that this is in accord with experiments on low-degree partial dissolution of jarosite, even when the jarosite itself is highly enriched in LREE. There is a clear fractionation in the patterns between the clay-rich soil matrix, which is slightly depleted in the LREE when normalized to PAAS (La/Yb_PAAS ∼0.5), and the secondary mineral phase jarosite, which is enriched in the LREE (La/Yb_PAAS = 15-50). The REE pattern in the porewater changes with the transition from jarosite- to goethite-rich mottles, becoming relatively more enriched in the LREE compared to the HREE, which is consistent with the incongruent dissolution of jarosite to form goethite and the release of greater amounts of jarosite REE to solution, including proportionately more of the jarosite-compatible LREE.Maximum surface water REE concentrations in acidic water were 100-200 ppb La and Ce. REE patterns in surface water were very similar to the porewater transition zone, enriched in the MREE, but asymmetric, relatively enriched in the LREE compared to the HREE.     

Centimeter-Level Positioning of a U. S. Coast Guard Buoy Tender

With the availability of high-accuracy, differential global positioning system (GPS) results in real-time, there is a new opportunity to use GPS to accurately measure a marine vessel's dynamic draft (settlement and squat) and 3D attitude (roll, pitch, and heading). The National Geodetic Survey (NGS) and the Coast Survey (CS), offices of the National Ocean Service (NOS), National Oceanic and Atmospheric Administration (NOAA), propose to transfer this technology to the shipping industry. The overall goal of this project is to provide the position of a vessel's keel in real time to within 10 cm (about 4 inches) relative to the bottom of the shipping channel. In support of this phase of the project, there were three meetings hosted by the Port of Oakland, California and NOS to discuss the real-time positioning of vessels project. On December 3 and 4, 1996, CS, NGS, Trimble Navigation Ltd., and the U. S. Coast Guard (USCG) performed GPS tests on a USCG buoy-tender ship. GPS data were used to compute the vessel's dynamic draft and 3D attitude. During the test, five receivers continually collected data; one receiver was located at a base station on the USCG pier on Yerba Buena Island, and four were on the ship: two on the stern and two on the bow. CS installed a TSS-335B vertical reference unit (to measure heave, pitch, and roll) in the engine room of the ship. NOS processed the GPS data and computed the vessel's dynamic draft and 3D attitude. The results indicate that the linear equivalent to the vessel's dynamic draft and 3D attitude were accurate to the 10-cm level using GPS. It was also demonstrated how a ship can be used to measure local water-level changes and actual water-level values everywhere it travels. ? 1999 John Wiley & Sons, Inc.     

Vulnerability of Island Tropical Montane Cloud Forests to Climate Change, with Special Reference to East Maui, Hawaii

Island tropical montane cloud forests may be among the most sensitive of the world's ecosystems to global climate change. Measurements in and above a montane cloud forest on East Maui, Hawaii, document steep microclimatic gradients. Relatively small climate-driven shifts in patterns of atmospheric circulation are likely to trigger major local changes in rainfall, cloud cover, and humidity. Increased interannual variability in precipitation and hurricane incidence would provide additional stresses on island biota that are highly vulnerable to disturbance-related invasion of non-native species. Because of the exceptional sensitivity of these microclimates and forests to change, they may provide valuable listening posts for detecting the onset of human-induced global climate change.     

URBAN COGNITIVE MAPS: COMPUTATION AND STRUCTURE

Geographic research has not focused on the information we encode into our memories about the characteristics of locations. The accuracy of information encoded in urban cognitive maps, how information varies among individuals, and the structure of the information were studied. Experimental results indicated subjects were more accurate and consistent for socio-economic than for life-cycle characteristics. Some characteristics of the population in a neighborhood, such as race and income, may be more visible and easier to encode through direct contact than other less visible characteristics such as age. A theoretical argument is made that characteristics not encoded for locations can possibly be computed through their covariation with known characteristics.     

The hydrodynamics of bipolar explosions

Bipolarity is a common feature in the outbursts of classical, recurrent and symbiotic novae. In this paper, we present the results of numerical calculations of bipolar explosions in which two parcels of gas are ejected at highly supersonic and oppositely directed velocities into a cold surrounding medium. The calculations demonstrate the formation of a dense ring of shocked material in the plane normal to the line of ejection, due to the interaction of two bowshocks. Observational candidates for this hydrodynamic phenomenon are discussed.This author is supported by the SERC.     

THE IDENTIFICATION OF REGIONAL BOUNDARIES ON COGNITIVE MAPS*

This study investigates regions on cognitive maps and methods used to identify their boundaries. Subjects either drew regional boundaries on a map or decided in which region sample points were located. These methods produced similar results with differences associated more with regional boundaries than cores. The amount of time needed to make point decisions demonstrated the subjects' cognitive process and corroborated boundaries and cores for the cognitive regions. Differences among subjects' maps were greater when boundaries were drawn.     

Microstructural analysis of faulting in quartzite,Assynt, NW Scotland: Implications for fault zone evolution

Macroscopic fracture arrays, microstructures and interpreted deformation mechanisms are used to assess the development of a minor reverse fault (backthrust) in quartzite from the Moine Thrust Zone, Assynt, NW Scotland. Fracturing dominates the faulting via the progression: intragranular extension microcracks; transgranular, cataclasite absent extension fractures; through-going, cataclasite filled shear microfaults, within which fracturing and particulate flow operate. However, both diffusive mass transfer (DMT) and intracrystalline plasticity (low temperature plasticity, LTP) processes also contribute to the fault zone deformation and lead to distinct associations of deformation mechanisms (e.g., DMT-fracture and LTP-fracture or low-temperature ductile fracture, LTDF). Over a large range of scales the fault zone consists of blocks of relatively intact rock separated by narrow zones of intense deformation where fracture processes dominate. The populations of fragments/blocks of different sizes in the fault zone have a power-law relationship which is related to the dimension of the fault zone. These observations are used to develop a general model for fault zone evolution based on the distribution of deformation features as a function of either time or space. A systematic variation in the deformation rate: time histories is recognised, associated with different positions within the fault zone. Thus, the fault zone preserves elements of the birth, life and death sequences associated with the displacement history and strain accommodation.Dedicated to the memory of Will Ramsbotham (1967–93).     

Late Pleistocene-Holocene Paleoceanography and Ventilation of the Gulf of California

Sediment cores collected in 1990 from the Gulf of California have been studied using stable isotope and radiocarbon techniques to reconstruct the climate and ventilation histories since the last glacial maximum. Benthic foraminiferal δ¹⁸O from core tops in a water depth range of 145 to 1442 m increases by about 2% with increasing depth. This is consistent with a composite temperature profile constructed from several hydrocasts in the various gulf basins. However, the δ¹⁸O water/salinity relationship is not sufficiently linear in gulf locations or in nearby open Pacific Geochemical Ocean Sections Study (GEOSECS) stations to be useful in solving paleotemperature equations. Of the most common benthic foraminifera, only Planulina ariminensis has δ¹³C that is consistent with the measured δ¹³C of ΣCO₂. Several cores in the depth range 500 to 900 m have the laminated Holocene and Bolling/Allerod sediments, and the nonlaminated glacial age and Younger Dryas sediments that are typical of the gulf and other locations such as Santa Barbara Basin. The best of those, Jumbo Piston Core (JPC) 56 from 818 m water depth on the western margin of Guaymas Basin, was sampled for intensive study. Oxygen isotope ratios in benthic and planktonic foraminifera show little evidence for deglacial temperature oscillations. Carbon isotope ratios are generally lower during warm epochs, but the most striking result is strongly lowered benthic and planktonic δ¹³C about 9500 years ago. This may reflect water column oxidation of locally released methane. Neither benthic δ¹³C in depth section nor paired benthic and planktonic ¹⁴C data in JPC56 are consistent with increased intermediate water ventilation during the glacial maximum and Younger Dryas. Likewise, ¹⁴C data from 5 pairs of foraminifera from the Okhotsk Sea fail to support better ventilation in that basin during the last glacial maximum. This revised version was published online in August 2006 with corrections to the Cover Date.     

Molecular and cultivation-dependent analysis of metal-reducing bacteria implicated in arsenic mobilisation in south-east asian aquifers

The reduction of sorbed As(V) to the potentially more mobile As(III) by As-respiring anaerobic bacteria has been implicated in the mobilisation of the toxic metalloid in aquifer sediments in SE Asia. However, there is currently only a limited amount of information on the identity of the organisms that can respire As(V) in these sediment systems. Here experiments are described that have targeted As(V)-respiring bacteria using cultivation-independent molecular techniques, and also more traditional microbiological approaches that have used growth media highly selective for organisms that can grow using arsenate as the sole electron acceptor supplied for anaerobic growth. The molecular techniques used have initially targeted DNA from microcosms displaying maximal rates of arsenate reduction, both with and without added electron donor. More recent studies from the authors’ laboratory have used stable isotope probing techniques, targeting DNA from the active microbial fraction in microcosms labelled with [¹³C]acetate supplied as an electron donor for arsenate reduction. Phylogenetic analyses using a highly conserved genetic marker (the 16S rRNA gene) have suggested the involvement of Sulfurospirillum and Geobacter species in arsenate-respiration, and this has been supported further by complimentary experiments using more traditional microbiological techniques. Additional research required to clarify the role of these organisms in the mobilisation of As in situ are discussed.