Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

Neodymium isotopic variations in Northwest Pacific waters

Four vertical profiles of the concentration and isotopic composition of Nd in seawater were obtained in the western North Pacific. Two profiles from the Kuroshio Current regime showed congruently that although the Nd concentration increases gradually with depth, its isotopic composition varies significantly with depth depending upon the water mass occupying the water column. The high-salinity Kuroshio waters originating from the North Pacific Tropical Water (NPTW) carry the least radiogenic Nd (?_Nd = −7.4 to −8.7) to this region at ∼250 m from the western margin continental shelves, most likely from the East China Sea. The Nd isotopic compositions in the North Pacific Intermediate Water (NPIW) that occurs at 600 to 1000 m in the subtropical region are fairly uniform at ?_Nd = −3.7. The profile data from the ∼38° to 40°N Kuroshio/Oyashio mixed water region off Sanriku of Honshu, Japan, also suggest that the newest NPIW with ?_Nd = −3.2 is formed there by the mixing of various source waters, and the radiogenic component of Nd is derived mainly from the Oyashio waters.In the Pacific Deep Water (PDW) below ∼1000 m, the Nd isotopic composition is neither vertically nor horizontally homogeneous, suggesting that it serves as a useful tracer for sluggish deep water circulation as well. Two profiles from the Izu-Ogasawara Trench showed a minimum ?_Nd value at ∼2000 m, suggesting that there exists a horizontal advective flow in the vicinity of Honshu, Japan. There is some evidence from other chemical properties to support this observation. The waters below 4000 m including those within the trench in the subtropical region have ?_Nd values of around −5, suggesting that the deep waters are fed from the south along the western boundary, ultimately from the Antarctic Bottom Water (AABW) in the South Pacific. This extends up to ∼40°N along the Japanese Islands. In the subarctic region (>∼42°N), the waters have more radiogenic Nd with ?_Nd > −4.0 throughout the water column, presumably due to the supply of Nd by weathering in such igneous provinces as the Kuril-Kamchatska-Aleutian Island chain. The lateral inhomogeneity of the Nd isotopic composition in PDW suggests that there may be different circulation and mixing regimes in the North Pacific Basin.     

Late Quaternary downcutting rates of the Qianyou River from U/Th speleothem dates, Qinling mountains, China

Dating deposits in caves formed by rivers may yield insight into rates and processes of bedrock incision. Three cave passages at different levels have developed in the walls of the Qianyou River valley in the Qinling mountains, south of the city of Xian, China. Twelve speleothem samples near the position of palaeowater tables in three cave passages are dated by the ²³⁰Th dating method. The results show that the river cut down at the rate of 0.23 ± 0.02 mm/yr from 358,000 ± 38,000 to 247,000 ± 28,000 yr ago, 0.19 ± 0.03 mm/yr from 247,000 ± 28,000 to 118,000 ± 19,000 yr ago, and 0.51 ± 0.08 mm/yr from 118,000 ± 19,000 yr ago until today. These fall very close to the glacial-interglacial transition following marine oxygen isotope stages 10, 8, and 6, respectively. The increase in downcutting rates during the interglacial period is consistent with warm, wet weather, increasing rates of erosion. This may lead us toward an underlying mechanism for modulating incision that is not in a direct response to the presence of headwater glaciers.     

Coastline configuration and geomorphologic development mode of arc-shaped coast in South China

1IntroductionArc-shaped bays are quite common on exposed sediment coast in South China, where the crenulate-bay beaches occur with the presence of two consecutive headlands and a predominant wave approach oblique to the alignment of the upcoast and downcoast headlands (Yasso, 1965). Oblique persistent swell striking a shoreline transports sediment alongshore and sculptures a coast into arc-shaped beaches. The shoreline of beach appearance mainly consists of straight segment and shadow segment…     

国内旅游文化开发研究综述

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宁夏中北部地区沙尘暴天气发生过程中的不稳定条件分析

从沙尘暴的形成条件入手，对宁夏中北部地区近30a来沙尘暴天气发生过程中的不稳定条件进行了较为详尽的分析。结果表明：沙尘暴发生三前，大气的不稳定性明显增强；沙尘暴天气发生时不稳定性主要发生在700hPa以下，最为突出的是850hPa以下；沙尘暴发生过程中不稳定性达到最强。     

博斯腾湖向塔里木河输水风险分析方法

为了拯救塔里木河下游生态环境，塔里木河流域管理局根据博斯腾湖从1999年到2003年处于丰水期，湖泊处于高水位的有利时机，从2000年5月到2003年6月实施5次向塔里木河下游生态应急输水，结束塔里木河下游300多km河道近30年的断流历史。现在的问题是“博斯腾湖向塔里木河生态输水能否持续?”，“保证可持续输水的风险有多大?”本文以解决此问题为实例，介绍一般水库调节计算和水库特征水位确定方法；主要探讨水库(湖泊)向下游输水可持续性风险分析问题，提出的方法称为“水库输水可持续性风险计算时历试算法”，简称为“试算法”(T＆E方法)；并将此方法应用于实例中，计算博斯腾湖向塔里木河下游输水的可持续风险。     

武汉地铁及长江隧道沿线地下管线现状分析

本文论述了利用城市地下管线信息系统对武汉地铁和长江隧道沿线进行地下管线现状调查的过程和方法，结果表明利用该系统所完成的分析和成果资料满足了武汉及长江隧道沿线工程可行性研究的需要。