USGS46 Greenland Ice Core Water – A New Isotopic Reference Material for δ2H and δ18O Measurements of Water

Ice core from Greenland was melted, filtered, homogenised, loaded into glass ampoules, sealed, autoclaved to eliminate biological activity, and calibrated by dual‐inlet isotope‐ratio mass spectrometry. This isotopic reference material (RM), USGS46, is intended as one of two secondary isotopic reference waters for daily normalisation of stable hydrogen (δ²H) and stable oxygen (δ¹⁸O) isotopic analysis of water with a mass spectrometer or a laser absorption spectrometer. The measured δ²H and δ¹⁸O values of this reference water were ?235.8 ± 0.7‰ and ?29.80 ± 0.03‰, respectively, relative to VSMOW on scales normalised such that the δ²H and δ¹⁸O values of SLAP reference water are, respectively, ?428 and ?55.5‰. Each uncertainty is an estimated expanded uncertainty (U = 2u_c) about the reference value that provides an interval that has about a 95‐percent probability of encompassing the true value. This reference water is available in cases containing 144 glass ampoules that are filled with either 4 ml or 5 ml of water per ampoule.     

Evaluating spatiotemporal variation in water chemistry of the upper Colorado River using longitudinal profiling

Stream water chemistry is traditionally measured as variation over time at fixed sites, with sparse sites providing a crude understanding of spatial heterogeneity. An alternative Lagrangian reference frame measures changes with respect to both space and time as water travels through a network. Here, we collected sensor-based measurements of water chemistry at high spatial resolution along nearly 500 km of the Upper Colorado River. Our objective was to understand sources of spatiotemporal heterogeneity across different solutes and determine whether longitudinal change manifests as smooth gradients as suggested by the River Continuum Concept (RCC) or as abrupt changes as suggested by the Serial Discontinuity Concept (SDC). Our results demonstrate that Lagrangian sampling integrates spatiotemporal variation, and profiles reflect processes that vary in both space and time and over different scales. Over each day of sampling, water temperature (T) and dissolved oxygen (DO) varied strongly in response to diel solar cycles, with most of the variation driven by sampling time rather than sampling location. Equilibration of T and DO with the atmosphere limited small scale spatial heterogeneity, with variation at the entire profile scale driven by regional climate gradients. As such, T and DO profiles more closely approximated the smooth gradients of the RCC (though including temporal sampling artefacts). Conversely, variation in specific conductance and nitrate (NO₃-N) was largely driven by spatial patterns of lateral inflows such as tributaries and groundwater. This resulted in discrete shifts in the profiles at or downstream of discontinuities, appearing as the profiles expected with the SDC. The concatenation of spatiotemporal variation that produces observed Lagrangian profiles presents interpretive challenges but also augments our understanding of where, how, and critically why water chemistry changes in time and space as it moves through river networks.     

Exploring the application of topographic indices in urban areas as indicators of pluvial flooding locations

In urban areas, the presence of impervious surfaces limits natural drainage and routes water to stormwater infrastructure with finite capacity, making these areas especially prone to flooding. Though large floods are responsible for endangering lives and causing extensive damage, there is growing evidence that more frequent floods with shallow water depths, termed nuisance flooding, can have a high cumulative cost and many direct and indirect damages. To determine whether locations of nuisance flooding may be linked to topography, we took a parsimonious, spatially distributed approach to explore whether high topographic index values co-occur with citizen-reported nuisance flooding. We obtained nuisance flood reports from the municipal data service 311 for several watersheds in New York City and Baltimore, USA. Our analysis tested two topographic indices (TI)—topographic wetness index (TWI) and sink depth—both calculated from high-resolution (~1 m) digital elevation models. Generally, our findings suggest that not all but many locations of reported flooding tend to coincide with deep sinks or large TWI. However, nuisance flooding reports most commonly coincided with deep sinks and high TWI when using a maximum, instead of coincident, TI value extracted around each reported location of flooding, an approach we used due to the uncertainty in location accuracy of flooding reports. Overall, our results show promise for application of topographic indices, typically applied in more natural settings, as indicators of nuisance flooding areas in urbanized environments. Although limitations to this approach exist, the application of TIs and crowd-sourced reporting in tandem could provide a useful starting point for mapping flood-prone areas in many cities with technologically adept community members and ample geospatial data.     

Urban greening,property and more-than-human commoning

ABSTRACT

Urban greening is about bringing vegetation into cities in ways that produce flourishing urban ecologies whilst also making cities more liveable for human inhabitants. We focus here on greening that is done through the maintenance or establishment of gardens, parks, urban forests and informal spaces. We argue that in contexts with established property law systems, such as Australia, making urban ecologies through greening is shaped heavily by relations of property tied to land. This includes constraining the extent to which urban greening can contribute to socio-ecologically just cities. We suggest that progressing greening that is more attentive to the geographies and temporalities of more-than-human life requires us to trouble the hold of property over greening. To do this we explore the possibilities opened up by the lens of urban commons/commoning. We engage with the emerging concept of more-than-human commoning as a way of attuning urban greening to nonhuman agency and affordances. We also grapple with the risk of obscuring or concealing difference between humans in the way commoning makes room for more-than-humans, especially in the context of settler-colonialism. We conclude by calling for a more overt politics of urban greening that encompasses diverse human and more-than-human experiences of the city.     

Reproductive Ecology of Black Mangrove (<Emphasis Type="Italic">Avicennia germinans</Emphasis>) Along the Louisiana Coast: Propagule Production Cycles,Dispersal Limitations,and Establishment Elevations

Black mangrove (Avicennia germinans) reproduces by producing propagules through the process of cryptovivipary, which requires a significant energy investment. We conducted a series of field and greenhouse studies to track propagule production in years of high and low disturbances (i.e., hurricanes), the effects of time and salinity on propagule dispersal potential, and the relationship between hydrology and propagule establishment elevations. Trees tended to produce greater numbers of propagules in years after hurricanes, and individual trees alternated the amount of energy they invested in reproduction in consecutive years. In the greenhouse, propagule buoyancy was affected by salinity with propagules in 36 remaining buoyant for over 110 days and establishment success decreasing with dispersal period length. Finally, a field survey across five sites in southeastern Louisiana revealed that the 2009 cohort of propagules established at significantly lower elevations than mature trees occurred. These findings elucidate some salient features of black mangrove reproductive biology in the northern portion of its North American distribution.     

Use of Fossil Bryozoans in Sourcing Lithic Artifacts

This study reviews the occurrence and potential of bryozoans within lithic artifacts and also sets out a methodology for their use in sourcing and discusses the advantages and disadvantages of this approach. We present case studies from our own research and from the literature on using bryozoans in sourcing archaeological lithic artifacts. Fossil bryozoans of different ages and clades can be effectively used to determine the material source of lithic artifacts from a variety of prehistoric ages. The case studies included in this report span the stratigraphic range of bryozoans from the Ordovician to the Neogene. The bryozoans came from four different orders: trepostome, fenestrate, cyclostome, and cheilostome. The use of these lithic artifacts ranged back to 25 ka. Although the majority of the fossil bryozoans were incidental in the artifacts, the bryozoans were still useful for determining their original source rock. The improved searchable online paleontologic databases allow for more efficient use of fossil bryozoans to constrain the stratigraphic and paleogeographic distribution of source outcrops. Although generally underutilized in sourcing prehistoric lithic artifacts, it is clear that by analyzing bryozoans, an increased understanding of the lithologic nature of these materials could be gained by the archaeological community.     

Cassini RADAR observations of Enceladus, Tethys, Dione, Rhea, Iapetus, Hyperion, and Phoebe

Cassini 2.2-cm radar and radiometric observations of seven of Saturn's icy satellites yield properties that apparently are dominated by subsurface volume scattering and are similar to those of the icy Galilean satellites. Average radar albedos decrease in the order Enceladus/Tethys, Hyperion, Rhea, Dione, Iapetus, and Phoebe. This sequence most likely corresponds to increasing contamination of near-surface water ice, which is intrinsically very transparent at radio wavelengths. Plausible candidates for contaminants include ammonia, silicates, metallic oxides, and polar organics (ranging from nitriles like HCN to complex tholins). There is correlation of our targets' radar and optical albedos, probably due to variations in the concentration of optically dark contaminants in near-surface water ice and the resulting variable attenuation of the high-order multiple scattering responsible for high radar albedos. Our highest radar albedos, for Enceladus and Tethys, probably require that at least the uppermost one to several decimeters of the surface be extremely clean water ice regolith that is structurally complex (i.e., mature) enough for there to be high-order multiple scattering within it. At the other extreme, Phoebe has an asteroidal radar reflectivity that may be due to a combination of single and volume scattering. Iapetus' 2.2-cm radar albedo is dramatically higher on the optically bright trailing side than the optically dark leading side, whereas 13-cm results reported by Black et al. [Black, G.J., Campbell, D.B., Carter, L.M., Ostro, S.J., 2004. Science 304, 553] show hardly any hemispheric asymmetry and give a mean radar reflectivity several times lower than the reflectivity measured at 2.2 cm. These Iapetus results are understandable if ammonia is much less abundant on both sides within the upper one to several decimeters than at greater depths, and if the leading side's optically dark contaminant is present to depths of at least one to several decimeters. As argued by Lanzerotti et al. [Lanzerotti, L.J., Brown, W.L., Marcantonio, K.J., Johnson, R.E., 1984. Nature 312, 139-140], a combination of ion erosion and micrometeoroid gardening may have depleted ammonia from the surfaces of Saturn's icy satellites. Given the hypersensitivity of water ice's absorption length to ammonia concentration, an increase in ammonia with depth could allow efficient 2.2-cm scattering from within the top one to several decimeters while attenuating 13-cm echoes, which would require a six-fold thicker scattering layer. If so, we would expect each of the icy satellites' average radar albedos to be higher at 2.2 cm than at 13 cm, as is the case so far with Rhea [Black, G., Campbell, D., 2004. Bull. Am. Astron. Soc. 36, 1123] as well as Iapetus.     

Application of 210Pbex inventories to measure net hillslope erosion at burned sites

Fallout radionuclides, including lead‐210 excess (²¹⁰Pb_ex), have been broadly and successfully used to quantify net hillslope sediment transport in agricultural, pastoral and forested landscapes but have only recently been applied in burned terrain. Quantifying post‐fire erosion is important because fires can amplify hillslope erosion, impacting terrestrial and aquatic habitat and water quality. However, we lack a basic understanding of the fate of ²¹⁰Pb_ex in fires. To address this knowledge gap, we collected over 400 soil samples from unburned, moderately and severely burned forested sites in central Idaho. We measured soil ²¹⁰Pb_ex content at stable reference and eroding sites and in mineral and organic soil components. At all sites, organic matter had the highest concentration of ²¹⁰Pb_ex, representing 30% to 73% of the total activity. At the severely and moderately burned sites, ²¹⁰Pb_ex reference inventories were lower by 58% and 41%, with about 40% less organic mass, relative to the unburned site. These results indicate that most ²¹⁰Pb_ex in our semi‐arid, forested sites was bound to organic matter, and that a substantial portion of this lead was lost due to forest fires. These losses likely occurred through volatilization and wind transport of smoke and ash. In the moderately burned site, ²¹⁰Pb_ex losses were more spatially variable, potentially due to spatially uneven fire intensity and effects. Despite equal percent losses of ²¹⁰Pb_ex, lower inventories at the burned sites produced lower calculated net erosion rates relative to the unburned site. Thus, given methodological uncertainties, ²¹⁰Pb_ex losses due to fire, and the subsequent sensitivity of calculated net erosion rates to these lower ²¹⁰Pb_ex inventories, we suggest this method should not be used in burned terrain to calculate absolute net erosion and deposition rates. However, within a given burned site, ²¹⁰Pb_ex inventories still provide useful information describing relative soil losses and storage across the landscape. Copyright © 2012 John Wiley & Sons, Ltd.